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Register a new userReemergence of high-Tc superconductivity in the (Li1-xFex)OHFe1-ySe under high pressure
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The pressure-induced reemergence of the second high-Tc superconducting phase (SC-II) in the alkali-metal intercalated AxFe2-ySe2 (A = K, Rb, Cs, Tl) remains an enigma and proper characterizations on the superconducting- and normal-state properties of the SC-II phase were hampered by the intrinsic inhomogeneity and phase separation. To elucidate this intriguing problem, we performed a detailed high-pressure magnetotransport study on the recently discovered (Li1-xFex)OHFe1-ySe single crystals, which have high Tc~40 K and share similar Fermi surface topology as AxFe2-ySe2, but are free from the sample complications. We found that the ambient-pressure Tc~41 K is suppressed gradually to below 2 K upon increasing pressure to Pc ~5 GPa, above which a SC-II phase with higher Tc emerges and the Tc increases progressively to above 50 K up to 12.5 GPa. Interestingly, our high-precision resistivity data enable us to uncover the sharp transition of the normal state from a Fermi liquid for SC-I phase (0 < P < 5 GPa) to a non-Fermi-liquid for SC-II phase (P > 5GPa). In addition, the reemergence of high-Tc SC-II phase is found to accompany with a concurrent enhancement of electron carrier density. Since high-pressure structural study based on the synchrotron X-ray diffraction rules out the structural transition below 10 GPa, the observed SC-II phase with enhanced carrier density should be ascribed to an electronic origin associated with a pressure-induced Fermi surface reconstruction.
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Hydrothermal synthesis is described of layered lithium iron selenide hydroxides Li1-xFex(OH)Fe1-ySe (x ~ 0.2; 0.02 < y < 0.15) with a wide range of iron site vacancy concentrations in the iron selenide layers. This iron vacancy concentration is revealed as the only significant compositional variable and as the key parameter controlling the crystal structure and the electronic properties. Single crystal X-ray diffraction, neutron powder diffraction and X-ray absorption spectroscopy measurements are used to demonstrate that superconductivity at temperatures as high as 40 K is observed in the hydrothermally synthesised samples when the iron vacancy concentration is low (y < 0.05) and when the iron oxidation state is reduced slightly below +2, while samples with a higher vacancy concentration and a correspondingly higher iron oxidation state are not superconducting. The importance of combining a low iron oxidation state with a low vacancy concentration in the iron selenide layers is emphasised by the demonstration that reductive post-synthetic lithiation of the samples turns on superconductivity with critical temperatures exceeding 40 K by displacing iron atoms from the Li1-xFex(OH) reservoir layer to fill vacancies in the selenide layer
Iron pnictides are the only known family of unconventional high-temperature superconductors besides cuprates. Until recently, it was widely accepted that superconductivity is spin-fluctuation driven and intimately related to their fermiology, specifically, hole and electron pockets separated by the same wave vector that characterizes the dominant spin fluctuations, and supporting order parameters (OP) of opposite signs. This picture was questioned after the discovery of a new family, based on the FeSe layers, either intercalated or in the monolayer form. The critical temperatures there reach ~40 K, the same as in optimally doped bulk FeSe - despite the fact that intercalation removes the hole pockets from the Fermi level and, seemingly, undermines the basis for the spin-fluctuation theory and the idea of a sign-changing OP. In this paper, using the recently proposed phase-sensitive quasiparticle interference technique, we show that in LiOH intercalated FeSe compound the OP does change sign, albeit within the electronic pockets, and not between the hole and electron ones. This result unifies the pairing mechanism of iron based superconductors with or without the hole Fermi pockets and supports the conclusion that spin fluctuations play the key role in electron pairing.
Electrical resistivity measurements under high pressures up to 29 GPa were performed for oxypnictide compound LaFeAsO. We found a pressure-induced superconductivity in LaFeAsO. The maximum value of Tc is 21 K at ~12 GPa. The pressure dependence of the Tc is similar to those of LaFeAsO1-xFx series reported previously.
We have studied the structural and superconducting properties of tetragonal FeSe under pressures up to 26GPa using synchrotron radiation and diamond anvil cells. The bulk modulus of the tetragonal phase is 28.5(3)GPa, much smaller than the rest of Fe based superconductors. At 12GPa we observe a phase transition from the tetragonal to an orthorhombic symmetry. The high pressure orthorhombic phase has a higher Tc reaching 34K at 22GPa.
The long-sought goal of room-temperature superconductivity has reportedly recently been realized in a carbonaceous sulfur hydride compound under high pressure, as reported by Snider et al. [1]. The evidence presented in that paper is stronger than in other similar recent reports of high temperature superconductivity in hydrides under high pressure [2-7], and has been received with universal acclaim [8-10]. Here we point out that features of the experimental data shown in Ref. [1] indicate that the phenomenon observed in that material is not superconductivity. This observation calls into question earlier similar claims of high temperature conventional superconductivity in hydrides under high pressure based on similar or weaker evidence [2-7].
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