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Register a new userThe first and second order approximations of the third-law moist-air entropy potential temperature
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Pascal Marquet
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It is important to be able to calculate the moist-air entropy of the atmosphere with precision. A potential temperature has already been defined from the third law of thermodynamics for this purpose. However, a doubt remains as to whether this entropy potential temperature can be represented with simple but accurate first- or second-order approximate formulas. These approximations are rigorously defined in this paper using mathematical arguments and numerical adjustments to some datasets. The differentials of these approximations lead to simple but accurate formulations for tendencies, gradients and turbulent fluxes of the moist-air entropy. Several physical consequences based on these approximations are described and can serve to better understand moist-air processes (like turbulence or diabatic forcing) or properties of certain moist-air quantities (like the static energies).
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Calculations of entropy fluxes and production rate have been evaluated with some success to study atmospheric processes. However, recurring questions arise as to how best to take into account entropy flux due to radiation, for example. This article raises another kind of question: how to define the entropy of the atmosphere itself, which is composed of variable proportions of dry air (nitrogen, oxygen, argon, etc.) and water (vapour, liquid, ice). The specific values of the entropy for such a variable composition system depend on the reference values of its components. Most of the current definitions are based on entropies set at zero for dry air and liquid water at zero degrees Celsius. Differently, the third law of thermodynamics assumes that the entropy of all species cancels out for the more stable solid state at the zero of absolute temperatures. In this paper, we analyze the possible consequences of this absolute definition of entropy of moist air on the calculation of entropy fluxes. The impacts of moisture are significant and these new calculation methods seem to be able to modify the budgets of atmospheric entropy, with possible impacts on the nature of the equilibrium of the atmosphere resulting from entropic imbalances induced by radiations.
A framework is introduced to compare moist `potential temperatures. The equivalent potential temperature, $theta_e,$ the liquid water potential temperature, $theta_ell,$ and the entropy potential temperature, $theta_s$ are all shown to be potential temperatures in the sense that they measure the temperature moist-air, in some specified state, must have to have the same entropy as the air-parcel that they characterize. They only differ in the choice of reference state composition: $theta_ell$ describes the temperature a condensate-free state, $theta_e$ a vapor-free state, and $theta_s$ a water-free state would require to have the same entropy as the given state. Although in this sense $theta_e,$ $theta_ell,$ and $theta_s$ are all different flavors of the same thing, only $theta_ell$ satisfies the stricter definition of a `potential temperature, as corresponding to a reference temperature accessible by an isentropic and closed transformation of a system in equilibrium; only $theta_e$ approximately measures the ability of moist-air to do work; and only $theta_s$ measures air-parcel entropy. None mix linearly, but all do so approximately, and all reduce to the dry potential temperature, $theta$ in the limit as the water mass fraction goes to zero. As is well known, $theta$ does mix linearly and inherits all the favorable (entropic, enthalpic, and potential temperature) properties of its various -- but descriptively less rich -- moist counterparts. All, involve quite complex expressions, but admit relatively simple and useful approximations. Of the three moist `potential temperatures, $theta_s$ is the least familiar, but the most well mixed in the broader tropics, a property that merits further study as a basis for constraining mixing processes.
A careful reading of old articles puts Olivier Pauluis criticisms concerning the definition of isentropic processes in terms of a potential temperature closely associated with the entropy of moist air, together with the third principle of thermodynamics, into perspective.
We extend the theory for third-order structure functions in homogeneous incompressible magnetohydrodynamic (MHD) turbulence to the case in which a constant velocity shear is present. A generalization is found of the usual relation [Politano and Pouquet, Phys. Rev. E, 57 21 (1998)] between third-order structure functions and the dissipation rate in steady inertial range turbulence, in which the shear plays a crucial role. In particular, the presence of shear leads to a third-order law which is not simply proportional to the relative separation. Possible implications for laboratory and space plasmas are discussed.
We explore the possibility to identify areas of intense patch formation from floating items due to systematic convergence of surface velocity fields by means of a visual comparison of Lagrangian Coherent Structures (LCS) and estimates of areas prone to patch formation using the concept of Finite-Time Compressibility (FTC, a generalisation of the notion of time series of divergence). The LCSs are evaluated using the Finite Time Lyapunov Exponent (FTLE) method. The test area is the Gulf of Finland (GoF) in the Baltic Sea. A basin-wide spatial average of backward FTLE is calculated for the GoF for the first time. This measure of the mixing strength displays a clear seasonal pattern. The evaluated backward FTLE features are linked with potential patch formation regions with high FTC levels. It is shown that areas hosting frequent upwelling or downwelling have consistently stronger than average mixing intensity. The combination of both methods, FTC and LCS, has the potential of being a powerful tool to identify the formation of patches of pollution at the sea surface.
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