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Register a new userThe Belgian repository of fundamental atomic data and stellar spectra (BRASS). I. Cross-matching atomic databases of astrophysical interest
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Fundamental atomic parameters, such as oscillator strengths, play a key role in modelling and understanding the chemical composition of stars in the universe. Despite the significant work underway to produce these parameters for many astrophysically important ions, uncertainties in these parameters remain large and can propagate throughout the entire field of astronomy. The Belgian repository of fundamental atomic data and stellar spectra (BRASS) aims to provide the largest systematic and homogeneous quality assessment of atomic data to date in terms of wavelength, atomic and stellar parameter coverage. To prepare for it, we first compiled multiple literature occurrences of many individual atomic transitions, from several atomic databases of astrophysical interest, and assessed their agreement. Several atomic repositories were searched and their data retrieved and formatted in a consistent manner. Data entries from all repositories were cross-matched against our initial BRASS atomic line list to find multiple occurrences of the same transition. Where possible we used a non-parametric cross-match depending only on electronic configurations and total angular momentum values. We also checked for duplicate entries of the same physical transition, within each retrieved repository, using the non-parametric cross-match. We report the cross-matched transitions for each repository and compare their fundamental atomic parameters. We find differences in log(gf) values of up to 2 dex or more. We also find and report that ~2% of our line list and Vienna Atomic Line Database retrievals are composed of duplicate transitions. Finally we provide a number of examples of atomic spectral lines with different log(gf) values, and discuss the impact of these uncertain log(gf) values on quantitative spectroscopy. All cross-matched atomic data and duplicate transitions are available to download at brass.sdf.org.
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Fundamental atomic transition parameters, such as oscillator strengths and wavelengths, play a key role in modelling and understanding the chemical composition of stars in the universe. Despite the significant work under way to produce these parameters for many ions, uncertainties in these parameters remain large and can limit the accuracy of chemical abundance determinations. The Belgian repository of fundamental atomic data and stellar spectra (BRASS) aims to provide a large systematic and homogeneous quality assessment of the atomic data available for quantitative spectroscopy. BRASS shall compare synthetic spectra against extremely high quality observed spectra, at a resolution of ~85000 and signal-noise ratios of ~1000, for around 20 bright BAFGK spectral type stars, in order to evaluate the atomic data available for over a thousand potentially useful spectral lines. A large-scale homogeneous selection of atomic lines is performed by synthesising theoretical spectra of literature atomic lines, for FGK-type stars including the Sun, resulting in a selection of 1091 theoretically deep and unblended lines, in the wavelength range 4200-6800~AA, which may be suitable for quality assessment. Astrophysical log(gf) values are determined for the 1091 transitions using two commonly employed methods. The agreement of these log(gf) values are used to select well-behaving lines for quality assessment. 845 atomic lines were found to be suitable for quality assessment, of which 408 were found to be robust against systematic differences between analysis methods. Around 54% of the quality-assessed lines were found to have at least one literature log(gf) value in agreement with our derived values, though the remaining values can disagree by as much as 0.5 dex. Only 38% of FeI lines were found to have sufficiently accurate log(gf) values, increasing to ~70-75% for the remaining Fe-group lines.
A review of a renewed effort to recalculate astrophysical opacities using the R-Matrix method is presented. The computational methods and new extensions are described. Resulting enhancements found in test calculations under stellar interior conditions compared to the Opacity Project could potentially lead to the resolution of the solar abundances problem, as well as discrepancies between recent experimental measurements at the Sandia Z-pinch inertial confinement fusion device and theoretical opacity models. Outstanding issues also discussed are: (i) accuracy, convergence, and completeness of atomic calculations, (ii) improvements in the Equation-of-State of high-temperature-density plasmas, and (iii) redistribution of resonant oscillator strength in the bound-free continuum, and (iv) plasma broadening of auotionizing resonances.
We develop a new method to determine oscillator strength values of atomic absorption lines with state-of-the-art detailed spectral synthesis calculations of the optical spectrum of the Sun and of standard spectral reference stars. We update the log(gf)-values of 911 neutral lines observed in the KPNO-FTS flux spectrum of the Sun and high-resolution echelle spectra (R=80,000) of Procyon (F5 IV-V) and {epsilon} Eri (K2 V) observed with large signal-to-noise (S/N) ratios of ~2,000 using the new Mercator-Hermes spectrograph at La Palma Observatory (Spain). We find for 483 Fe I, 85 Ni I, and 51 Si I absorption lines in the sample a systematic over-estimation of the literature log(gf)-values with central line depths below 15 %. We employ a curve-of-growth analysis technique to test the accuracy of the new oscillator strength values and compare calculated equivalent line widths to the Moore, Minnaert, & Houtgast atlas of the Sun. The online SpectroWeb database at http://spectra.freeshell.org interactively displays the observed and synthetic spectra and provides the new log(gf)-values together with important atomic line data. The graphical database is under development for stellar reference spectra of every spectral sub-class observed with large spectral resolution and S/N ratios.
Accurate rates for energy-degenerate l-changing collisions are needed to determine cosmological abundances and recombination. There are now several competing theories for the treatment of this process, and it is not possible to test these experimentally. We show that the H I two-photon continuum produced by astrophysical nebulae is strongly affected by l-changing collisions. We perform an analysis of the different underlying atomic processes and simulate the recombination and two-photon spectrum of a nebula containing H and He. We provide an extended set of effective recombination coefficients and updated l-changing 2s-2p transition rates using several competing theories. In principle, accurate astronomical observations could determine which theory is correct.
We consider three recent large-scale calculations for the radiative and electron-impact excitation data of N IV, carried out with different methods and codes. The scattering calculations employed the relativistic Dirac $R$-matrix (DARC) method, the intermediate coupling frame transformation (ICFT) $R$-matrix method, and the B-spline $R$-matrix (BSR) method. These are all large-scale scattering calculations with well-tested and sophisticated codes, which use the same set of target states. One concern raised in previous literature is related to the increasingly large discrepancies in the effective collision strengths between the three sets of calculations for increasingly weak and/or high-lying transitions. We have built three model ions and calculated the intensities of all the main spectral lines in this ion. We have found that, despite such large differences, excellent agreement (to within $pm$~20%) exists between all the spectroscopically-relevant line intensities. This provides confidence in the reliability of the calculations for plasma diagnostics. We have used the differences in the radiative and excitation rates amongst the three sets of calculations to obtain a measure of the uncertainty in each rate. Using a Monte Carlo approach, we have shown how these uncertainties affect the main theoretical ratios which are used to measure electron densities and temperatures.
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