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Circumstellar ammonia in oxygen-rich evolved stars

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 Added by Ka Tat Wong
 Publication date 2017
  fields Physics
and research's language is English




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The circumstellar ammonia (NH$_3$) chemistry in evolved stars is poorly understood. Previous observations and modelling showed that NH$_3$ abundance in oxygen-rich stars is several orders of magnitude above that predicted by equilibrium chemistry. In this article, we characterise the spatial distribution and excitation of NH$_3$ in the O-rich circumstellar envelopes (CSEs) of four diverse targets: IK Tau, VY CMa, OH 231.8+4.2, and IRC +10420 with multi-wavelength observations. We observed the 1.3-cm inversion line emission with the Very Large Array (VLA) and submillimetre rotational line emission with the Heterodyne Instrument for the Far-Infrared (HIFI) aboard Herschel from all four targets. For IK Tau and VY CMa, we observed the rovibrational absorption lines in the $ u_2$ band near 10.5 $mu$m with the Texas Echelon Cross Echelle Spectrograph (TEXES) at the NASA Infrared Telescope Facility (IRTF). We also attempted to search for the rotational transition within the $v_2=1$ state near 2 mm with the IRAM 30m Telescope towards IK Tau. Non-LTE radiative transfer modelling, including radiative pumping to the vibrational state, was carried out to derive the radial distribution of NH$_3$ in these CSEs. Our modelling shows that the NH$_3$ abundance relative to molecular hydrogen is generally of the order of $10^{-7}$, which is a few times lower than previous estimates that were made without considering radiative pumping and is at least 10 times higher than that in the C-rich CSE of IRC +10216. Incidentally, we also derived a new period of IK Tau from its $V$-band light curve. NH$_3$ is again detected in very high abundance in O-rich CSEs. Its emission mainly arises from localised spatial-kinematic structures that are probably denser than the ambient gas. Circumstellar shocks in the accelerated wind may contribute to the production of NH$_3$. (Abridged abstract)



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The HIFI instrument on board of the Herschel Space Observatory (HSO) has been very successful in detecting molecular lines from circumstellar envelopes around evolved stars, like massive red supergiants, Asymptotic Giant Branch (AGB) and post-AGB stars, as well as planetary nebulae. Among others, ammonia has been found in circumstellar envelopes of C-rich AGB stars in amounts that significantly exceeded theoretical predictions for C-rich stars. Few scenarios have been proposed to resolve this problem: formation of ammonia behind the shock front, photochemical processes in the inner part of the envelope partly transparent to UV background radiation due to the clumpy structure of the gas, and formation of ammonia on dust grains. Careful analysis of observations may help to put constraints on one or another mechanism of ammonia formation. Here, we present results of the non-LTE radiative transfer modeling of ammonia transitions including a crucial process of radiative pumping via v$_2$ = 1 vibrational band (at $sim$10 $mu$m) for V Cyg. Only ground-based ammonia transition NH$_{3}$ J = 1$_{0}$ - 0$_{0}$ at 572.5 GHz has been observed by HIFI. Therefore, to determine abundance of ammonia we estimate a photodissociation radius of NH$_{3}$ using chemical model of the envelope consistent with dust grain properties concluded from the spectral energy distribution.
In order to determine the composition of the dust in the circumstellar envelopes of oxygen-rich asymptotic giant branch (AGB) stars we have computed a grid of modust radiative-transfer models for a range of dust compositions, mass-loss rates, dust shell inner radii and stellar parameters. We compare the resulting colours with the observed oxygen-rich AGB stars from the SAGE-Spec Large Magellanic Cloud (LMC) sample, finding good overall agreement for stars with a mid-infrared excess. We use these models to fit a sample of 37 O-rich AGB stars in the LMC with optically thin circumstellar envelopes, for which 5$-$35-$mu$m Spitzer infrared spectrograph (IRS) spectra and broadband photometry from the optical to the mid-infrared are available. From the modelling, we find mass-loss rates in the range $sim 8times10^{-8}$ to $5times10^{-6}$ M$_{odot} mathrm{yr}^{-1}$, and we show that a grain mixture consisting primarily of amorphous silicates, with contributions from amorphous alumina and metallic iron provides a good fit to the observed spectra. Furthermore, we show from dust models that the AKARI [11]$-$[15] versus [3.2]$-$[7] colour-colour diagram, is able to determine the fractional abundance of alumina in O-rich AGB stars.
Aluminium monoxide, AlO, is likely efficiently depleted from the gas around oxygen-rich evolved stars to form alumina clusters and dust seeds. Its presence in the extended atmospheres of evolved stars has been derived from optical spectroscopy. More recently, AlO gas was also detected at long wavelengths around the supergiant VY CMa and the oxygen-rich asymptotic giant branch (AGB) star o Cet (Mira A). In search of AlO, we mined data obtained with APEX, the IRAM 30m telescope, Herschel/HIFI, SMA, and ALMA, which were primarily aimed at studying other molecular species. We report here on observations of AlO towards a sample of eight oxygen-rich AGB stars in different rotational transitions, up to seven for some stars. We present definite detections of one rotational transition of AlO for o Cet and R Aqr, and tentative detections of one transition for R Dor and o Cet, and two for IK Tau and W Hya. The presented spectra of WX Psc, R Cas, and TX Cam show no signature of AlO. For o Cet, R Aqr, and IK Tau, we find that the AlO(N=9-8) emission likely traces the inner parts of the wind, out to only a few tens of AU, where the gas has not yet reached its terminal velocity. The conclusive detections of AlO emission in the case of o Cet and R Aqr confirm the presence of AlO gas in outflows of AGB stars. The tentative detections further support this. Since most of the observations presented in this study were obtained with stronger emission from other species than AlO in mind, observations with higher sensitivity in combination with high angular resolution will improve our understanding of the presence and behaviour of AlO. From the current data sets we cannot firmly conclude whether there is a direct correlation between the wind properties and the detection rate of AlO emission. We hope that this study can serve as a stimulus to perform sample studies in search of AlO in oxygen-rich outflows.
Rotational transitions in vibrationally excited AlO and TiO -- two possible precursors of dust -- were observed in the 300 GHz range (1 mm wavelength) towards the oxygen rich AGB stars R Dor and IK Tau with ALMA, and vibrationally excited AlO was observed towards the red supergiant VY CMa with the SMA. The $J=11 to 10$ transition of TiO in the $v=1~{rm{and}}~2$ levels, and the $N = 9 to 8$ transition in the $v=2$ level of AlO were identified towards R Dor; the $J=11 to 10$ line of TiO was identified in the $v=1$ level towards IK Tau; and two transitions in the $v=1~{rm{and}}~2$ levels of AlO were identified towards VY CMa. The newly-derived high vibrational temperature of TiO and AlO in R Dor of $1800 pm 200$ K, and prior measurements of the angular extent confirm that the majority of the emission is from a region within $lesssim2R_{star}$ of the central star. A full radiative transfer analysis of AlO in R Dor yielded a fractional abundance of $sim$3% of the solar abundance of Al. From a similar analysis of TiO a fractional abundance of $sim78$% of the solar abundance of Ti was found. The observations provide indirect evidence that TiO is present in a rotating disk close to the star. Further observations in the ground and excited vibrational levels are needed to determine whether AlO, TiO, and TiO$_2$ are seeds of the Al$_2$O$_3$ dust in R Dor, and perhaps in the gravitationally bound dust shells in other AGB stars with low mass loss rates.
For decades ever since the early detection in the 1990s of the emission spectral features of crystalline silicates in oxygen-rich evolved stars, there is a long-standing debate on whether the crystallinity of the silicate dust correlates with the stellar mass loss rate. To investigate the relation between the silicate crystallinities and the mass loss rates of evolved stars, we carry out a detailed analysis of 28 nearby oxygen-rich stars. We derive the mass loss rates of these sources by modeling their spectral energy distributions from the optical to the far infrared. Unlike previous studies in which the silicate crystallinity was often measured in terms of the crystalline-to-amorphous silicate mass ratio, we characterize the silicate crystallinities of these sources with the flux ratios of the emission features of crystalline silicates to that of amorphous silicates. This does not require the knowledge of the silicate dust temperatures which are the major source of uncertainties in estimating the crystalline-to-amorphous silicate mass ratio. With a Pearson correlation coefficient of ~0.24, we find that the silicate crystallinities and the mass loss rates of these sources are not correlated. This supports the earlier findings that the dust shells of low mass-loss rate stars can contain a significant fraction of crystalline silicates without showing the characteristic features in their emission spectra.
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