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Register a new userTheoretical transmission spectra of exoplanet atmospheres with hydrocarbon haze: Effect of creation, growth, and settling of haze particles. I. Model description and first results
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Recently, properties of exoplanet atmospheres have been constrained via multi-wavelength transit observation, which measures an apparent decrease in stellar brightness during planetary transit in front of its host star (called transit depth). Sets of transit depths so far measured at different wavelengths (called transmission spectra) are somewhat diverse: Some show steep spectral slope features in the visible, some contain featureless spectra in the near-infrared, some show distinct features from radiative absorption by gaseous species. These facts infer the existence of haze in the atmospheres especially of warm, relatively low-density super-Earths and mini-Neptunes. Previous studies that addressed theoretical modeling of transmission spectra of hydrogen-dominated atmospheres with haze used some assumed distribution and size of haze particles. In this study, we model the atmospheric chemistry, derive the spatial and size distributions of haze particles by simulating the creation, growth and settling of hydrocarbon haze particles directly, and develop transmission spectrum models of UV-irradiated, solar-abundance atmospheres of close-in warm ($sim$ 500 K) exoplanets. We find that the haze is distributed in the atmosphere much more broadly than previously assumed and consists of particles of various sizes. We also demonstrate that the observed diversity of transmission spectra can be explained by the difference in the production rate of haze monomers, which is related to the UV irradiation intensity from host stars.
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Recent transmission spectroscopy has revealed that clouds and hazes are common in the atmospheres of close-in exoplanets. In this study, using the photochemical, microphysical, and transmission spectrum models for close-in warm ($lesssim$ 1000 K) exoplanet atmospheres that we newly developed in our preceding paper (Kawashima & Ikoma 2018), we investigate the vertical distributions of haze particles and gaseous species and the resultant transmission spectra over wide ranges of the model parameters including UV irradiation intensity, metallicity, carbon-to-oxygen ratio (C/O), eddy diffusion coefficient, and temperature. The sensitivity to metallicity is of particular interest. We find that a rise in metallicity leads basically to reducing the photodissociation rates of the hydrocarbons and therefore the haze monomer production rates. This is due to an enhanced photon-shielding effect by the major photon absorbers such as $mathrm{H_2O}$, $mathrm{CO}$, $mathrm{CO_2}$, and $mathrm{O_2}$, existing at higher altitudes than the hydrocarbons. We also find that at relatively short wavelengths ($lesssim$ 2-3 $mu$m), the absorption features in transmission spectra are most pronounced for moderate metallicities such as 100 times the solar metallicity, whereas the lower the metallicity the stronger the absorption features at relatively long wavelengths ($gtrsim$ 2-3 $mu$m), where the contribution of haze is small. These are because of the two competing effects of reduced haze production rate and atmospheric scale height for higher metallicities. For the other model parameters, we show that stronger absorption features appear in transmission spectra of the atmospheres with lower UV irradiation, lower C/O ratio, higher eddy diffusion coefficient, and higher temperature.
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 and 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20 to 140 nm) and relative low production rate (2.4 x 10-5 to 9.7 x 10-5 mg cm-3 h-1), but the particle size and production rate is dependent on the initial gas mixtures and the energy sources used in the simulation experiments. The gas phase mass spectra show that complex chemical processes happen in these atmospheres and generate new gas products that can further react to form larger molecules and solid haze particles. Two H2-rich atmospheres with similar C/O ratios (~0.5) yield different haze particles size, haze production rate, and gas products, suggesting both the elemental abundances and their bonding environments in an atmosphere can significantly affect the photochemistry. There is no methane (CH4) in our initial gas mixtures, although CH4 is often believed to be required to generate organic hazes. However, haze production rates from our experiments with different initial gas mixtures indicate that CH4 is neither required to generate organic hazes nor necessary to promote the organic haze formation. The variety and relative yield of the gas products indicate that CO and N2 enrich chemical reactions in H2-rich atmospheres.
Having a short orbital period and being tidally locked makes WASP-43b an ideal candidate for JWST observations. Phase curve observations of an entire orbit will enable the mapping of the atmospheric structure across the planet, with different wavelengths of observation allowing different atmospheric depths to be seen. We provide insight into the details of the clouds that may form on WASP-43b in order to prepare the forthcoming interpretation of the JWST and follow-up data. We utilize 3D GCM results as input for a kinetic, non-equilibrium model for mineral cloud particles, and for a kinetic model to study a photochemicaly-driven hydrocarbon haze component. Mineral condensation seeds form throughout the atmosphere of WASP-43b. This is in stark contrast to the ultra-hot Jupiters, like WASP-18b and HAT-P-7b. The dayside is loaded with few but large mineral cloud particles in addition to hydrocarbon haze particles of comparable abundance. Photochemically driven hydrocarbon haze appears on the dayside, but does not contribute to the cloud formation on the nightside. The geometrical cloud extension differs across the globe due to the changing thermodynamic conditions. Day and night differ by 6000km in pressure scale height. As reported for other planets, the C/O is not constant throughout the atmosphere. The mean molecular weight is approximately constant in a H2-dominated WASP-43b. WASP-43b is expected to be fully covered in clouds which are not homogeneously distributed throughout the atmosphere. The dayside and the terminator clouds will be a combination of mineral particles of locally varying size and composition, and of hydrocarbon hazes. The optical depth of hydrocarbon hazes is considerably lower than that of mineral cloud particles such that a wavelength-dependent radius measurement of WASP-43b would be determined by the mineral cloud particles but not by hazes.
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood due to a lack of chemical-kinetics information for sulfur species under relevant conditions. Here, we study the photochemical role of hydrogen sulfide (H2S) in warm CO2-rich exoplanet atmospheres (800 K) by carrying out laboratory simulations. We find that H2S plays a significant role in photochemistry, even when present in the atmosphere at relatively low concentrations (1.6%). It participates in both gas and solid phase chemistry, leading to the formation of other sulfur gas products (CH3SH/SO, C2H4S/OCS, SO2/S2, and CS2) and to an increase in solid haze particle production and compositional complexity. Our study shows that we may expect thicker haze with small particle sizes (20 to 140 nm) for warm CO2-rich exoplanet atmospheres that possess H2S.
Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between haze production and removal. However, the material-dependent removal physics of the haze particles is currently unknown under exoplanetary conditions. Here we provide experimentally-measured surface energies for a grid of temperate exoplanet hazes to characterize haze removal in exoplanetary atmospheres. We found large variations of surface energies for hazes produced under different energy sources, atmospheric compositions, and temperatures. The surface energies of the hazes were found to be the lowest around 400 K for the cold plasma samples, leading to the lowest removal rates. We show a suggestive correlation between haze surface energy and atmospheric haziness with planetary equilibrium temperature. We hypothesize that habitable zone exoplanets could be less hazy, as they would possess high-surface-energy hazes which can be removed efficiently.
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