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Register a new userDefinition of the moist-air exergy norm: a comparison with existing moist energy norms
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This study presents a new formulation for the norms and scalar products used in tangent linear or adjoint models to determine forecast errors and sensitivity to observations and to calculate singular vectors. The new norm is derived from the concept of moist-air available enthalpy, which is one of the availability functions referred to as exergy in general thermodynamics. It is shown that the sum of the kinetic energy and the moist-air available enthalpy can be used to define a new moist-air squared norm which is quadratic in: 1) wind components; 2) temperature; 3) surface pressure; and 4) water vapor content. Preliminary numerical applications are performed to show that the new weighting factors for temperature and water vapor are significantly different from those used in observation impact studies, and are in better agreement with observed analysis increments. These numerical applications confirm that the weighting factors for water vapor and temperature exhibit a large increase with height (by several orders of magnitude) and a minimum in the middle troposphere, respectively.
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The exergy of the dry atmosphere can be considered as another aspect of the meteorological theories of available energies. The local and global properties of the dry available enthalpy function, also called flow exergy, were investigated in a previous paper (Marquet, Q. J. R. Meteorol. Soc., Vol 117, p.449-475, 1991). The concept of exergy is well defined in thermodynamics, and several generalizations to chemically reacting systems have already been made. Similarly, the concept of moist available enthalpy is presented in this paper in order to generalize the dry available enthalpy to the case of a moist atmosphere. It is a local exergy-like function which possesses a simple analytical expression where only two unknown constants are to be determined, a reference temperature and a reference pressure. The moist available enthalpy, $a_m$, is defined in terms of a moist potential change in total entropy. The local function $a_m$ can be separated into temperature, pressure and latent components. The latent component is a new component that is not present in the dry case. The moist terms have been estimated using a representative cumulus vertical profile. It appears that the modifications brought by the moist formulation are important in comparison with the dry case. Other local and global properties are also investigated and comparisons are made with some other available energy functions used in thermodynamics and meteorology.
Calculations of entropy fluxes and production rate have been evaluated with some success to study atmospheric processes. However, recurring questions arise as to how best to take into account entropy flux due to radiation, for example. This article raises another kind of question: how to define the entropy of the atmosphere itself, which is composed of variable proportions of dry air (nitrogen, oxygen, argon, etc.) and water (vapour, liquid, ice). The specific values of the entropy for such a variable composition system depend on the reference values of its components. Most of the current definitions are based on entropies set at zero for dry air and liquid water at zero degrees Celsius. Differently, the third law of thermodynamics assumes that the entropy of all species cancels out for the more stable solid state at the zero of absolute temperatures. In this paper, we analyze the possible consequences of this absolute definition of entropy of moist air on the calculation of entropy fluxes. The impacts of moisture are significant and these new calculation methods seem to be able to modify the budgets of atmospheric entropy, with possible impacts on the nature of the equilibrium of the atmosphere resulting from entropic imbalances induced by radiations.
It is important to be able to calculate the moist-air entropy of the atmosphere with precision. A potential temperature has already been defined from the third law of thermodynamics for this purpose. However, a doubt remains as to whether this entropy potential temperature can be represented with simple but accurate first- or second-order approximate formulas. These approximations are rigorously defined in this paper using mathematical arguments and numerical adjustments to some datasets. The differentials of these approximations lead to simple but accurate formulations for tendencies, gradients and turbulent fluxes of the moist-air entropy. Several physical consequences based on these approximations are described and can serve to better understand moist-air processes (like turbulence or diabatic forcing) or properties of certain moist-air quantities (like the static energies).
A framework is introduced to compare moist `potential temperatures. The equivalent potential temperature, $theta_e,$ the liquid water potential temperature, $theta_ell,$ and the entropy potential temperature, $theta_s$ are all shown to be potential temperatures in the sense that they measure the temperature moist-air, in some specified state, must have to have the same entropy as the air-parcel that they characterize. They only differ in the choice of reference state composition: $theta_ell$ describes the temperature a condensate-free state, $theta_e$ a vapor-free state, and $theta_s$ a water-free state would require to have the same entropy as the given state. Although in this sense $theta_e,$ $theta_ell,$ and $theta_s$ are all different flavors of the same thing, only $theta_ell$ satisfies the stricter definition of a `potential temperature, as corresponding to a reference temperature accessible by an isentropic and closed transformation of a system in equilibrium; only $theta_e$ approximately measures the ability of moist-air to do work; and only $theta_s$ measures air-parcel entropy. None mix linearly, but all do so approximately, and all reduce to the dry potential temperature, $theta$ in the limit as the water mass fraction goes to zero. As is well known, $theta$ does mix linearly and inherits all the favorable (entropic, enthalpic, and potential temperature) properties of its various -- but descriptively less rich -- moist counterparts. All, involve quite complex expressions, but admit relatively simple and useful approximations. Of the three moist `potential temperatures, $theta_s$ is the least familiar, but the most well mixed in the broader tropics, a property that merits further study as a basis for constraining mixing processes.
Raylaigh-Benard convection is one of the most well-studied models in fluid mechanics. Atmospheric convection, one of the most important components of the climate system, is by comparison complicated and poorly understood. A key attribute of atmospheric convection is the buoyancy source provided by the condensation of water vapour, but the presence of radiation, compressibility, liquid water and ice further complicate the system and our understanding of it. In this paper we present an idealized model of moist convection by taking the Boussinesq limit of the ideal gas equations and adding a condensate that obeys a simplified Clausius--Clapeyron relation. The system allows moist convection to be explored at a fundamental level and reduces to the classical Rayleigh-Benard model if the latent heat of condensation is taken to be zero. The model has an exact, Rayleigh-number independent `drizzle solution in which the diffusion of water vapour from a saturated lower surface is balanced by condensation, with the temperature field (and so the saturation value of the moisture) determined self-consistently by the heat released in the condensation. This state is the moist analogue of the conductive solution in the classical problem. We numerically determine the linear stability properties of this solution as a function of Rayleigh number and a nondimensional latent-heat parameter. We also present a number of turbulent solutions.
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