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Thermoelectric study of dissipative quantum dot heat engines

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 Publication date 2016
  fields Physics
and research's language is English




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This paper examines the thermoelectric response of a dissipative quantum dot heat engine based on the Anderson-Holstein model in two relevant operating limits: (i) when the dot phonon modes are out of equilibrium, and (ii) when the dot phonon modes are strongly coupled to a heat bath. In the first case, a detailed analysis of the physics related to the interplay between the quantum dot level quantization, the on-site Coulomb interaction and the electron-phonon coupling on the thermoelectric performance reveals that an n-type heat engine performs better than a p-type heat engine. In the second case, with the aid of the dot temperature estimated by incorporating a {it{thermometer bath}}, it is shown that the dot temperature deviates from the bath temperature as electron-phonon interaction becomes stronger. Consequently, it is demonstrated that the dot temperature controls the direction of phonon heat currents, thereby influencing the thermoelectric performance. Finally, the conditions on the maximum efficiency with varying phonon couplings between the dot and all the other macroscopic bodies are analyzed in order to reveal the nature of the optimum junction.



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Quantum dots (QDs) can serve as near perfect energy filters and are therefore of significant interest for the study of thermoelectric energy conversion close to thermodynamic efficiency limits. Indeed, recent experiments in [Nat. Nano. 13, 920 (2018)] realized a QD heat engine with performance near these limits and in excellent agreement with theoretical predictions. However, these experiments also highlighted a need for more theory to help guide and understand the practical optimization of QD heat engines, in particular regarding the role of tunnel couplings on the performance at maximum power and efficiency for QDs that couple seemingly weakly to electronic reservoirs. Furthermore, these experiments also highlighted the critical role of the external load when optimizing the performance of a QD heat engine in practice. To provide further insight into the operation of these engines we use the Anderson impurity model together with a Master equation approach to perform power and efficiency calculations up to co-tunneling order. This is combined with additional thermoelectric experiments on a QD embedded in a nanowire where the power is measured using two methods. We use the measurements to present an experimental procedure for efficiently finding the external load $R_P$ which should be connected to the engine to optimize power output. Our theoretical estimates of $R_P$ show a good agreement with the experimental results, and we show that second order tunneling processes and non-linear effects have little impact close to maximum power, allowing us to derive a simple analytic expression for $R_P$. In contrast, we find that the electron contribution to the thermoelectric efficiency is significantly reduced by second order tunneling processes, even for rather weak tunnel couplings.
Efficiency at maximum power (EMP) is a very important specification for a heat engine to evaluate the capacity of outputting adequate power with high efficiency. It has been proved theoretically that the limit EMP of thermoelectric heat engine can be achieved with the hypothetical boxcar-shaped electron transmission, which is realized here by the resonant tunneling in the one-dimensional symmetric InP/InSe superlattice. It is found with the transfer matrix method that a symmetric mode is robust that regardless of the periodicity, and the obtained boxcar-like electron transmission stems from the strong coupling between symmetric mode and Fabry-Perot modes inside the allowed band. High uniformity of the boxcar-like transmission and the sharp drop of the transmission edge are both beneficial to the maximum power and the EMP, which are optimized by the bias voltage and the thicknesses of barrier and well. The maximum power and EMP are extracted with the help of machine learning technique, and more than 95% of their theoretical limits can both be achieved for smaller temperature difference, smaller barrier width and larger well width. We hope the obtain results could provide some basic guidance for the future designs of high EMP thermoelectric heat engines.
122 - L. Arrachea , M. Moskalets 2009
A quantum dot driven by two ac gate potentials oscillating with a phase lag may be regarded as a quantum engine, where energy is transported and dissipated in the form of heat. In this chapter we introduce a microscopic model for a quantum pump and analyze the fundamental principle for the conservation of the charge and energy in this device. We also present the basics of two well established many-body techniques to treat quantum transport in harmonically time-dependent systems. We discuss the different operating modes of this quantum engine, including the mechanism of heat generation. Finally, we establish the principles of quantum refrigeration within the weak driving regime. We also show that it is possible to achieve a regime where part of the work done by some of the ac fields can be coherently transported and can be used by the other driving voltages.
We discuss the temperature-dependent thermoelectric transport properties of semiconductor nanostructures comprising a quantum dot coupled to quantum wires: the thermal dependence of the electrical conductance, thermal conductance, and thermopower. We explore the universality of the thermoelectric properties in the temperature range associated with the Kondo crossover. In this thermal range, general arguments indicate that any equilibrium propertys temperature dependence should be a universal function of the ratio $T^{*}=T/T_{K}$, where $T_{K}$ is the Kondo temperature. Considering the particle-hole symmetric, spin-degenerate Anderson model, the zero-bias electrical conductance has already been shown to map linearly onto a universal conductance through a quantum dot embedded or side-coupled to a quantum wire. Employing rigorous renormalization-group arguments, we calculate universal thermoelectric transport coefficients that allow us to extend this result to the thermopower and the thermal conductance. We present numerical renormalization-group results to illustrate the physics in our findings. Applying the universal thermoelectric coefficients to recent experimental results of the electrical conductance and thermo-voltages versus $V_{gate}$, at different temperatures in the Kondo regime, we calculate all the thermoelectric properties and obtain simple analytical fitting functions that can be used to predict the experimental results of these properties. However, we cannot check all of them, due to the lack of available experimental results over a broad temperature range.
The thermoelectric performance of a topological Josephson nonlocal heat engine is thoroughly investigated. The nonlocal response is obtained by using a normal metal probe coupled with only one of the proximized helical edges in the middle of the junction. In this configuration, we investigate how the flux bias and the phase bias trigger the nonlocal thermoelectric effects under the application of a thermal difference between the superconducting terminals. Possible experimental nonidealities such as asymmetric proximized superconducting gaps are considered showing how the nonlocal response can be affected. The interplay between Doppler-shift, which tends to close gaps, and Andreev interferometry, which affects particle-hole resonant transport, are clearly identified for different operating regimes. Finally, we discuss the power and the efficiency of the topological thermoelectric engine which reaches maximum power at maximal efficiency for a well coupled normal probe. We find quite high nonlocal Seebeck coefficient of the order of tenths of $mu$V/K at a few kelvin, a signal that would be clearly detectable also against any spurious local effect even with moderate asymmetry of the gaps.
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