Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userInfluence of external magnetic field on laser breakdown plasma in aqueous Au nanoparticles colloidal solutions
115
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Influence of permanent magnetic field up to 7.5 T on plasma emission and laser-assisted Au nanoparticles fragmentation in water is experimentally studied. It is found that presence of magnetic field causes the breakdown plasma emission to start earlier regarding to laser pulse. Field presence also accelerates the fragmentation of nanoparticles down to a few nanometers. Dependence of Au NPs fragmentation rate in water on magnetic field intensity is investigated. The results are discussed on the basis of laser-induced plasma interaction with magnetic field.
rate research
Read More
The formation of stable products of water decomposition under laser exposure of aqueous colloidal solutions of nanoparticles is experimentally studied. Laser exposure of colloidal solutions leads to formation of H2, O2, and H2O2. The dependence of the yield of these products depends on the energy density of laser radiation inside the liquid and concentration of nanoparticles. The ratio H2/O2 depends on laser fluence and is shifted towards H2. There are at least to sources of H2O2, namely, laser-induced breakdown plasma and ultrasound induced by laser pulses in the liquid. The formation of both H2 and O2 is tentatively assigned to direct dissociation of H2O molecules by electron impact from laser-induced plasma.
Formation of molecular H2 and O2 is experimentally studied under laser exposure of water colloidal solution to radiation of a Nd:YAG laser at pulse duration of 10 ns and laser fluence in the liquid of order of 100 J/cm2. It is found the partial pressure of both H2 and O2 first increases with laser exposure time and saturates at exposures of order of 1 hour. The balance between O2 and H2 content depends on the laser energy fluence in the solution and is shifted towards H2 at high fluences. Possible mechanisms of formation of the dissociation products are discussed, from direct dissociation of H2O molecules by electrons of plasma breakdown to emission of laser-induced plasma in liquid.
We report the generation of molecular hydrogen from water by laser irradiation, without any electrodes and photocatalysts. A near infrared pulsed nanosecond laser is used for exposure of colloidal solution of Au nanoparticles suspended in water. Laser exposure of the colloidal solution results in formation of plasma of laser breakdown of liquid and emission of H2. The rate of H2 emission depends critically on the energy of laser pulses. There is a certain threshold in laser fluence in liquid (around 50 J/cm2) below which plasma disappears and H2 emission stops. H2 emission from colloidal solution of Au nanoparticles in ethanol is higher than that from similar water colloid. It is found that formation of plasma and emission of H2 or D2 can be induced by laser exposure of pure liquids, either H2O or D2O, respectively. The results are interpreted as water molecules splitting by direct electron impact from breakdown plasma.
The subject of the present theoretical and experimental investigations is the effect of the external magnetic field induction on dark current and a possibility of breakdown. The generalization of the Fowler-Nordheim equation makes it possible to take into account the influence of a magnetic field parallel to the cathode surface on the field emission current. The reduction in the breakdown voltage due to the increment in electron-impact ionization was theoretical predicted. Experimentally shown that the presence of a magnetic field about a tenth as a large as the cutoff magnetic field [18] reduces the breakdown voltage by 10% to 20% for practically all cathodes no matter what their surface treatment.
Imposing an external magnetic field in short-pulse intense laser-plasma interaction is of broad scientific interest in related plasma research areas. We propose a simple method using a virtual current layer by introducing an extra current density term to simulate the external magnetic field, and demonstrate it with three-dimensional particle-in-cell simulations. The field distribution and its evolution in sub-picosecond time scale are obtained. The magnetization process takes a much longer time than that of laser-plasma interaction due to plasma diamagnetism arising from collective response. The long-time evolution of magnetic diffusion and diamagnetic current can be predicted based on a simplified analytic model in combination with simulations.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
