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Comment on Tip induced unconventional superconductivity on Weyl semimetal TaAs [arXiv:1607.00513]

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 Publication date 2016
  fields Physics
and research's language is English




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Recently, Wang $et$ $al.$ have reported the observation of unconventional superconductivity in the Weyl semimetal TaAs [arXiv:1607.00513]. The authors have written textit{A conductance plateau and sharp double dips are observed in the point contact spectra, indicating p-wave like unconventional superconductivity. Furthermore, the zero bias conductance peak in low temperature regime is detected, suggesting potentially the existence of Majorana zero modes. The experimentally observed tunneling spectra can be interpreted with a novel mirror-symmetry protected topological superconductor induced in TaAs, which can exhibit zero bias and double finite bias peaks, and double conductance dips in the measurements}. In this comment we show that for a superconducting point contact, the features like a zero-bias conductance peak, a plateau and single or multiple conductance dips might arise due to simple contact-heating related effects. Such features are routinely observed in point contacts involving a wide variety of superconductors when the experiments are not performed in the right regime of mesoscopic transport. We also show that the data presented by Wang $et$ $al.$ in a single transport regime of point contact do not confirm tip induced superconductivity (TISC). Even if it is assumed that Wang $et$ $al.$ achieved TISC on TaAs, all the spectra that they have reported show striking similarities with the type of spectra expected in thermal regime of transport. Such data cannot be used for extracting any spectroscopic information and based on such data any discussion on p-wave superconductivity or the emergence of Majorana modes should be considered invalid. This version (v2) also includes a brief discussion on the response of Wang $et$ $al.$ to the first version (v1) of this comment. Correct ballistic regime data on TaAs point contacts can be found in arXiv:1607.05131 (2016).



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A Weyl semimetal is a topologically non-trivial phase of matter that hosts mass-less Weyl fermions, the particles that remained elusive for more than 80 years since their theoretical discovery. The Weyl semimetals exhibit unique transport and magneto-transport properties and remarkably high surface spin polarization. Here we show that a unique mesoscopic superconducting phase with a critical temperature up to 7 K can be realized by forming metallic point contacts with silver (Ag) on single crystals of TaAs, while neither Ag nor TaAs are superconductors. The Andreev reflection spectra obtained from such point contacts are fitted well within a modified Blonder-Tinkham-Klapwijk (BTK) model with a superconducting energy gap up to 1.2 meV. The analysis within this model also reveals high transport spin polarization up to 60% indicating a spin polarized supercurrent flowing through the point contacts on TaAs. Such point contacts also show a large anisotropic magnetoresistance (AMR) originating from the spin polarized current. Therefore, apart from the discovery of a novel mesoscopic superconducting phase and its coexistence with a large spin polarization, our results also show that the point contacts on Weyl semimetals are potentially important for applications in spintronics.
It is widely believed that topological superconductivity, a hitherto elusive phase of quantum matter, can be achieved by inducing superconductivity in topological materials. In search of such topological superconductors, certain topological insulators (like, Bi$_2$Se$_3$) were successfully turned into superconductors by metal-ion (Cu, Pd, Sr, Nb etc. ) intercalation. Superconductivity could be induced in topological materials through applying pressure as well. for example, a pressure-induced superconducting phase was found in the topological insulator Bi$_2$Se$_3$. However, in all such cases, no conclusive signature of topological superconductivity was found. In this review, we will discuss about another novel way of inducing superconductivity in a non-superconducting topological material -- by creating a mesoscopic interface on the material with a non-superconducting, normal metallic tip where the mesoscopic interface becomes superconducting. Such a phase is now known as a tip-induced superconducting (TISC) phase. This was first seen in 2014 on Cd$_3$As$_2$ at IISER Mohali, India. Following that, a large number of other topological materials were shown to display TISC. Since the TISC phase emerges only at a confined region under a mesoscopic point contact, traditional bulk tools for characterizing superconductivity cannot be employed to detect/confirm such a phase. On the other hand, such a point contact geometry is ideal for probing the possible existence of a temperature and magnetic field dependent superconducting energy gap and a temperature and magnetic field dependent critical current. We will review the details of the experimental signatures that can be used to prove the existence of superconductivity even when the text-book tests for detecting superconductivity cannot be performed. Then, we will review different systems where a TISC phase could be realized.
ZrSiS was recently shown to be a new material with topologically non-trivial band structure which exhibits multiple Dirac nodes and a robust linear band dispersion up to an unusually high energy of 2,eV. Such a robust linear dispersion makes the topological properties of ZrSiS insensitive to perturbations like carrier doping or lattice distortion. Here we show that a novel superconducting phase with a remarkably high $T_c$ of 7.5,K can be induced in single crystals of ZrSiS by a non-superconducting metallic tip of Ag. From first-principles calculations we show that the observed superconducting phase might originate from dramatic enhancement of density of states due to the presence of a metallic tip on ZrSiS. Our calculations also show that the emerging tip-induced superconducting phase co-exists with the well preserved topological properties of ZrSiS.
247 - B. Q. Lv , H. M. Weng , B. B. Fu 2015
Weyl semimetals are a class of materials that can be regarded as three-dimensional analogs of graphene breaking time reversal or inversion symmetry. Electrons in a Weyl semimetal behave as Weyl fermions, which have many exotic properties, such as chiral anomaly and magnetic monopoles in the crystal momentum space. The surface state of a Weyl semimetal displays pairs of entangled Fermi arcs at two opposite surfaces. However, the existence of Weyl semimetals has not yet been proved experimentally. Here we report the experimental realization of a Weyl semimetal in TaAs by observing Fermi arcs formed by its surface states using angle-resolved photoemission spectroscopy. Our first-principles calculations, matching remarkably well with the experimental results, further confirm that TaAs is a Weyl semimetal.
211 - Guo-meng Zhao 2011
In our recent paper entitled Pairing mechanism of high-temperature superconductivity: Experimental constraints (to be published in Physica Scripta, arXiv:1012.2368), we review some crucial experiments that place strong constraints on the microscopic pairing mechanism of high-temperature superconductivity in cuprates. In particular, we show that phonons rather than spin-fluctuation play a predominant role in the microscopic pairing mechanism. We further show that the intrinsic pairing symmetry in the bulk is not d-wave, but extended s-wave (having eight line nodes) in hole-doped cuprates and nodeless s-wave in electron-doped cuprates. In contrast, the author of the Comment (to be published in Physica Scripta) argues that our conclusions are unconvincing and even misleading. In response to the criticisms in the Comment, we further show that our conclusions are well supported by experiments and his criticisms are lack of scientific ground.
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