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Multilayer black phosphorus as broadband saturable absorber for pulsed lasers from 1 to 2.7 {mu}m wavelength

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 Added by Zhipeng Qin
 Publication date 2015
  fields Physics
and research's language is English




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It attracts wide interest to seek universe saturable absorber covering wavelengths from near infrared to mid-infrared band. Multilayer black phosphorus, with variable direct bandgap (0.3-2 eV) depending on the layer number, becomes a good alternative as a universe saturable absorber for pulsed lasers. In this contribution, we first experimentally demonstrated broadband saturable absorption of multilayer black phosphorus from 1 {mu}m to 2.7 {mu}m wavelength. With the as-fabricated black phosphorus nanoflakes as saturable absorber, stable Q-switching operation of bulk lasers at 1.03 {mu}m, 1.93 {mu}m, 2.72 {mu}m were realized, respectively. In contrast with large-bandgap semiconducting transition metal dichalcogenides, such as MoS2, MoSe2, multilayer black phosphorus shows particular advantage at the long wavelength regime thanks to its narrow direct bandgap. This work will open promising optoelectronic applications of black phosphorus in mid-infrared spectral region and further demonstrate that BP may fill the gap of between zero-bandgap graphene and large-bandgap TMDs.



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Black phosphorus, a newly emerged two-dimensional material, has attracted wide attention as novel photonic material. Here, multi-layer black phosphorus is successfully fabricated by liquid phase exfoliation method. By employing black phosphorus as saturable absorber, we demonstrate a passively Q-switched Er-doped ZBLAN fiber laser at the wavelength of 2.8 {mu}m. The modulation depth and saturation fluence of the black phosphorus saturable absorber are measured to be 15% and 9 {mu}J/cm2, respectively. The Q-switched fiber laser delivers a maximum average power of 485 mW with corresponding pulse energy of 7.7 {mu}J and pulse width of 1.18 {mu}s at repetition rate of 63 kHz. To the best of our knowledge, this is the first time to demonstrate that black phosphorus can realize Q-switching of 2.8-{mu}m fiber laser. Our research results show that black phosphorus is a promising saturable absorber for mid-infrared pulsed lasers.
We present a numerical study of the collective dynamics in a population of coupled excitable lasers with saturable absorber. At variance with previous studies where real-valued (lossy) coupling was considered, we focus here on the purely imaginary coupling (evanescent wave coupling). We show that evanescently coupled excitable lasers synchronize in a more efficient way compared to the lossy coupled ones. Furthermore we show that out-of-diagonal disorder-induced localization of excitability takes place for imaginary coupling too, but it can be frustrated by nonvanishing linewidth enhancement factor.
We demonstrate that the intrinsic properties of monolayer graphene allow it to act as a more effective saturable absorber for mode-locking fiber lasers compared to multilayer graphene. The absorption of monolayer graphene can be saturated at lower excitation intensity compared to multilayer graphene, graphene with wrinkle-like defects, and functionalized graphene. Monolayer graphene has a remarkable large modulation depth of 95.3%, whereas the modulation depth of multilayer graphene is greatly reduced due to nonsaturable absorption and scattering loss. Picoseconds ultrafast laser pulse (1.23 ps) can be generated using monolayer graphene as saturable absorber. Due to the ultrafast relaxation time, larger modulation depth and lower scattering loss of monolayer graphene, it performs better than multilayer graphene in terms of pulse shaping ability, pulse stability and output energy.
Based on self - consistent field theory we study a soliton generation in cw solid-state lasers with semiconductor saturable absorber. Various soliton destabilizations, i.e. the switch from femtosecond to picosecond generation (picosecond collapse), an automodulation regime, breakdown of soliton generation and hysteresis behavior, are predicted.
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