The shot noise of the current $I$ through junctions to single trioxatriangulenium cations (TOTA$^+$) on Au(111) is measured with a low temperature scanning tunneling microscope using Au tips. The noise is significantly reduced compared to the Poisson noise power of $2eI$ and varies linearly with the junction conductance. The data are consistent with electron transmission through a single spin-degenerate transport channel and show that TOTA$^+$ in a Au contact does not acquire an unpaired electron. Ab initio calculations reproduce the observations and show that the current involves the lowest unoccupied orbital of the molecule and tip states close to the Fermi level.
We investigate diffusive nanowire-based structures with two normal terminals on the sides and a central superconducting island in the middle, which is either grounded or floating. Using a semiclassical calculation we demonstrate that both device layouts permit a quantitative measurement of the energy-dependent sub-gap thermal conductance $G_mathrm{th}$ from the spectral density of the current noise. In the floating case this goal is achieved without the need to contact the superconductor provided the device is asymmetric, that may be attractive from the experimental point of view. In addition, we observe that the shot noise in the floating case is sensitive to a well-known effect of non-equilibrium suppression and bistability of the superconducting gap. Our calculations are directly applicable to the multi-mode case and can serve as a starting point to understand the shot noise response in open one dimensional Majorana device.
Pinning single molecules at desired positions can provide opportunities to fabricate bottom-up designed molecular machines. Using the combined approach of scanning tunneling microscopy and density functional theory, we report on tip-induced anchoring of Niphthalocyanine molecules on an Au(111) substrate. We demonstrate that the tip-induced current leads to the dehydrogenation of a benzene-like ligand in the molecule, which subsequently creates chemical bonds between the molecule and the substrate. It is also found that the diffusivity of Ni-phthalocyanine molecules is dramatically reduced when the molecules are anchored on the Au adatoms produced by bias pulsing. The tip-induced molecular anchoring would be readily applicable to other functional molecules that contain similar ligands.
Electrical conductance measurements have limited scope in identifying Andreev edge states (AESs), which form the basis for realizing various topological excitations in quantum Hall (QH) - superconductor (SC) junctions. To unambiguously detect AESs, we measure shot noise along with electrical conductance in a graphene based QH-SC junction at integer filling nu=2. Remarkably, we find that the Fano factor of shot noise approaches half when the bias energy is less than the superconducting gap, whereas it is close to zero above the superconducting gap. This is striking, given that, at the same time, the electrical conductance remains quantized at 2e^2/h within and above the superconducting gap. A quantized conductance is expected to produce zero shot noise due to its dissipationless flow. However, at a QH-SC interface, AESs carry the current in the zero-bias limit and an equal mixing of electron and hole like states produces half of the Poissonian shot noise with quantized conductance. The observed results are in accord with our detailed theoretical calculations of electrical conductance and shot noise based on non-equilibrium Greens function method in the presence of disorder. Our results pave the way in using shot noise as a detection tool in the search of exotic topological excitations in QH-SC hybrids.
Quantum dots (QDs) investigated through electron transport measurements often exhibit varying, state-dependent tunnel couplings to the leads. Under specific conditions, weakly coupled states can result in a strong suppression of the electrical current and they are correspondingly called blocking states. Using the combination of conductance and shot noise measurements, we investigate blocking states in carbon nanotube (CNT) QDs. We report negative differential conductance and super-Poissonian noise. The enhanced noise is the signature of electron bunching, which originates from random switches between the strongly and weakly conducting states of the QD. Negative differential conductance appears here when the blocking state is an excited state. In this case, at the threshold voltage where the blocking state becomes populated, the current is reduced. Using a master equation approach, we provide numerical simulations reproducing both the conductance and the shot noise pattern observed in our measurements.
The conductance quantization and shot noise below the first conductance plateau $G_0 = 2e^2/h$ are measured in a quantum point contact fabricated in a GaAs/AlGaAs tunnel-coupled double quantum well. From the conductance measurement, we observe a clear quantized conductance plateau at $0.5G_0$ and a small minimum in the transconductance at $0.7 G_0$. Spectroscopic transconductance measurement reveals three maxima inside the first diamond, thus suggesting three minima in the dispersion relation for electric subbands. Shot noise measurement shows that the Fano factor behavior is consistent with this observation. We propose a model that relates these features to a wavenumber directional split subband due to a strong Rashba spin--orbit interaction that is induced by the center barrier potential gradient of the double-layer sample.
Michael Mohr
,Torben Jasper-Toennies
,Thomas Frederiksen
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(2019)
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"Conductance channels of a platform molecule on Au(111) probed with shot noise"
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Thomas Frederiksen
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