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Completely open systems can exchange heat, work, and matter with the environment. While energy, volume, and number of particles fluctuate under completely open conditions, the equilibrium states of the system, if they exist, can be specified using the temperature, pressure, and chemical potential as control parameters. The unconstrained ensemble is the statistical ensemble describing completely open systems and the replica energy is the appropriate free energy for these control parameters from which the thermodynamics must be derived. It turns out that macroscopic systems with short-range interactions cannot attain equilibrium configurations in the unconstrained ensemble, since temperature, pressure, and chemical potential cannot be taken as a set of independent variables in this case. In contrast, we show that systems with long-range interactions can reach states of thermodynamic equilibrium in the unconstrained ensemble. To illustrate this fact, we consider a modification of the Thirring model and compare the unconstrained ensemble with the canonical and grand canonical ones: the more the ensemble is constrained by fixing the volume or number of particles, the larger the space of parameters defining the equilibrium configurations.
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The unconstrained ensemble describes completely open systems in which energy, volume and number of particles fluctuate. Here we show that not only equilibrium states can exist in this ensemble, but also that completely open systems can undergo first-order phase transitions. This is shown by studying a modified version of the Thirring model with attractive and repulsive interactions and with particles of finite size. The model exhibits first-order phase transitions in the unconstrained ensemble, at variance with the analogous model with point-like particles. While unconstrained and grand canonical ensembles are equivalent for this model, we found inequivalence between the unconstrained and isothermal-isobaric ensembles. By comparing the thermodynamic phase diagram in the unconstrained case with that obtained in the isothermal-isobaric ensemble, we show that phase transitions under completely open conditions for this model are different from those in which the number of particles is fixed, highlighting the inequivalence of ensembles.
The unconstrained ensemble describes completely open systems whose control parameters are chemical potential, pressure, and temperature. For macroscopic systems with short-range interactions, thermodynamics prevents the simultaneous use of these intensive variables as control parameters, because they are not independent and cannot account for the system size. When the range of the interactions is comparable with the size of the system, however, these variables are not truly intensive and may become independent, so equilibrium states defined by the values of these parameters may exist. Here, we derive a Monte Carlo algorithm for the unconstrained ensemble and show that simulations can be performed using chemical potential, pressure, and temperature as control parameters. We illustrate the algorithm by applying it to physical systems where either the system has long-range interactions or is confined by external conditions. The method opens up a new avenue for the simulation of completely open systems exchanging heat, work, and matter with the environment.
Systems with long-range interactions display a short-time relaxation towards Quasi Stationary States (QSSs) whose lifetime increases with system size. The application of Lynden-Bells theory of violent relaxation to the Hamiltonian Mean Field model leads to the prediction of out-of-equilibrium first and second order phase transitions between homogeneous (zero magnetization) and inhomogeneous (non-zero magnetization) QSSs, as well as an interesting phenomenon of phase re-entrances. We compare these theoretical predictions with direct $N$-body numerical simulations. We confirm the existence of phase re-entrance in the typical parameter range predicted from Lynden-Bells theory, but also show that the picture is more complicated than initially thought. In particular, we exhibit the existence of secondary re-entrant phases: we find un-magnetized states in the theoretically magnetized region as well as persisting magnetized states in the theoretically unmagnetized region.
The presence of non-local and long-range interactions in quantum systems induces several peculiar features in their equilibrium and out-of-equilibrium behavior. In current experimental platforms control parameters such as interaction range, temperature, density and dimension can be changed. The existence of universal scaling regimes, where diverse physical systems and observables display quantitative agreement, generates a common framework, where the efforts of different research communities can be -- in some cases rigorously -- connected. Still, the application of this general framework to particular experimental realisations requires the identification of the regimes where the universality phenomenon is expected to appear. In the present review we summarise the recent investigations of many-body quantum systems with long-range interactions, which are currently realised in Rydberg atom arrays, dipolar systems, trapped ion setups and cold atoms in cavity experiments. Our main aim is to present and identify the common and (mostly) universal features induced by long-range interactions in the behaviour of quantum many-body systems. We will discuss both the case of very strong non-local couplings, i.e. the non-additive regime, and the one in which energy is extensive, but nevertheless low-energy, long wavelength properties are altered with respect to the short-range limit. Cases of competition with other local effects in the above mentioned setups are also reviewed.
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