Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userTetraphenyl Butadiene Emanation and Bulk Fluorescence from Wavelength Shifting Coatings in Liquid Argon
70
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We study the stability of three types of popularly employed TPB coatings under immersion in liquid argon. TPB emanation from each coating is quantified by fluorescence assay of molecular sieve filter material after a prolonged soak time. Two of the coatings are shown to emanate a detectable concentration of TPB into argon over a 24 hour period, which corresponds to tens of parts per billion in argon by mass. In an independent setup, the dissolved or suspended TPB is shown to produce a wavelength shifting effect in the argon bulk. Interpretations of these results and implications for present and future liquid argon time projection chamber experiments are discussed.
rate research
Read More
We report on studies of degradation mechanisms of tetraphenyl butadiene (TPB) coatings of the type used in neutrino and dark matter liquid argon experiments. Using gas chromatography coupled to mass spectrometry we have detected the ultraviolet-blocking impurity benzophenone (BP). We monitored the drop in performance and increase of benzophenone concentration in TPB plates with exposure to ultraviolet (UV) light, and demonstrate the correlation between these two variables. Based on the presence and initially exponential increase in the concentration of benzophenone observed, we propose that TPB degradation is a free radical-mediated photooxidation reaction, which is subsequently confirmed by displaying delayed degradation using a free radical inhibitor. Finally we show that the performance of wavelength-shifting coatings of the type envisioned for the LBNE experiment can be improved by 10-20%, with significantly delayed UV degradation, by using a 20% admixture of 4-tert-Butylcatechol.
TetraPhenyl Butadiene is the wavelength shifter most widely used in combination with liquid Argon. The latter emits scintillation photons with a wavelength of 127 nm that need to be downshifted to be detected by photomultipliers with glass or quartz windows. TetraPhenyl Butadiene has been demonstrated to have an extremely high conversion efficiency, possibly higher than 100 % for 127 nm photons, while there is no precise information about the time dependence of its emission. It is usually assumed to be exponentially decaying with a characteristic time of the order of one ns, as an extrapolation from measurements with exciting radiation in the near UV. This work shows that TetraPhenyl Butadiene, when excited by 127 nm photons, reemits photons not only with a very short decay time, but also with slower ones due to triplet states de-excitations. This fact can strongly contribute to clarify the anomalies in liquid Argon scintillation light reported in literature since seventies, namely the inconsistency in the measured values of the long decay time constant and the appearance of an intermediate component. Similar effects should be also expected when the TPB is used in combination with Helium and Neon, that emit scintillation photons with wavelengths shorter than 127 nm.
To increase the light yield of a liquid Ar (LAr) detector, we optimized the evaporation technique of tetraphenyl butadiene (TPB) on the detector surface and tested the operability of a silicon photomultiplier (SiPM), namely, the multi-pixel photon counter with through-silicon-via (TSV-MPPC, Hamamatsu Photonics K.K.) at LAr temperature. TPB converts the LAr scintillations (vacuum ultraviolet light) to visible light, which can be detected by high-sensitivity photosensors. Because the light yield depends on the deposition mass of TPB on the inner surface of the detector, we constructed a well-controlled TPB evaporator to ensure reproducibility and measured the TPB deposition mass using a quartz crystal microbalance sensor. After optimizing the deposition mass of TPB (30 $mu g/cm^2$ on the photosensor window and 40 $mu g/cm^2$ on the detector wall), the light yield was 12.8 $pm$ 0.3 p.e./keVee using PMTs with a quantum efficiency of approximately 30% for TPB-converted light. We also tested the low-temperature tolerance of TSV-MPPC, which has a high photon-detection efficiency, in the LAr environment. The TSV-MPPC detected the LAr scintillations converted by TPB with a photon-detection efficiency exceeding 50%.
The use of efficient wavelength-shifters from the vacuum-ultraviolet to the photosensors range of sensitivity is a key feature in detectors for Dark Matter search and neutrino physics based on liquid argon scintillation detection. Thin film of Tetraphenyl-butadiene (TPB) deposited onto the surface delimiting the active volume of the detector and/or onto the photosensor optical window is the most common solution in current and planned experiments. Detector design and response can be evaluated and correctly simulated only when the properties of the optical system in use (TPB film + substrate) are fully understood. Characterization of the optical system requires specific, sometimes sophisticated optical methodologies. In this paper the main features of TPB coatings on different, commonly used substrates is reported, as a result of two independent campaigns of measurements at the specialized optical metrology labs of ENEA and University of Tor Vergata. Measured features include TPB emission spectra with lineshape and relative intensity variation recorded as a function of the film thickness and for the first time down to LAr temperature, as well as optical reflectance and transmittance spectra of the TPB coated substrates in the wavelength range of the TPB emission.
The scintillation detection systems of liquid argon time projection chambers (LArTPCs) require wavelength shifters to detect the 128 nm scintillation light produced in liquid argon. Tetraphenyl butadiene (TPB) is a fluorescent material that can shift this light to a wavelength of 425 nm, lending itself well to use in these detectors. We can coat the glass of photomultiplier tubes (PMTs) with TPB or place TPB-coated plates in front of the PMTs. In this paper, we investigate the degradation of a chemical TPB coating in a laboratory or factory environment to assess the viability of long-term TPB film storage prior to its initial installation in an LArTPC. We present evidence for severe degradation due to common fluorescent lights and ambient sunlight in laboratories, with potential losses at the 40% level in the first day and eventual losses at the 80% level after a month of exposure. We determine the degradation is due to wavelengths in the UV spectrum, and we demonstrate mitigating methods for retrofitting lab and factory environments.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
