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Influence of Turbulent Fluctuations on Detonation Propagation

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 Added by Brian Maxwell
 Publication date 2016
  fields Physics
and research's language is English




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The present study addresses the reaction zone structure and burning mechanism of unstable detonations. Experiments investigated mainly two-dimensional methane-oxygen cellular detonations in a thin channel geometry. The sufficiently high temporal resolution permitted to determine the PDF of the shock distribution, a power-law with an exponent of -3, and the burning rate of unreacted pockets from their edges - through surface turbulent flames with a speed approximately 3-7 times larger than the laminar one at the local conditions. Numerical simulations were performed using a novel Large Eddy Simulation method where the reactions due to both auto-ignition and turbulent transport and treated exactly at the sub-grid scale in a reaction-diffusion formulation. The model is an extension of Kerstein & Menons Linear Eddy Model for Large Eddy Simulation to treat flows with shock waves and rapid gasdynamic transients. The two-dimensional simulations recovered well the amplification of the laminar flame speed owing to the turbulence generated mainly by the shear layers originating from the triple points and subsequent Richtmyer-Meshkov instability associated with the internal pressure waves. The simulations clarified how the level of turbulence generated controlled the burning rate of the pockets, the hydrodynamic thickness of the wave, the cellular structure and its distribution. Three-dimensional simulations were found in general good agreement with the two-dimensional ones, in that the sub-grid scale model captured the ensuing turbulent burning once the scales associated with the cellular dynamics, where turbulent kinetic energy is injected, are well resolved.



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Turbulent flows frequently accompany physical, chemical and biological processes, such as mixing, two-phase flow, combustion and even foraging by bacteria and plankton larvae, all of which are in principle subject to thermal fluctuations already on scales of several microns. Nevertheless the large separation between the millimeter scale at which turbulent fluctuations begin to be strongly damped and the mean free path of the fluid has been generally assumed to imply that thermal fluctuations are irrelevant to the turbulent dissipation range. Here we use statistical mechanical estimates to show that thermal fluctuations are not negligible compared to turbulent eddies in the dissipation range. Simulation of the Sabra shell model shows that intermittent bursts of turbulence lead to a fluctuating length scale below which thermal fluctuations are important: over three decades of length, from sub-millimeter scales down to the mean free path, thermal fluctuations coexist with hydrodynamics. Our results imply that thermal fluctuations cannot be neglected when modeling turbulent phenomena in the far dissipation range.
We evaluate the effect of boundary layer losses on two-dimensional H2/O2/Ar cellular detonations obtained in narrow channels. The experiments provide the details of the cellular structure and the detonation speed deficits from the ideal CJ speed. We model the effect of the boundary layer losses by incorporating the flow divergence in the third dimension due to the negative boundary layer displacement thickness, modeled using Mirels theory. The cellular structures obtained numerically with the resulting quasi-2D formulation of the reactive Euler equations with two-step chain-branching chemistry are found in excellent agreement with experiment, both in terms of cell dynamics and velocity deficits, provided the boundary layer constant of Mirels is modified by a factor of 2. A significant increase in the cell size is found with increasing velocity deficit. This is found to be very well captured by the induction zone increase in slower detonations due to the lower temperatures in the induction zone.
In turbulent Rayleigh-Benard convection, a large-scale circulation (LSC) develops in a nearly vertical plane, and is maintained by rising and falling plumes detaching from the unstable thermal boundary layers. Rare but large fluctuations in the LSC amplitude can lead to extinction of the LSC (a cessation event), followed by the re-emergence of another LSC with a different (random) azimuthal orientation. We extend previous models of the LSC dynamics to include momentum and thermal diffusion in the azimuthal plane, and calculate the tails of the probability distributions of both the amplitude and azimuthal angle. Our analytical results are in very good agreement with experimental data.
The present work examines the role of instability and diffusive phenomena in controlling the limits of detonations subject to lateral strain rates. Experiments were conducted in hydrocarbon-oxygen mixtures with varying levels of cellular instability. These detonations were propagated in channels with exponentially enlarging cross-sections, following the recent works of Radulescu & Borzou (2018) and Xiao & Radulescu (2020). Steady detonation waves were obtained at the macro-scale, with the near-limit reaction zone structures characterized by significant unreacted gas pockets. The turbulent flame burning velocity of these pockets was evaluated to be 30 m/s to 70 m/s, which is larger than the theoretical laminar value by a factor of 2 to 7. For all the mixtures tested, the characteristic $D-K$ relationships, relating the detonation mean propagation speed with lateral flow divergence, were obtained directly from experiments and as well from the generalized ZND model with lateral strain rates using detailed chemical kinetics. The results showed that the degree of departure between experiments and the theoretical predictions increases significantly with the detonation instability level. As compared to the laminar ZND wave, the more unstable detonations are much more detonable than the more stable detonations, with substantially larger limiting divergence rates and maximum velocity deficits. Such enhanced detonability with detonation instability can be manifested in the significantly enhanced global rates of energy release with the notably suppressed thermal character of ignition for the more unstable detonations. This globally enhanced burning mechanism is found to be realized by the intensified auto-ignition assisted by the turbulent diffusive burning of the unreacted gas pockets, substantially shortening the characteristic reaction zone lengths.
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