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Register a new userOn the Energetics of the HCO$^+$ + C $to$ CH$^+$ + CO Reaction and Some Astrochemical Implications
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We explore the energetics of the titular reaction, which current astrochemical databases consider open at typical dense molecular (i.e., dark) cloud conditions. As is common for reactions involving the transfer of light particles, we assume that there are no intersystem crossings of the potential energy surfaces involved. In the absence of any such crossings, we find that this reaction is endoergic and will be suppressed at dark cloud temperatures. Updating accordingly a generic astrochemical model for dark clouds changes the predicted gas-phase abundances of 224 species by greater than a factor of 2. Of these species, 43 have been observed in the interstellar medium. Our findings demonstrate the astrochemical importance of determining the role of intersystem crossings, if any, in the titular reaction.
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The CH$^+$ ion is a key species in the initial steps of interstellar carbon chemistry. Its formation in diverse environments where it is observed is not well understood, however, because the main production pathway is so endothermic (4280 K) that it is unlikely to proceed at the typical temperatures of molecular clouds. We investigation CH$^+$ formation with the first velocity-resolved spectral mapping of the CH$^+$ $J=1-0, 2-1$ rotational transitions, three sets of CH $Lambda$-doubled triplet lines, $^{12}$C$^+$ and $^{13}$C$^+$, and CH$_3$OH 835~GHz E-symmetry Q branch transitions, obtained with Herschel/HIFI over $approx$12 arcmin$^2$ centered on the Orion BN/KL source. We present the spatial morphologies and kinematics, cloud boundary conditions, excitation temperatures, column densities, and $^{12}$C$^+$ optical depths. Emission from C$^+$, CH$^+$, and CH is indicated to arise in the diluted gas, outside of the explosive, dense BN/KL outflow. Our models show that UV-irradiation provides favorable conditions for steady-state production of CH$^+$ in this environment. Surprisingly, no spatial or kinematic correspondences of these species are found with H$_2$ S(1) emission tracing shocked gas in the outflow. We propose that C$^+$ is being consumed by rapid production of CO to explain the lack of C$^+$ and CH$^+$ in the outflow, and that fluorescence provides the reservoir of H$_2$ excited to higher ro-vibrational and rotational levels. Hence, in star-forming environments containing sources of shocks and strong UV radiation, a description of CH$^+$ formation and excitation conditions is incomplete without including the important --- possibly dominant --- role of UV irradiation.
We study the metallicity dependence of the H/H$_2$ and C$^+$/C/CO distributions in a self-regulated interstellar medium (ISM) across a broad range of metallicities ($0.1 < Z/Z_odot < 3$). To this end, we conduct high-resolution (particle mass of $1 {rm M_odot}$) hydrodynamical simulations coupled with a time-dependent H$_2$ chemistry network. The results are then post-processed with an accurate chemistry network to model the associated C$^+$/C/CO abundances, based on the time-dependent non-steady-state (``non-equilibrium) H$_2$ abundances. We find that the time-averaged star formation rate and the ISM structure are insensitive to metallicity. The column densities relevant for molecular shielding appear correlated with the volume densities in gravitationally unstable gas. As metallicity decreases, H$_2$ progressively deviates from steady state (``equilibrium) and shows shallow abundance profiles until they sharply truncate at the photodissociation fronts. In contrast, the CO profile is sharp and controlled by photodissociation as CO quickly reaches steady state. We construct effective one-dimensional cloud models that successfully capture the time-averaged chemical distributions in simulations. At low metallicities, the steady-state model significantly overestimates the abundance of H$_2$ in the diffuse medium. The overestimated H$_2$, however, has little impact on CO. Consequently, the mass fraction of CO-dark H$_2$ gas is significantly lower than what a fully steady-state model predicts. The mass ratios of H$_2$/C$^+$ and H$_2$/C both show a weaker dependence on $Z^{prime}$ than H$_2$/CO, which potentially indicates that C$^+$ and C could be alternative tracers for H$_2$ at low $Z^{prime}$ in terms of mass budget. Our chemistry code for post-processing is publicly available.
Photon-stimulated desorption (PSD) is a process of interest for the two seemingly unrelated topics of accelerator vacuum dynamics and astrochemistry. Here we present an approach to studying PSD of interstellar ice analogs, i.e. condensed films of molecules of astrophysical interest at cryogenic temperatures, using synchrotron radiation. We present results obtained in the VUV range on various pure and layered ices, focusing on elucidating the desorption mechanisms, and results in the X-ray range for H$_2$O.
We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal) species is explicitly considered. In addition, we have included non-thermal, non-diffusive chemistry to account for the low-temperature characteristic of cold cores. As an initial test of our method, we have simulated two previous experimental studies involving the UV irradiation of pure solid O$_2$. In contrast to previous solid-state astrochemical model calculations which have used gas-phase photoabsorption cross-sections, we have employed solid-state cross-sections in our calculations. This method allows the model to be tested using well-constrained experiments rather than poorly constrained gas-phase abundances in ISM regions. Our results indicate that inclusion of non-thermal reactions and suprathermal species allows for reproduction of low-temperature solid-phase photoprocessing that simulate interstellar ices within cold ($sim$ 10 K) dense cores such as TMC-1.
Young massive stars regulate the physical conditions, ionization, and fate of their natal molecular cloud. It is important to find tracers that help quantifying the stellar feedback processes that take place at different scales. We present ~85 arcmin^2 velocity-resolved maps of several submm molecular lines toward the closest high-mass star-forming region, OMC-1. The observed rotational lines include probes of warm and dense molecular gas that are difficult to detect from ground-based telescopes: CH+ (1-0), CO (10-9), HCO+ (6-5), and HCN (6-5). These lines trace an extended but thin layer of molecular gas at high thermal pressure, P_th ~ 1e7-1e9 K/cm3, associated with the FUV-irradiated surface of OMC-1. The intense FUV field, emerging from massive stars in the Trapezium cluster, heats, compresses and photoevaporates the cloud edge. It also triggers the formation of reactive molecules such as CH+. The CH+ (1-0) emission spatially correlates with the flux of FUV photons impinging the cloud: G_0 from 1e3 to 1e5. This correlation is supported by isobaric PDR models in the parameter space P_th/G_0 ~ [5e3-8e4] K/cm3 where many PDRs seem to lie. The CH+ (1-0) emission correlates with the extended emission from vibrationally excited H2, and with that of [CII]158um and CO 10-9, all emerging from FUV-irradiated gas. These correlations link the presence of CH+ to the availability of C+ ions and of FUV-pumped H2(v>0) molecules. The parsec-scale CH+ emission and narrow-line (dv ~ 3 km/s) mid-J CO emission arises from extended PDRs and not from fast shocks. PDR line tracers are the smoking gun of the stellar feedback from young massive stars. The PDR component in OMC-1 represents 5 to 10% of the total gas mass, however, it dominates the emitted line luminosity. These results provide insights into the source of submm CH+ and mid-J CO emission from distant star-forming galaxies.
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