No Arabic abstract
Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. We present the detection of the Complex Organic Molecules (COMs) acetaldehyde and methyl formate as well as formic acid and ketene, and the tentative detection of di-methyl ether towards the methanol hotspot of Barnard 5 located between two dense cores using the single dish OSO 20m, IRAM 30m, and NRO 45m telescopes. The high energy cis- conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between $sim 1$ and $sim 10$ % relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6 %, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as lukewarm COMs whereas methyl formate and di-methyl ether were defined as warm species. Comparison with previous observations of other types of sources confirms that lukewarm and warm COMs show similar abundances in low-density cold gas whereas the warm COMs tend to be more abundant than the lukewarm species in warm protostellar cores.
Dust grains play an important role in the synthesis of molecules in the interstellar medium, from the simplest species to complex organic molecules. How some of these solid-state molecules are converted into gas-phase species is still a matter of debate. Our aim is to directly compare ice and gas abundances of methanol (CH$_3$OH) and CO, and to investigate the relationship between ice and gas in low-mass protostellar envelopes. We present Submillimeter Array and Atacama Pathfinder EXperiment observations of gas-phase CH$_3$OH and CO towards the multiple protostellar system IRAS05417+0907 located in the B35A cloud. We use archival AKARI ice data toward the same target to calculate CH$_3$OH and CO gas-to-ice ratios. The CO isotopologues emissions are extended, whereas the CH$_3$OH emission is compact and traces the giant outflow emanating from IRAS05417+0907. A discrepancy between submillimeter dust emission and H$_2$O ice column density is found for B35A$-$4 and B35A$-$5, similar to what has previously been reported. B35A$-$2 and B35A$-$3 are located where the submillimeter dust emission peaks and show H$_2$O column densities lower than for B35A$-$4. The difference between the submillimeter continuum emission and the infrared H$_2$O ice observations suggests that the distributions of dust and H$_2$O ice differ around the young stellar objects in this dense cloud. The reason for this may be that the sources are located in different environments resolved by the interferometric observations: B35A$-$2, B35A$-$3 and in particular B35A$-$5 are situated in a shocked region plausibly affected by sputtering and heating impacting the submillimeter dust emission pattern, while B35A$-$4 is situated in a more quiescent part of the cloud. Gas and ice maps are essential to connect small-scale variations in the ice composition with large-scale astrophysical phenomena probed by gas observations.
G+0.693-0.03 is a quiescent molecular cloud located within the Sagittarius B2 (Sgr B2) star-forming complex. Recent spectral surveys have shown that it represents one of the most prolific repositories of complex organic species in the Galaxy. The origin of such chemical complexity, along with the small-scale physical structure and properties of G+0.693-0.03, remains a mystery. In this paper, we report the study of multiple molecules with interferometric observations in combination with single-dish data in G+0.693-0.03. Despite the lack of detection of continuum source, we find small-scale (0.2 pc) structures within this cloud. The analysis of the molecular emission of typical shock tracers such as SiO, HNCO, and CH$_3$OH unveiled two molecular components, peaking at velocities of 57 and 75 km s$^{-1}$. They are found to be interconnected in both space and velocity. The position-velocity diagrams show features that match with the observational signatures of a cloud-cloud collision. Additionally, we detect three series of class rom{1} methanol masers known to appear in shocked gas, supporting the cloud-cloud collision scenario. From the maser emission we provide constraints on the gas kinetic temperatures ($sim$30-150 K) and H$_2$ densities (10$^4$-10$^5$ cm$^{-2}$). These properties are similar to those found for the starburst galaxy NGC253 also using class rom{1} methanol masers, suggested to be associated with a cloud-cloud collision. We conclude that shocks driven by the possible cloud-cloud collision is likely the most important mechanism responsible for the high level of chemical complexity observed in G+0.693-0.03.
We have mapped six molecular cloud cores in the Orion A giant molecular cloud (GMC), whose kinetic temperatures range from 10 to 30 K, in CCS and N2H+ with Nobeyama 45 m radio telescope to study their chemical characteristics. We identified 31 intensity peaks in the CCS and N2H+ emission in these molecular cloud cores. It is found for cores with temperatures lower than ~ 25 K that the column density ratio of N(N2H+)/N(CCS) is low toward starless core regions while it is high toward star-forming core regions, in case that we detected both of the CCS and N2H+ emission. This is very similar to the tendency found in dark clouds (kinetic temperature ~ 10 K). The criterion found in the Orion A GMC is N(N2H+)/N(CCS) ~ 2-3. In some cases, the CCS emission is detected toward protostars as well as the N2H+ emission. Secondary late-stage CCS peak in the chemical evolution caused by CO depletion may be a possible explanation for this. We found that the chemical variation of CCS and N2H+ can also be used as a tracer of evolution in warm (10-25 K) GMC cores. On the other hand, some protostars do not accompany N2H+ intensity peaks but are associated with dust continuum emitting regions, suggesting that the N2H+ abundance might be decreased due to CO evaporation in warmer star-forming sites.
Dense cores are the final place where turbulence is dissipated. It has been proposed from theoretical arguments that the non-thermal velocity dispersion should be narrower both for molecular ions (compared to neutrals) and for transitions with higher critical densities. To test these hypotheses, we compare the velocity dispersion of N$_2$H$^+$ (1--0) (n$_{rm crit}$ = $6times10^4$ cm$^{-3}) and NH$_3$ (n$_{rm crit}=2times10^3$ cm$^{-3}), in the dense core Barnard 5. We analyse well resolved and high signal-to-noise observations of NH$_3$ (1,1) and (2,2) obtained with combining GBT and VLA data, and N$_2$H$^+$ (1--0) obtained with GBT Argus, which present a similar morphology. % Surprisingly, the non-thermal velocity dispersion of the ion is systematically higher than that of the neutral by 20%. The derived sonic Mach number, $mathcal{M}_s = sigma_{rm NT}/c_s$, has peak values $mathcal{M}_{s, {rm N_2H^+}} = 0.59$ and $mathcal{M}_{s, {rm NH}_3} = 0.48$ for N$_2$H$^+$ and NH$_3$, respectively. % This observed difference may indicate that the magnetic field even deep within the dense core is still oscillating, as it is in the turbulent region outside the core. The ions should be more strongly dynamically coupled to this oscillating field than the neutrals, thus accounting for their broader linewidth. If corroborated by further observations, this finding would shed additional light on the transition to quiescence in dense cores.
The extremely young Class 0 object B1b-S and the first hydrostatic core (FSHC) candidate, B1b-N, provide a unique opportunity to study the chemical changes produced in the elusive transition from the prestellar core to the protostellar phase. We present 40x70 images of Barnard 1b in the 13CO 1->0, C18O 1->0, NH2D 1_{1,1}a->1_{0,1}s, and SO 3_2->2_1 lines obtained with the NOEMA interferometer. The observed chemical segregation allows us to unveil the physical structure of this young protostellar system down to scales of ~500au. The two protostellar objects are embedded in an elongated condensation, with a velocity gradient of ~0.2-0.4 m s^{-1} au^{-1} in the east-west direction, reminiscent of an axial collapse. The NH2D data reveal cold and dense pseudo-disks (R~500-1000 au) around each protostar. Moreover, we observe evidence of pseudo-disk rotation around B1b-S. We do not see any signature of the bipolar outflows associated with B1b-N and B1b-S, which were previously detected in H2CO and CH3OH, in any of the imaged species. The non-detection of SO constrains the SO/CH3OH abundance ratio in the high-velocity gas.