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Register a new userSpatial Variations in Titans Atmospheric Temperature: ALMA and Cassini Comparisons from 2012 to 2015
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Submillimeter emission lines of carbon monoxide (CO) in Titans atmosphere provide excellent probes of atmospheric temperature due to the molecules long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) from 2012 to 2015 that contain strong CO rotational transitions. Utilizing ALMAs high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titans disk using datasets with beam sizes of ~0.3. Temperature profiles retrieved by the NEMESIS radiative transfer code are compared to Cassini Composite Infrared Spectrometer (CIRS) and radio occultation science results from similar latitude regions. Small seasonal variations in atmospheric temperature are present from 2012 to 2015 in the stratosphere and mesosphere (~100-500 km) of spatially resolved regions. We measure the stratopause (320 km) to increase in temperature by 5 K in northern latitudes from 2012-2015, while temperatures rise throughout the stratosphere at lower latitudes. While retrieved temperature profiles cover a range of latitudes in these observations, deviations from CIRS nadir maps and radio occultation measurements convolved with the ALMA beam-footprint are not found to be statistically significant, and discrepancies are often found to be less than 5 K throughout the atmosphere. ALMAs excellent sensitivity in the lower stratosphere (60-300 km) provides a highly complementary dataset to contemporary CIRS and radio science observations. The demonstrated utility of CO emission lines in the submillimeter as a tracer of Titans atmospheric temperature lays the groundwork for future studies of other molecular species, as temperature profiles are found to consistently vary with latitude in all three years by up to 15 K.
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We present spatially resolved ($0.1 - 1.0$) radio maps of Neptune taken from the Very Large Array and Atacama Large Submillimeter/Millimeter Array between $2015-2017$. Combined, these observations probe from just below the main methane cloud deck at $sim 1$ bar down to the NH$_4$SH cloud at $sim50$ bar. Prominent latitudinal variations in the brightness temperature are seen across the disk. Depending on wavelength, the south polar region is $5-40$ K brighter than the mid-latitudes and northern equatorial region. We use radiative transfer modeling coupled to Markov Chain Monte Carlo methods to retrieve H$_2$S, NH$_3$, and CH$_4$ abundance profiles across the disk, though only strong constraints can be made for H$_2$S. Below all cloud formation, the data are well fit by $53.8^{+18.9}_{-13.4}times$ and $3.9^{+2.1}_{-3.1}times$ protosolar enrichment in the H$_2$S and NH$_3$ abundances, respectively, assuming a dry adiabat. Models in which the radio-cold mid-latitudes and northern equatorial region are supersaturated in H$_2$S are statistically favored over models following strict thermochemical equilibrium. H$_2$S is more abundant at the equatorial region than at the poles, indicative of strong, persistent global circulation. Our results imply that Neptunes sulfur-to-nitrogen ratio exceeds unity as H$_2$S is more abundant than NH$_3$ in every retrieval. The absence of NH$_3$ above 50 bar can be explained either by partial dissolution of NH$_3$ in an ionic ocean at GPa pressures or by a planet formation scenario in which hydrated clathrates preferentially delivered sulfur rather than nitrogen onto planetesimals, or a combination of these hypotheses.
We have searched for the presence of simple P and S-bearing molecules in Titans atmosphere, by looking for the characteristic signatures of phosphine and hydrogen sulfide in infrared spectra obtained by Cassini CIRS. As a result we have placed the first upper limits on the stratospheric abundances, which are 1 ppb (PH3) and 330 ppb (H2S), at the 2-sigma significance level.
In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30S--30N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new line list for the range 1300-1400cm -1, along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376 cm-1. At 748 cm-1 we retrieve 4.2 +/- 0.5 x 10(-7) (1-sigma error) at 2 mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 +/- 0.8 x 10(-7) at 2 mbar from the 1376 cm-1 band - a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperfect model of the n6 band of ethane. This study clearly shows for the first time the ubiquity of propanes emission bands across the thermal infrared spectrum of Titan, and points to an urgent need for further laboratory spectroscopy work, both to provide the line positions and intensities needed to model these bands, and also to further characterize haze spectral opacity. The present lack of accurate modeling capability for propane is an impediment not only for the measurement of propane itself, but also for the search for the emissions of new molecules in many spectral regions.
Titans ionosphere contains a plethora of hydrocarbons and nitrile cations and anions as measured by the Ion Neutral Mass Spectrometer and Cassini Plasma Spectrometer (CAPS) onboard the Cassini spacecraft. Data from the CAPS Ion Beam Spectrometer (IBS) sensor have been examined for five close encounters of Titan during 2009. The high relative velocity of Cassini with respect to the cold ions in Titans ionosphere allows CAPS IBS to function as a mass spectrometer. Positive ion masses between 170 and 310 u/q are examined with ion mass groups identified between 170 and 275 u/q containing between 14 and 21 heavy (carbon/nitrogen/oxygen) atoms. These groups are the heaviest positive ion groups reported so far from the available in situ ion data at Titan. The ion group peaks are found to be consistent with masses associated with Polycyclic Aromatic Compounds (PAC), including Polycyclic Aromatic Hydrocarbon (PAH) and nitrogen-bearing polycyclic aromatic molecular ions. The ion group peak identifications are compared with previously proposed neutral PAHs and are found to be at similar masses, supporting a PAH interpretation. The spacing between the ion group peaks is also investigated, finding a spacing of 12 or 13 u/q indicating the addition of C or CH. Lastly, the occurrence of several ion groups is seen to vary across the five flybys studied, possibly relating to the varying solar radiation conditions observed across the flybys. These findings further the understanding between the low mass ions and the high mass negative ions, as well as with aerosol formation in Titans atmosphere.
We examine Saturns atmosphere with observations from ground-based telescopes and Hubble Space Telescope (HST). We present a detailed analysis of observations acquired during 2018. A system of polar storms that appeared in the planet in March 2018 and remained active with a complex phenomenology at least until Sept. is analyzed elsewhere (Sanchez-Lavega et al., in press , 2019). Many of the cloud features in 2018 are long-lived and can be identified in images in 2017, and in some cases, for up to a decade using also Cassini ISS images. Without considering the polar storms, the most interesting long-lived cloud systems are: i) A bright spot in the EZ that can be tracked continuously since 2014 with a zonal velocity of 444 m/s in 2014 and 452 m/s in 2018. This velocity is different from the zonal winds at the cloud level at its latitude during the Cassini mission, and is closer to zonal winds obtained at the time of the Voyager flybys and zonal winds from Cassini VIMS infrared images of the lower atmosphere. ii) A large Anticyclone Vortex, here AV, that formed after the GWS of 2010-2011. This vortex has changed significantly in visual contrast, drift rate and latitude with minor changes in size over the last years. iii) A system of subpolar vortices present at least since 2011. These vortices follow drift rates consistent with zonal winds obtained by Cassini. We also present the positions of the vertices of the North polar hexagon from 2015 to 2018 compared with previous analyses during Cassini (2007-2014), observations with HST, and Voyager data in 1980-1981 to explore the long-term hexagons drift rate. Variations in the drift rate cannot be fit by seasonal changes. Instead, the different drift rates reinforce the role of the North Polar Spot that was present in the Voyager epoch to cause a faster drift rate of the hexagon at that time compared with the current one.
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