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Register a new userValence Characterization of Surface and Subsurface Region in SmB6
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Samarium hexaboride (SmB6), which lies in the mixed valence regime in the Anderson model, has been predicted to possess topologically protected surface states. The intensive investigations on SmB6 have brought up the long standing questions about the discrepancy between the surface and bulk electronic properties in rare-earth compounds in general. Here, we investigate and eventually clarify this discrepancy in the particular case of SmB6 by the photoemission core-level spectra. We focus on the change in both Sm and B states depending on time, temperature, probing depth, and surface termination on the cleaved (100) surface. Our spectra show that the unusual time-dependent change in the Sm valence occurs within a period of hours, which is not related to the adsorption of residual gases. Moreover, we observe a reduction of the surface feature in the B and Sm states on the same timescale accompanied by the formation of a subsurface region. Thus, it indicates the relatively slow charge redistribution between the surface and subsurface regions. Our findings demonstrate that the f states is strongly involved in the surface relaxation.
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The intermediate valent systems TmSe and SmB6 have been investigated up to 16 and 18 GPa by ac microcalorimetry with a pressure (p) tuning realized in situ at low temperature. For TmSe, the transition from an antiferromagnetic insulator for p<3 GPa to an antiferromagnetic metal at higher pressure has been confirmed. A drastic change in the p variation of the Neel temperature (Tn) is observed at 3 GPa. In the metallic phase (p>3 GPa), Tn is found to increase linearly with p. A similar linear p increase of Tn is observed for the quasitrivalent compound TmS which is at ambiant pressure equivalent to TmSe at p=7 GPa. In the case of SmB6 long range magnetism has been detected above p=8 GPa, i.e. at a pressure slightly higher than the pressure of the insulator to metal transition. However a homogeneous magnetic phase occurs only above 10 GPa. The magnetic and electronic properties are related to the renormalization of the 4f wavefunction either to the divalent or the trivalent configurations. As observed in SmS, long range magnetism in SmB6 occurs already far below the pressure where a trivalent Sm3+ state will be reached. It seems possible, to describe roughly the physical properties of the intermediate valence equilibrium by assuming formulas for the Kondo lattice temperature depending on the valence configuration. Comparison is also made with the appearance of long range magnetism in cerium and ytterbium heavy fermion compounds.
Samarium hexaboride crystallizes in a simple cubic structure (space group #221, Pm-3m), but its properties are far from being straightforward. Initially classified as a Kondo insulator born out of its intriguing intermediate valence ground state, SmB6 has been recently predicted to be a strongly correlated topological insulator. The subsequent experimental discovery of surface states has revived the interest in SmB6, and our purpose here is to review the extensive and in many aspects perplexing experimental record of this material. We will discuss both surface and bulk properties of SmB6 with an emphasis on the role of crystal growth and sample preparation. We will also highlight the remaining mysteries and open questions in the field.
Samarium hexaboride (SmB$_6$), a Kondo insulator with mixed valence, has recently attracted much attention as a possible host for correlated topological surface states. Here, we use a combination of x-ray absorption and reflectometry techniques, backed up with a theoretical model for the resonant $M_{4,5}$ absorption edge of Sm and photoemission data, to establish laterally averaged chemical and valence depth profiles at the surface of SmB$_6$. We show that upon cleaving, the highly polar (001) surface of SmB$_6$ undergoes substantial chemical and valence reconstruction, resulting in boron termination and a Sm$^{3+}$ dominated sub-surface region. Whereas at room temperature, the reconstruction occurs on a time scale of less than two hours, it takes about 24 hours below 50 K. The boron termination is eventually established, irrespective of the initial termination. Our findings reconcile earlier depth resolved photoemission and scanning tunneling spectroscopy studies performed at different temperatures and are important for better control of polarity and, as a consequence, surface states in this system.
Strongly correlated Kondo insulator SmB6 is known for its peculiar low temperature residual conduction, which has recently been demonstrated to arise from a robust metallic surface state, as predicted by the theory of topological Kondo insulator (TKI). Photoemission, quantum oscillation and magnetic doping experiments have provided evidence for the Dirac-like dispersion and topological protection. Questions arise as whether signatures of spin-momentum locking and electron interaction could be resolved in transport measurements. Here we report metallic conduction of surface state down to mK temperatures with saturation behaviors suggestive of Kondo effect. We observe in the surface state the weak-antilocalization (WAL) effect that is in agreement with a spin-momentum locked metallic surface. At larger perpendicular magnetic fields, the surface state exhibits an unusual linear magnetoresistance similar to those found in Bi-based topological insulators and in graphene. (Correspondence to: [email protected])
In this study, we report the first results of the high-pressure Hall coefficient (RH) measurements in the putative topological Kondo insulator SmB6 up to 37 GPa. Below 10 GPa, our data reveal that RH(T) exhibits a prominent peak upon cooling below 20 K. Remarkably, the temperature at which surface conduction dominates coincides with the temperature of the peak in RH(T). The temperature dependent resistance and Hall coefficient can be well fitted by a two-channel model with contributions from the metallic surface and the thermally activated bulk states. When the bulk of SmB6 becomes metallic and magnetic at ~ 10 GPa, both the RH(T) peak and the resistance plateau disappear simultaneously. Our results indicate that the RH(T) peak is a fingerprint to diagnose the presence of a metallic surface state in SmB6. The high-pressure magnetic state of SmB6 is robust to 180 GPa, and no evidence of superconductivity is observed in the metallic phase.
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