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Register a new userPossible Fano resonance for high Tc multi-gap superconductivity in p-Terphenyl doped by K at the Lifshitz transition
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Recent experiments have reported the emergence of high temperature superconductivity with critical temperature $T_c$ between 43K and 123K in a potassium doped aromatic hydrocarbon para-Terphenyl or p-Terphenyl. This achievement provides the record for the highest Tc in an organic superconductor overcoming the previous record of Tc=38 K in Cs3C60 fulleride. Here we propose that the driving mechanism is the quantum resonance between superconducting gaps near a Lifshitz transition which belongs to the class of Fano resonances called shape resonances. For the case of p-Terphenyl our numerical solutions of the multi gap equation shows that high Tc is driven by tuning the chemical potential by K doping and it appears only in a narrow energy range near a Lifshitz transition. At the maximum critical temperature, Tc=123K, the condensate in the appearing new small Fermi surface pocket is in the BCS-BEC crossover while the Tc drops below 0.3 K where it is in the BEC regime. Finally we predict the experimental results which can support or falsify our proposed mechanism: a) the variation of the isotope coefficient as a function of the critical temperature and b) the variation of the gaps and their ratios 2Delta/Tc as a function of Tc.
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Synthesis methodology for flakes of p-terphenyl through sublimation under inert atmosphere of argon is presented. Flake morphology of p-terphenyl provides a favourable environment for efficient intercalation of potassium. Ratio of potassium and p-terphenyl is adjusted so as to obtain the desired superconducting phase i.e. potassium doped p-terphenyl (K3C18H14). A clear transition is observed at 107 K under Zero Field Cooled (ZFC) and Field Cooled (FC) mode. But overall the moment is positive possibly due to impurity phase dominating characteristics in the presence of negligible superconducting volume fraction. The M-H loop taken at 20 K shows magnetic behaviour in synthesized K- doped p-terphenyl but upon background subtraction, it does exhibit characteristics of a type-2 superconductor.
By using high pressure synthesis method, we have fabricated the potassium doped para-terphenyl. The temperature dependence of magnetization measured in both zero-field-cooled and field-cooled processes shows step like transitions at about 125 K. This confirms earlier report about the possible superconductivity like transition in the same system. However, the magnetization hysteresis loop exhibits a weak ferromagnetic background. After removing this ferromagnetic background, a Meissner effect like magnetic shielding can be found. A simple estimate on the diamagnetization of this step tells that the diamagnetic volume is only about 0.0427% at low temperatures, if we assume the penetration depth is much smaller than the size of possible superconducting grains. This magnetization transition does not shift with magnetic field but is suppressed and becomes almost invisible above 1.0 T. The resistivity measurements are failed because of an extremely large resistance. By using the same method, we also fabricated the potassium doped para-quaterphenyl. A similar step like transition at about 125 K was also observed by magnetization measurement. Since there is an unknown positive background and the diamagnetic volume is too small, it is insufficient to conclude that this step is derived from superconductivity although it looks like.
Polycrystalline Sr1-xNdxFeAsF samples were prepared at various Nd-doping levels using both a stoichiometric mixture of the starting materials and in slight excess amounts of FeAs. Susceptibility and resistivity of the samples were studied down to 4 K revealing a probable coexistence of superconductivity and a magnetic ordering. Temperature dependence of resistivity for all the Nd-doped samples shows the presence of a transition below 15 K most likely originating from the magnetic ordering of Nd moments, while the spin-density-wave anomaly at 175 K survives up to 0.35 Nd-doping. Superconductivity only occurs above 0.40 Nd-doping with onset maximum Tc reaching as high as 52 K.
The layered lithium borocarbide LiBC, isovalent with and structurally similar to the superconductor MgB2, is an insulator due to the modulation within the hexagonal layers (BC vs. B2). We show that hole-doping of LiBC results in Fermi surfaces of B-C p sigma character that couple very strongly to B-C bond stretching modes, precisely the features that lead to superconductivity at Tc = 40 K in MgB2. Comparison of Li{0.5}BC with MgB2 indicates the former to be a prime candidate for electron-phonon coupled superconductivity at substantially higher temperature than in MgB2.
Following a recent proposal by Burrard-Lucas et al. [unpublished, arXiv: 1203.5046] we intercalated FeSe by Li in liquid ammonia. We report on the synthesis of new LixFe2Se2(NH3)y phases as well as on their magnetic and superconducting properties. We suggest that the superconducting properties of these new hybride materials appear not to be influenced by the presence of electronically-innocent Li(NH2) salt moieties. Indeed, high onset temperatures of 44 K and shielding fractions of almost 80% were only obtained in samples containing exclusively Lix(NH3)y moieties acting simultaneously as electron donors and spacer units. The c-axis of the new intercalated phases is strongly enhanced when compared to the alkali-metal intercalated iron selenides A1-xFe2-ySe2 with A = K, Rb, Cs, Tl with T c = 32 K.
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