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The Distribution and Chemistry of H$_2$CO in the DM Tau Protoplanetary Disk

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 Added by Ryan Loomis
 Publication date 2015
  fields Physics
and research's language is English




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H$_2$CO ice on dust grains is an important precursor of complex organic molecules (COMs). H$_2$CO gas can be readily observed in protoplanetary disks and may be used to trace COM chemistry. However, its utility as a COM probe is currently limited by a lack of constraints on the relative contributions of two different formation pathways: on icy grain-surfaces and in the gas-phase. We use archival ALMA observations of the resolved distribution of H$_2$CO emission in the disk around the young low-mass star DM Tau to assess the relative importance of these formation routes. The observed H$_2$CO emission has a centrally peaked and radially broad brightness profile (extending out to 500 AU). We compare these observations with disk chemistry models with and without grain-surface formation reactions, and find that both gas and grain-surface chemistry are necessary to explain the spatial distribution of the emission. Gas-phase H$_2$CO production is responsible for the observed central peak, while grain-surface chemistry is required to reproduce the emission exterior to the CO snowline (where H$_2$CO mainly forms through the hydrogenation of CO ice before being non-thermally desorbed). These observations demonstrate that both gas and grain-surface pathways contribute to the observed H$_2$CO in disks, and that their relative contributions depend strongly on distance from the host star.



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88 - D. Semenov 2018
Context. Several sulfur-bearing molecules are observed in the interstellar medium and in comets, in strong contrast to protoplanetary disks where only CS, H$_2$CS and SO have been detected so far. Aims. We combine observations and chemical models to constrain the sulfur abundances and their sensitivity to physical and chemical conditions in the DM Tau protoplanetary disk. Methods. We obtained $0.5^{}$ ALMA observations of DM Tau in Bands 4 and 6 in lines of CS, SO, SO$_2$, OCS, CCS, H$_2$CS and H$_2$S, achieving a $sim 5$ mJy sensitivity. Using the non-LTE radiative transfer code RADEX and the forward-modeling tool DiskFit, disk-averaged CS column densities and upper limits for the other species were derived. Results. Only CS was detected with a derived column density of $sim 2-6 times 10^{12}$ cm$^{-2}$. We report a first tentative detection of SO$_2$ in DM Tau. The upper limits range between $sim 10^{11}$ and $10^{14}$ cm$^{-2}$ for the other S-bearing species. The best-fit chemical model matching these values requires a gas-phase C/O ratio of > 1 at $r sim 50-100$ au. With chemical modeling we demonstrate that sulfur-bearing species could be robust tracers of the gas-phase C/O ratio, surface reaction rates, grain size and UV intensities. Conclusions. The lack of detections of a variety of sulfur-bearing molecules in DM Tau other than CS implies a dearth of reactive sulfur in the gas phase, either through efficient freeze-out or because most of the elemental sulfur is in other large species, as found in comets. The inferred high CS/SO and CS/SO$_2$ ratios require a non-solar C/O gas-phase ratio of > 1, consistent with the recent observations of hydrocarbon rings in DM Tau. The stronger depletion of oxygen-bearing S-species compared to CS is likely linked to the low observed abundances of gaseous water in DM Tau and points to a removal mechanism of oxygen from the gas.
We study the content in S-bearing molecules of protoplanetary disks around low-mass stars. We used the new IRAM 30-m receiver EMIR to perform simultaneous observations of the $1_{10}-1_{01}$ line of H$_2$S at 168.8 GHz and $2_{23}-1_{12}$ line of SO at 99.3 GHz. We compared the observational results with predictions coming from the astrochemical code NAUTILUS, which has been adapted to protoplanetary disks. The data were analyzed together with existing CS J=3-2 observations. We fail to detect the SO and H$_2$S lines, although CS is detected in LkCa15, DM,Tau, and GO,Tau but not in MWC,480. However, our new upper limits are significantly better than previous ones and allow us to put some interesting constraints on the sulfur chemistry. Our best modeling of disks is obtained for a C/O ratio of 1.2, starting from initial cloud conditions of H density of $2times 10^5$ cm$^{-3}$ and age of $10^6$ yr. The results agree with the CS data and are compatible with the SO upper limits, but fail to reproduce the H$_2$S upper limits. The predicted H$_2$S column densities are too high by at least one order of magnitude. H$_2$S may remain locked onto grain surfaces and react with other species, thereby preventing the desorption of H$_2$S.
Aims: To constrain the ionization fraction in protoplanetary disks, we present new high-sensitivity interferometric observations of N$_2$H$^+$ in three disks surrounding DM Tau, LkCa 15, and MWC 480. Methods: We used the IRAM PdBI array to observe the N$_2$H$^+$ J=1-0 line and applied a $chi^2$-minimization technique to estimate corresponding column densities. These values are compared, together with HCO$^+$ column densities, to results of a steady-state disk model with a vertical temperature gradient coupled to gas-grain chemistry. Results: We report two dhp detections for LkCa 15 and DM Tau at the $5 sigma$ level and an upper limit for MWC 480. The column density derived from the data for LkCa 15 is much lower than previously reported. The [N$_2$H$^+$/HCO$^+$] ratio is on the order of 0.02--0.03. So far, HCO$^+$ remains the most abundant observed molecular ion in disks. Conclusions: All the observed values generally agree with the modelled column densities of disks at an evolutionary stage of a few million years (within the uncertainty limits), but the radial distribution of the molecules is not reproduced well. The low inferred concentration of N$_2$H$^+$ in three disks around low-mass and intermediate-mass young stars implies that this ion is not a sensitive tracer of the overall disk ionization fraction.
We performed a sensitive search for the ground-state emission lines of ortho- and para-water vapor in the DM Tau protoplanetary disk using the Herschel/HIFI instrument. No strong lines are detected down to 3sigma levels in 0.5 km/s channels of 4.2 mK for the 1_{10}--1_{01} line and 12.6 mK for the 1_{11}--0_{00} line. We report a very tentative detection, however, of the 1_{10}--1_{01} line in the Wide Band Spectrometer, with a strength of T_{mb}=2.7 mK, a width of 5.6 km/s and an integrated intensity of 16.0 mK km/s. The latter constitutes a 6sigma detection. Regardless of the reality of this tentative detection, model calculations indicate that our sensitive limits on the line strengths preclude efficient desorption of water in the UV illuminated regions of the disk. We hypothesize that more than 95-99% of the water ice is locked up in coagulated grains that have settled to the midplane.
We report an analysis of the dust disk around DM~Tau, newly observed with the Atacama Large Millimeter/submillimeter Array (ALMA) at 1.3 mm. The ALMA observations with high sensitivity (8.4~$mu$Jy/beam) and high angular resolution (35~mas, 5.1~au) detect two asymmetries on the ring at $rsim$20~au. They could be two vortices in early evolution, the destruction of a large scale vortex, or double continuum emission peaks with different dust sizes. We also found millimeter emissions with $sim$50~$mu$Jy (a lower limit dust mass of 0.3~$M_{rm Moon}$) inside the 3-au ring. To characterize these emissions, we modeled the spectral energy distribution (SED) of DM~Tau using a Monte Carlo radiative transfer code. We found that an additional ring at $r=$ 1~au could explain both the DM~Tau SED and the central point source. The disk midplane temperature at the 1-au ring calculated in our modeling is less than the typical water sublimation temperature of 150~K, prompting the possibility of forming small icy planets there.
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