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Veit Elser
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These lectures were prepared for the 2014 PCMI graduate summer school and were designed to be a lightweight introduction to statistical mechanics for mathematicians. The applications feature some of the themes of the summer school: sphere packings and tilings.
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Recently, we have presented some simple arguments supporting the existence of certain complementarity between thermodynamic quantities of temperature and energy, an idea suggested by Bohr and Heinsenberg in the early days of Quantum Mechanics. Such a complementarity is expressed as the impossibility of perform an exact simultaneous determination of the system energy and temperature by using an experimental procedure based on the thermal equilibrium with other system regarded as a measure apparatus (thermometer). In this work, we provide a simple generalization of this latter approach with the consideration of a thermodynamic situation with several control parameters.
The local equilibrium approach previously developed by the Authors [J. Mabillard and P. Gaspard, J. Stat. Mech. (2020) 103203] for matter with broken symmetries is applied to crystalline solids. The macroscopic hydrodynamics of crystals and their local thermodynamic and transport properties are deduced from the microscopic Hamiltonian dynamics. In particular, the Green-Kubo formulas are obtained for all the transport coefficients. The eight hydrodynamic modes and their dispersion relation are studied for general and cubic crystals. In the same twenty crystallographic classes as those compatible with piezoelectricity, cross effects coupling transport between linear momentum and heat or crystalline order are shown to split the degeneracy of damping rates for modes propagating in opposite generic directions.
Noethers calculus of invariant variations yields exact identities from functional symmetries. The standard application to an action integral allows to identify conservation laws. Here we rather consider generating functionals, such as the free energy and the power functional, for equilibrium and driven many-body systems. Translational and rotational symmetry operations yield mechanical laws. These global identities express vanishing of total internal and total external forces and torques. We show that functional differentiation then leads to hierarchies of local sum rules that interrelate density correlators as well as static and time direct correlation functions, including memory. For anisotropic particles, orbital and spin motion become systematically coupled. The theory allows us to shed new light on the spatio-temporal coupling of correlations in complex systems. As applications we consider active Brownian particles, where the theory clarifies the role of interfacial forces in motility-induced phase separation. For active sedimentation, the center-of-mass motion is constrained by an internal Noether sum rule.
An interesting connection between the Regge theory of scattering, the Veneziano amplitude, the Lee-Yang theorems in statistical mechanics and nonextensive Renyi entropy is addressed. In this scheme the standard entropy and the Renyi entropy appear to be different limits of a unique mathematical object. This framework sheds light on the physical origin of nonextensivity. A non trivial application to spin glass theory is shortly outlined.
The lectures provide a pedagogical introduction to the methods of CFT as applied to two-dimensional critical behaviour.
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