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Unconventional superconductivity in the nickel-chalcogenide superconductor, TlNi$_2$Se$_2$

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 Added by Erik Jellyman
 Publication date 2018
  fields Physics
and research's language is English




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We present the results of a study of the vortex lattice (VL) of the nickel chalcogenide superconductor TlNi2Se2, using small angle neutron scattering. This superconductor has the same crystal symmetry as the iron arsenide materials. Previous work points to it being a two-gap superconductor, with an unknown pairing mechanism. No structural transitions in the vortex lattice are seen in the phase diagram, arguing against d-wave gap symmetry. Empirical fits of the temperature-dependence of the form factor and penetration depth rule out a simple s-wave model, supporting the presence of nodes in the gap function. The variation of the VL opening angle with field is consistent with earlier reports of of multiple gaps.



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After our first discovery of superconductivity (SC) with $T_C$=3.7 K in TlNi$_2$Se$_2$, we grew successfully a series of TlNi$_2$Se$_{2-x}$S$_x$ (0.0 $leq$ x $leq$2.0) single crystals. The measurements of resistivity, susceptibility and specific heat were carried out. We found that SC with $T_C$=2.3 K also emerges in TlNi$_2$S$_2$ crystal, which appears to involve heavy electrons with an effective mass $m^*$=13$sim$25 $m_b$, as inferred from the normal state electronic specific heat and the upper critical field, $H_{C2}(T)$. It was found that the $T_C$ and superconducting volume fraction in TlNi$_2$Se$_{2-x}$S$_x$ crystals changes with the disorder degree induced by the partial substitution of S for Se, which is characterized by the residual resistivity ratio (textit{RRR}). The effect of the disorder on SC may provide some information for understanding the mechanism of SC in this new Ni-chalcogenide system.
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173 - Wenhao Liu , Sheng Li , hanlin Wu 2021
Two-dimensional transition metal dichalcogenide PdTe$_2$ recently attracts much attention due to its phase coexistence of type-II Dirac semimetal and type-I superconductivity. Here we report a 67 % enhancement of superconducting transition temperature in the 1T-PdSeTe in comparison to that of PdTe2 through partial substitution of Te atoms by Se. The superconductivity has been unambiguously confirmed by the magnetization, resistivity and specific heat measurements. 1T-PdSeTe shows type-II superconductivity with large anisotropy and non-bulk superconductivity nature with volume fraction ~ 20 % estimated from magnetic and heat capacity measurements. 1T-PdSeTe expands the family of superconducting transition metal dichalcogenides and thus provides additional insights for understanding superconductivity and topological physics in the 1T-PdTe$_2$ system
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We report the pressure dependence of the superconducting transition temperature, $T_c$, in TlNi$_2$Se$_{2-x}$S$_x$ detected via the AC susceptibility method. The pressure-temperature phase diagram constructed for TlNi$_{2}$Se$_{2}$, TlNi$_{2}$S$_{2}$ and TlNi$_{2}$SeS exhibits two unexpected features: (a) a sudden collapse of the superconducting state at moderate pressure for all three compositions and (b) a dome-shaped pressure dependence of $T_c$ for TlNi$_{2}$SeS. These results point to the nontrivial role of S substitution and its subtle interplay with applied pressure, as well as novel superconducting properties of the TlNi$_2$Se$_{2-x}$S$_x$ system.
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