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Register a new userHerschel/HIFI Spectral Mapping of C$^+$, CH$^+$, and CH in Orion BN/KL: The Prevailing Role of Ultraviolet Irradiation in CH$^+$ Formation
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The CH$^+$ ion is a key species in the initial steps of interstellar carbon chemistry. Its formation in diverse environments where it is observed is not well understood, however, because the main production pathway is so endothermic (4280 K) that it is unlikely to proceed at the typical temperatures of molecular clouds. We investigation CH$^+$ formation with the first velocity-resolved spectral mapping of the CH$^+$ $J=1-0, 2-1$ rotational transitions, three sets of CH $Lambda$-doubled triplet lines, $^{12}$C$^+$ and $^{13}$C$^+$, and CH$_3$OH 835~GHz E-symmetry Q branch transitions, obtained with Herschel/HIFI over $approx$12 arcmin$^2$ centered on the Orion BN/KL source. We present the spatial morphologies and kinematics, cloud boundary conditions, excitation temperatures, column densities, and $^{12}$C$^+$ optical depths. Emission from C$^+$, CH$^+$, and CH is indicated to arise in the diluted gas, outside of the explosive, dense BN/KL outflow. Our models show that UV-irradiation provides favorable conditions for steady-state production of CH$^+$ in this environment. Surprisingly, no spatial or kinematic correspondences of these species are found with H$_2$ S(1) emission tracing shocked gas in the outflow. We propose that C$^+$ is being consumed by rapid production of CO to explain the lack of C$^+$ and CH$^+$ in the outflow, and that fluorescence provides the reservoir of H$_2$ excited to higher ro-vibrational and rotational levels. Hence, in star-forming environments containing sources of shocks and strong UV radiation, a description of CH$^+$ formation and excitation conditions is incomplete without including the important --- possibly dominant --- role of UV irradiation.
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We report the first sub-arc second (0.65$arcsec$ $times$ 0.51$arcsec$) image of the dimethyl ether molecule, (CH$_{3}$)$_{2}$O, toward the Orion Kleinmann-Low nebula (Orion--KL). The observations were carried at 43.4 GHz with the Expanded Very Large Array (EVLA). The distribution of the lower energy transition 6$_{1,5} - 6_{0,6}$, EE (E$rm_{u}$ = 21 K) mapped in this study is in excellent agreement with the published dimethyl ether emission maps imaged with a lower resolution. The main emission peaks are observed toward the Compact Ridge and Hot Core southwest components, at the northern parts of the Compact Ridge and in an intermediate position between the Compact Ridge and the Hot Core. A notable result is that the distribution of dimethyl ether is very similar to that of another important larger O-bearing species, the methyl formate (HCOOCH$_{3}$), imaged at lower resolution. Our study shows that higher spectral resolution (WIDAR correlator) and increased spectral coverage provided by the EVLA offer new possibilities for imaging complex molecular species. The sensitivity improvement and the other EVLA improvements make this instrument well suited for high sensitivity, high angular resolution, molecular line imaging.
Absorption spectra toward Herschel 36 for the A^1Pi <-- X^1Sigma transitions of CH+ in the J=1 excited rotational level and the A^2Delta <-- X^2Pi transition of CH in the J=3/2 excited fine structure level have been analyzed. These excited levels are above their ground levels by 40.1 K and ~25.7 K and indicate high radiative temperatures of the environment, 14.6 K and 6.7 K, respectively. The effect of the high radiative temperature is more spectacular in some diffuse interstellar bands (DIBs) observed toward Her 36; remarkable extended tails toward red (ETR) were observed. We interpret these ETRs as due to a small decrease of rotational constants upon excitation of excited electronic states. Along with radiative pumping of a great many high-J rotational levels, this causes the ETRs. In order to study this effect quantitatively, we have developed a model calculation in which the effects of collision and radiation are treated simultaneously. The simplest case of linear molecules is considered. It has been found that the ETR is reproduced if the fraction of the variation of the rotational constant, beta = (B-B)/B, is sufficiently high (3-5%) and the radiative temperature is high (T_r > 50 K). Although modeling for general molecules is beyond the scope of this paper, the results indicate that the prototypical DIBs at 5780.5, 5797.1, and 6613.6 A which show the pronounced ETRs are due to polar molecules sensitive to the radiative excitation. The requirement of high beta favors relatively small molecules with 3-6 heavy atoms. DIBs at 5849.8, 6196.0, and 6379.3 A which do not show the pronounced ETRs are likely due to non-polar molecules or large polar molecules with small beta.
We present a comprehensive study of the deuterated molecules detected in the fullband HIFI survey of the Orion KL region. Ammonia, formaldehyde, and methanol and their singly deuterated isotopologues are each detected through numerous transitions in this survey with a wide range in optical depths and excitation conditions. In conjunction with a recent study of the abundance of HDO and H$_2$O in Orion KL, this study yields the best constraints on deuterium fractionation in an interstellar molecular cloud to date. As previous studies have found, both the Hot Core and Compact Ridge regions within Orion KL contain significant abundances of deuterated molecules, suggesting an origin in cold grain mantles. In the Hot Core, we find that ammonia is roughly a factor of 2 more fractionated than water. In the Compact Ridge, meanwhile, we find similar deuterium fractionation in water, formaldehyde, and methanol, with D/H ratios of (2---8) $times$ $10^{-3}$. The [CH$_2$DOH]/[CH$_3$OD] ratio in the Compact Ridge is found to be $1.2 pm 0.3$. The Hot Core generally has lower deuterium fractionation than the Compact Ridge, suggesting a slightly warmer origin, or a greater contribution from warm gas phase chemistry.
We present ~2x2 spectral-maps of Orion BN/KL outflows taken with Herschel at ~12 resolution. For the first time in the far-IR domain, we spatially resolve the emission associated with the bright H2 shocked regions Peak 1 and Peak 2 from that of the Hot Core and ambient cloud. We analyze the ~54-310um spectra taken with the PACS and SPIRE spectrometers. More than 100 lines are detected, most of them rotationally excited lines of 12CO (up to J=48-47), H2O, OH, 13CO, and HCN. Peaks 1/2 are characterized by a very high L(CO)/L(FIR)~5x10^{-3} ratio and a plethora of far-IR H2O emission lines. The high-J CO and OH lines are a factor ~2 brighter toward Peak 1 whereas several excited H2O lines are ~50% brighter toward Peak 2. A simplified non-LTE model allowed us to constrain the dominant gas temperature components. Most of the CO column density arises from Tk~200-500 K gas that we associate with low-velocity shocks that fail to sputter grain ice mantles and show a maximum gas-phase H2O/CO~10^{-2} abundance ratio. In addition, the very excited CO (J>35) and H2O lines reveal a hotter gas component (Tk~2500 K) from faster (v_S>25 km/s) shocks that are able to sputter the frozen-out H2O and lead to high H2O/CO>~1 abundance ratios. The H2O and OH luminosities cannot be reproduced by shock models that assume high (undepleted) abundances of atomic oxygen in the preshock gas and/or neglect the presence of UV radiation in the postshock gas. Although massive outflows are a common feature in other massive star-forming cores, Orion BN/KL seems more peculiar because of its higher molecular luminosities and strong outflows caused by a recent explosive event.
The torsional Raman spectra of two astrophysically detected isotopologues of dimethyl-ether, ($^{12}$CH$_3$O$^{12}$CH$_3$ and $^{13}$CH$_3$O$^{12}$CH$_3$), have been recorded at room temperature and cooled in supersonic jet, and interpreted with the help of highly correlated ab initio calculations. Dimethyl-ether displays excited torsional and vibrational levels at low energy that can be populated at the temperatures of the star forming regions, obliging to extend the analysis of the rotational spectrum over the ground state. Its spectrum in the THz region is rather complex due to the coupling of the torsional overtones $2 u_{11}$ and $2 u_{15}$ with the COC bending mode, and the presence of many hot bands. The torsional overtones are set here at $2 u_{11}=385.2$~cm$^{-1}$ and $2 u_{15}=482.0$~cm$^{-1}$ for $^{12}$CH$_3$O$^{12}$CH$_3$, and $2 u_{11}=385.0$~cm$^{-1}$ and $2 u_{15}=481.1$~cm$^{-1}$ for $^{13}$CH$_3$O$^{12}$CH$_3$. The new assignment of $2 u_{11}$ is downshifted around $sim 10$~cm$^{-1}$ with respect to the literature. All the other (hot) bands have been re-assigned consistently. In addition, the infrared-forbidden torsional fundamental band $ u_{11}$ is observed here at 197.8~cm$^{-1}$. The new spectral characterization in the THz region reported here provides improved values of the Hamiltonian parameters, to be used in the analysis of the rotational spectra of DME isotopologues for further astrophysical detections.
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