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Volatiles beneath mid-ocean ridges: deep melting, channelised transport, focusing, and metasomatism

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 Added by Tobias Keller
 Publication date 2016
  fields Physics
and research's language is English




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Deep-Earth volatile cycles couple the mantle with near-surface reservoirs. Volatiles are emitted by volcanism and, in particular, from mid-ocean ridges, which are the most prolific source of basaltic volcanism. Estimates of volatile extraction from the asthenosphere beneath ridges typically rely on measurements of undegassed lavas combined with simple petrogenetic models of the mean degree of melting. Estimated volatile fluxes have large uncertainties; this is partly due to a poor understanding of how volatiles are transported by magma in the asthenosphere. Here, we assess the fate of mantle volatiles through numerical simulations of melting and melt transport at mid-ocean ridges. Our simulations are based on two-phase, magma/mantle dynamics theory coupled to idealised thermodynamic model of mantle melting in the presence of water and carbon dioxide. We combine simulation results with catalogued observations of all ridge segments to estimate a range of likely volatile output from the global mid-ocean ridge system. We thus predict global MOR crust production of 66-73 Gt/yr (22-24 km3/yr) and global volatile output of 52-110 Mt/yr, corresponding to mantle volatile contents of 100--200~ppm. We find that volatile extraction is limited: up to half of deep, volatile-rich melt is not focused to the axis but is rather deposited along the LAB. As these distal melts crystallise and fractionate, they metasomatise the base of the lithosphere, creating rheological heterogeneity that could contribute to the seismic signature of the LAB.



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Melting beneath mid-ocean ridges occurs over a region that is much broader than the zone of magmatic emplacement to form the oceanic crust. Magma is focused into this zone by lateral transport. This focusing has typically been explained by dynamic pressure gradients associated with corner flow, or by a sub-lithospheric channel sloping upward toward the ridge axis. Here we discuss a novel mechanism for magmatic focusing: lateral transport driven by gradients in compaction pressure within the asthenosphere. These gradients arise from the co-variation of melting rate and compaction viscosity. The compaction viscosity, in previous models, was given as a function of melt fraction and temperature. In contrast, we show that the viscosity variations relevant to melt focusing arise from grain-size variability and non-Newtonian creep. The asthenospheric distribution of melt fraction predicted by our models provides an improved ex- planation of the electrical resistivity structure beneath one location on the East Pacific Rise. More generally, although grain size and non-Newtonian viscosity are properties of the solid phase, we find that in the context of mid-ocean ridges, their effect on melt transport is more profound than their effect on the mantle corner-flow.
It is generally accepted that melt extraction from the mantle at mid-ocean ridges (MORs) is concentrated in narrow regions of elevated melt fraction called channels. Two feedback mechanisms have been proposed to explain why these channels grow by linear instability: shear flow of partially molten mantle and reactive flow of the ascending magma. These two mechanisms have been studied extensively, in isolation from each other, through theory and laboratory experiments as well as field and geophysical observations. Here, we develop a consistent theory that accounts for both proposed mechanisms and allows us to weigh their relative contributions. We show that interaction of the two feedback mechanisms is insignificant and that the total linear growth rate of channels is well-approximated by summing their independent growth rates. Furthermore, we explain how their competition is governed by the orientation of channels with respect to gravity and mantle shear. By itself, analysis of the reaction-infiltration instability predicts the formation of tube-shaped channels. We show that with the addition of even a small amount of extension in the horizontal, the combined instability favours tabular channels, consistent with the observed morphology of dunite bodies in ophiolites. We apply the new theory to MORs by calculating the accumulated growth and rotation of channels along streamlines of the solid flow. We show that reactive flow is the dominant mechanism deep beneath the ridge axis, where the most unstable orientation of high-porosity channels is sub-vertical. Channels are then rotated by the solid flow away from the vertical. The contribution of the shear-driven instability is confined to the margins of the melting region. Within the limitations of our study, the shear-driven feedback is not responsible for significant melt focusing or for shallowly dipping seismic anisotropy [abridged].
Experimental studies of mantle petrology find that small concentrations of water and carbon dioxide have a large effect on the solidus temperature and distribution of melting in the upper mantle. However, it has remained unclear what effect small fractions of deep, volatile-rich melts have on melt transport and reactive melting in the shallow asthenosphere. Here we present theory and computations indicating that low-degree, reactive, volatile-rich melts cause channelisation of magmatic flow at depths approximately corresponding to the anhydrous solidus temperature. These results are obtained with a novel method to simulate the thermochemical evolution of the upper mantle in the presence of volatiles. The method uses a thermodynamically consistent framework for reactive, disequilibrium, multi-component melting. It is coupled with a system of equations representing conservation of mass, momentum, and energy for a partially molten grain aggregate. Application of this method in two-phase, three-component upwelling-column models demonstrates that it reproduces leading-order features of hydrated and carbonated peridotite melting; in particular, it captures the production of low-degree, volatile-rich melt at depths far below the volatile-free solidus. The models predict that segregation of volatile-rich, deep melts promotes a reactive channeling instability that creates fast and chemically isolated pathways of melt extraction. Reactive channeling occurs where volatile-rich melts flux the base of the silicate melting region, enhancing dissolution of fusible components from the ambient mantle. We find this effect to be similarly expressed for models of both hydrated and carbonated mantle melting. These findings indicate that despite their small concentrations, water and carbon dioxide have an important control on the extent and style of magma genesis, as well as on the dynamics of melt transport.
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