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Register a new userPhotochemical Haze Formation in the Atmospheres of super-Earths and mini-Neptunes
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UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an important role in planetary atmospheres and may provide a source of organic material to the surface which may impact the origin or evolution of life. However, very little information is known about photochemical processes in cool, high-metallicity exoplanetary atmospheres. Previously, we investigated haze formation and particle size distribution in laboratory atmosphere simulation experiments using AC plasma as the energy source. Here, we use UV photons to initiate the chemistry rather than the AC plasma, since photochemistry driven by UV radiation is important for understanding exoplanet atmospheres. We present photochemical haze formation in current UV experiments, we investigated a range of atmospheric metallicities (100x, 1000x, and 10000x solar metallicity) at three temperatures (300 K, 400 K, and 600 K). We find that photochemical hazes are generated in all simulated atmospheres with temperature-dependent production rates: the particles produced in each metallicity group decrease as the temperature increases. The images taken with atomic force microscopy show the particle size (15-190 nm) varies with temperature and metallicity. Our laboratory experimental results provide new insight into the formation and properties of photochemical haze, which could guide exoplanet atmosphere modeling and help to analyze and interpret current and future observations of exoplanets.
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Studies of the atmospheres of hot Jupiters reveal a diversity of atmospheric composition and haze properties. Similar studies on individual smaller, temperate planets are rare due to the inherent difficulty of the observations and also to the average faintness of their host stars. To investigate their ensemble atmospheric properties, we construct a sample of 28 similar planets, all possess equilibrium temperature within 300-500K, have similar size (1-3 R_e), and orbit early M dwarfs and late K dwarfs with effective temperatures within a few hundred Kelvin of one another. In addition, NASAs Kepler/K2 and Spitzer missions gathered transit observations of each planet, producing an uniform transit data set both in wavelength and coarse planetary type. With the transits measured in Keplers broad optical bandpass and Spitzers 4.5 micron wavelength bandpass, we measure the transmission spectral slope, alpha, for the entire sample. While this measurement is too uncertain in nearly all cases to infer the properties of any individual planet, the distribution of alpha among several dozen similar planets encodes a key trend. We find that the distribution of alpha is not well-described by a single Gaussian distribution. Rather, a ratio of the Bayesian evidences between the likeliest 1-component and 2-component Gaussian models favors the latter by a ratio of 100:1. One Gaussian is centered around an average alpha=-1.3, indicating hazy/cloudy atmospheres or bare cores with atmosphere evaporated. A smaller but significant second population (20+-10% of all) is necessary to model significantly higher alpha values, which indicate atmospheres with potentially detectable molecular features. We conclude that the atmospheres of small and temperate planets are far from uniformly flat, and that a subset are particularly favorable for follow-up observation from space-based platforms like HST and JWST.
Hot super-Earths likely possess minimal atmospheres established through vapor saturation equilibrium with the ground. We solve the hydrodynamics of these tenuous atmospheres at the surface of Corot-7b, Kepler 10b and 55 Cnc-e, including idealized treatments of magnetic drag and ohmic dissipation. We find that atmospheric pressures remain close to their local saturation values in all cases. Despite the emergence of strongly supersonic winds which carry sublimating mass away from the substellar point, the atmospheres do not extend much beyond the day-night terminators. Ground temperatures, which determine the planetary thermal (infrared) signature, are largely unaffected by exchanges with the atmosphere and thus follow the effective irradiation pattern. Atmospheric temperatures, however, which control cloud condensation and thus albedo properties, can deviate substantially from the irradiation pattern. Magnetic drag and ohmic dissipation can also strongly impact the atmospheric behavior, depending on atmospheric composition and the planetary magnetic field strength. We conclude that hot super-Earths could exhibit interesting signatures in reflection (and possibly in emission) which would trace a combination of their ground, atmospheric and magnetic properties.
Spectral slopes in optical transmission spectra of exoplanetary atmospheres encapsulate information on the properties of exotic clouds. The slope is usually attributed to the Rayleigh scattering caused by tiny aerosol particles, whereas recent retrieval studies have suggested that the slopes are often steeper than the canonical Rayleigh slopes. Here, we propose that photochemical haze formed in vigorously mixing atmospheres can explain such super-Rayleigh slopes. We first analytically show that the spectral slope can be steepened by the vertical opacity gradient in which atmospheric opacity increases with altitude. Using a microphysical model, we demonstrate that such opacity gradient can be naturally generated by photochemical haze, especially when the eddy mixing is substantially efficient. The transmission spectra of hazy atmospheres can be demarcated into four typical regimes in terms of the haze mass flux and eddy diffusion coefficient. We find that the transmission spectrum can have the spectral slope 2--4 times steeper than the Rayleigh slope if the eddy diffusion coefficient is sufficiently high and the haze mass flux falls into a moderate value. Based on the eddy diffusion coefficient suggested by a recent study of atmospheric circulations, we suggest that photochemical haze preferentially generates super-Rayleigh slopes at planets with equilibrium temperature of 1000--1500 K, which might be consistent with results of recent retrieval studies. Our results would help to interpret the observations of spectral slopes from the perspective of haze formation.
Spectral characterization of Super-Earth atmospheres for planets orbiting in the Habitable Zone of M-dwarf stars is a key focus in exoplanet science. A central challenge is to understand and predict the expected spectral signals of atmospheric biosignatures (species associated with life). Our work applies a global-mean radiative-convective-photochemical column model assuming a planet with an Earth-like biomass and planetary development. We investigated planets with gravities of 1g and 3g and a surface pressure of one bar around central stars with spectral classes from M0 to M7. The spectral signals of the calculated planetary scenarios have been presented by Rauer et al. (2011). The main motivation of the present work is to perform a deeper analysis of the chemical processes in the planetary atmospheres. We apply a diagnostic tool, the Pathway Analysis Program, to shed light on the photochemical pathways that form and destroy biosignature species. Ozone is a potential biosignature for complex- life. An important result of our analysis is a shift in the ozone photochemistry from mainly Chapman production (which dominates in the terrestrial stratosphere) to smog-dominated ozone production for planets in the Habitable Zone of cooler (M5-M7)-class dwarf stars. This result is associated with a lower energy flux in the UVB wavelength range from the central star, hence slower planetary atmospheric photolysis of molecular oxygen, which slows the Chapman ozone production.
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 and 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20 to 140 nm) and relative low production rate (2.4 x 10-5 to 9.7 x 10-5 mg cm-3 h-1), but the particle size and production rate is dependent on the initial gas mixtures and the energy sources used in the simulation experiments. The gas phase mass spectra show that complex chemical processes happen in these atmospheres and generate new gas products that can further react to form larger molecules and solid haze particles. Two H2-rich atmospheres with similar C/O ratios (~0.5) yield different haze particles size, haze production rate, and gas products, suggesting both the elemental abundances and their bonding environments in an atmosphere can significantly affect the photochemistry. There is no methane (CH4) in our initial gas mixtures, although CH4 is often believed to be required to generate organic hazes. However, haze production rates from our experiments with different initial gas mixtures indicate that CH4 is neither required to generate organic hazes nor necessary to promote the organic haze formation. The variety and relative yield of the gas products indicate that CO and N2 enrich chemical reactions in H2-rich atmospheres.
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