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Tunable unconventional Kondo effect on topological insulator surfaces

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 Added by Leonid Isaev
 Publication date 2015
  fields Physics
and research's language is English




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We study Kondo physics of a spin-$frac{1}{2}$ impurity in electronic matter with strong spin-orbit interaction, which can be realized by depositing magnetic adatoms on the surface of a three-dimensional topological insulator. We show that magnetic properties of topological surface states and the very existence of Kondo screening strongly depend on details of the bulk material, and specifics of surface preparation encoded in time-reversal preserving boundary conditions for electronic wavefunctions. When this tunable Kondo effect occurs, the impurity spin is screened by purely orbital motion of surface electrons. This mechanism gives rise to a transverse magnetic response of the surface metal, and spin textures that can be used to experimentally probe signatures of a Kondo resonance. Our predictions are particularly relevant for STM measurements in ${rm Pb Te}$-class crystalline topological insulators, but we also discuss implications for other classes of topological materials.



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Proximity of two different materials leads to an intricate coupling of quasiparticles so that an unprecedented electronic state is often realized at the interface. Here, we demonstrate a resonance-type many-body ground state in graphene, a non-magnetic two-dimensional Dirac semimetal, when grown on SmB6, a Kondo insulator, via thermal decomposition of fullerene molecules. This ground state is typically observed in three-dimensional magnetic materials with correlated electrons. Above the characteristic Kondo temperature of the substrate, the electron band structure of pristine graphene remains almost intact. As temperature decreases, however, the Dirac fermions of graphene become hybridized with the Sm 4f states. Remarkable enhancement of the hybridization and Kondo resonance is observed with further cooling and increasing charge carrier density of graphene, evidencing the Kondo screening of the Sm 4f local magnetic moment by the conduction electrons of graphene at the interface. These findings manifest the realization of the Kondo effect in graphene by the proximity of SmB6 that is tuned by temperature and charge carrier density of graphene.
Proximity-induced superconductivity in three dimensional (3D) topological insulators forms a new quantum phase of matter and accommodates exotic quasiparticles such as Majorana bound states. One of the biggest drawbacks of the commonly studied 3D topological insulators is the presence of conducting bulk that obscures both surface states and low energy bound states. Introducing superconductivity in topological Kondo insulators such as SmB$_6$, however, is promising due to their true insulating bulk at low temperatures. In this work, we develop an unconventional Josephson junction by coupling superconducting Nb leads to the surface states of a SmB$_6$ crystal. We observe a robust critical current at low temperatures that responds to the application of an out-of-plane magnetic field with significant deviations from usual Fraunhofer patterns. The appearance of Shaphiro steps under microwave radiation gives further evidence of a Josephson effect. Moreover, we explore the effects of Kondo breakdown in our devices, such as ferromagnetism at the surface and anomalous temperature dependence of supercurrent. Particularly, the magnetic diffraction patterns show an anomalous hysteresis with the field sweep direction suggesting the coexistence of magnetism with superconductivity at the SmB$_6$ surface. The experimental work will advance the current understanding of topologically nontrivial superconductors and emergent states associated with such unconventional superconducting phases.
The compound SmB$_6$ is the best established realization of a topological Kondo insulator, in which a topological insulator state is obtained through Kondo coherence. Recent studies have found evidence that the surface of SmB$_6$ hosts ferromagnetic domains, creating an intrinsic platform for unidirectional ballistic transport at the domain boundaries. Here, surface-sensitive X-ray absorption (XAS) and bulk-sensitive resonant inelastic X-ray scattering (RIXS) spectra are measured at the Sm N$_{4,5}$-edge, and used to evaluate electronic symmetries, excitations and temperature dependence near the surface of cleaved samples. The XAS data show that the density of large-moment atomic multiplet states on a cleaved surface grows irreversibly over time, to a degree that likely exceeds a related change that has recently been observed in the surface 4f orbital occupation.
A necessary element for the predicted topological state in Kondo insulator SmB$_6$ is the hybridization gap which opens in this compound at low temperatures. In this work, we present a comparative study of the in-gap density of states due to Sm vacancies by Raman scattering spectroscopy and heat capacity for samples where the number of Sm vacancies is equal to or below 1 %. We demonstrate that hybridization gap is very sensitive to the presence of Sm vacancies. At the amount of vacancies above 1 % the gap fills in with impurity states and low temperature heat capacity is enhanced.
79 - Y. Sato , Z. Xiang , Y. Kasahara 2021
Kondo insulators have recently aroused great interest because they are promising materials that host a topological insulator state caused by the strong electron interactions. Moreover, recent observations of the quantum oscillations in the insulating state of Kondo insulators have come as a great surprise. Here, to investigate the surface electronic state of a prototype Kondo insulator YbB$_{12}$, we measured transport properties of single crystals and microstructures. In all samples, the temperature dependence of the electrical resistivity is insulating at high temperatures and the resistivity exhibits a plateau at low temperatures. The magnitude of the plateau value decreases with reducing sample thickness, which is quantitatively consistent with the surface electronic conduction in the bulk insulating YbB$_{12}$. Moreover, the magnetoresistance of the microstructures exhibits a weak-antilocalization effect at low field. These results are consistent with the presence of topologically protected surface state, suggesting that YbB$_{12}$ is a candidate material of the topological Kondo insulator. The high field resistivity measurements up to $mu_0H$ = 50 T of the microstructures provide supporting evidence that the quantum oscillations of the resistivity in YbB$_{12}$ occurs in the insulating bulk.
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