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Register a new userEvidence of unconventional superconductivity in the Ni-doped NbB2 system
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In this paper, a comprehensive study of the effects of Ni-doping on structural, electrical, thermal and magnetic properties of the NbB2 is presented. Low amounts (leq 10 %) of Ni substitution on Nb sites cause structural distortions and induce drastic changes in the physical properties, such as the emergence of a bulk superconducting state with anomalous behaviors in the critical fields (lower and upper) and in the specific heat. Ni-doping at the 9 at.% level, for instance, is able to increase the critical temperature (TC) in stoichiometric NbB2 (< 1.3 K) to approximately 6.0 K. Bulk superconductivity is confirmed by magnetization, electronic transport, and specific heat measurements. Both Hc1 and Hc2 critical fields exhibit a linear dependence with reduced temperature (T/TC), and the specific heat deviates remarkably from the conventional exponential temperature dependence of the single-band BCS theory. These findings suggest multiband superconductivity in the composition range from 0.01 leq x leq 0.10.
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Superconductivity (SC) is one of the most intriguing physical phenomena in nature. Nucleation of SC has long been considered highly unfavorable if not impossible near ferromagnetism, in low dimensionality and, above all, out of non-superconductor. Here we report observation of SC with TC near 4 K in Ni/Bi bilayers that defies all known paradigms of superconductivity, where neither ferromagnetic Ni film nor rhombohedra Bi film is superconducting in isolation. This highly unusual SC is independent of the growth order (Ni/Bi or Bi/Ni), but highly sensitive to the constituent layer thicknesses. Most importantly, the SC, distinctively non-s pairing, is triggered from, but does not occur at, the Bi/Ni interface. Using point contact Andreev reflection, we show evidences that the unique SC, naturally compatible with magnetism, is triplet p-wave pairing. This new revelation may lead to unconventional avenues to explore novel SC for applications in superconducting spintronics.
We report the synthesis, magnetic susceptibility and crystal structure analysis for NbB2+x (x = 0.0 to 1.0) samples. The study facilitates in finding a correlation among the lattice parameters, chemical composition and the superconducting transition temperature Tc. Rietveld analysis is done on the X- ray diffraction patterns of all synthesized samples to determine the lattice parameters. The a parameter decreases slightly and has a random variation with increasing x, while c parameter increases from 3.26 for pure NbB2 to 3.32 for x=0.4 i.e. NbB2.4. With higher Boron content (x>0.4) the c parameter decreases slightly. The stretching of lattice in c direction induces superconductivity in the non- stoichiometric niobium boride. Pure NbB2 is non-superconductor while the other NbB2+x (x>0.0) samples show diamagnetic signal in the temperature range 8.9-11K. Magnetization measurements (M-H) at a fixed temperature of 5K are also carried out in both increasing and decreasing directions of field. The estimated lower and upper critical fields (Hc1 & Hc2) as viewed from M-H plots are around 590 and 2000Oe respectively for NbB2.6 samples. In our case, superconductivity is achieved in NbB2 by varying the Nb/B ratios, rather than changing the processing conditions as reported by others.
IrTe$_2$ with large spin-orbital coupling (SOC) shows a CDW-like first order structural phase transition from high-temperature trigonal phase to low-temperature monoclinic phase at 270 K, accompanying with a large jump in transport and magnetic measurement as well as in heat capacity. Here, the 3d element Ni has been doped into IrTe$_2$ by growing Ir$_{1-x}$Ni$_x$Te$_2$ single crystals. Both XRD and XPS results reveal that the Ni atoms have substituted for Ir, which is consistent with the calculation result. Like the CDW behaviour, the structural phase transition shows competition and coexistence with the superconductivity. The monoclinic phase transition has been suppressed gradually with the increase of the doping amount of Ni, at last giving rise to the stabilization of the trigonal phase with superconductivity. Within 0.1$leq$x$leq$0.2, Ir$_{1-x}$Ni$_x$Te$_2$ shows the superconductive behaviour with T$_c$ around 2.6K. The superconductivity shows anisotropy with dimensionless anisotropy parameter $gamma$=$xi_{//}$$/$$xi_{perp}$$sim$ 2. Even Ni element shows ferromagnetic behaviour, Ir$_{1-x}$Ni$_x$Te$_2$ only shows weak paramagnetism, no ferromagnetic order is observed in it, which is coincident with the calculation result that their up and down spin density of states compensate each other well. In addition, for other 3d elements Fe, Co and Mn doped IrTe$_2$, only Ir$_{1-x}$Mn$_x$Te$_2$ owns magnetism with magnetic moment of 3.0$mu$$_B$ to the supercell, theoretically.
We have measured the magnetic penetration depth of the recently discovered binary superconductor MgB_2 using muon spin rotation and low field $ac$-susceptibility. From the damping of the muon precession signal we find the penetration depth at zero temperature is about 85nm. The low temperature penetration depth shows a quadratic temperature dependence, indicating the presence of nodes in the superconducting energy gap.
Conventional superconductivity, as used in this review, refers to electron-phonon coupled superconducting electron-pairs described by BCS theory. Unconventional superconductivity refers to superconductors where the Cooper pairs are not bound together by phonon exchange but instead by exchange of some other kind, e. g. spin fluctuations in a superconductor with magnetic order either coexistent or nearby in the phase diagram. Such unconventional superconductivity has been known experimentally since heavy fermion CeCu2Si2, with its strongly correlated 4f electrons, was discovered to superconduct below 0.6 K in 1979. Since the discovery of unconventional superconductivity in the layered cuprates in 1986, the study of these materials saw Tc jump to 164 K by 1994. Further progress in high temperature superconductivity would be aided by understanding the cause of such unconventional pairing. This review compares the fundamental properties of 9 unconventional superconducting classes of materials - from 4f-electron heavy fermions to organic superconductors to classes where only three known members exist to the cuprates with over 200 examples, with the hope that common features will emerge to help theory explain (and predict!) these phenomena. In addition, three new emerging classes of superconductors (topological, interfacial [e. g. FeSe on SrTiO3], and H2S under high pressure) are briefly covered, even though their conventionality is not yet fully determined.
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