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Register a new userCompressibility and pressure correlations in isotropic solids and fluids
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Presenting simple coarse-grained models of isotropic solids and fluids in $d=1$, $2$ and $3$ dimensions we investigate the correlations of the instantaneous pressure and its ideal and excess contributions at either imposed pressure (NPT-ensemble, $lambda=0$) or volume (NVT-ensemble, $lambda=1$) and for more general values of the dimensionless parameter $lambda$ characterizing the constant-volume constraint.
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Pressure is the mechanical force per unit area that a confined system exerts on its container. In thermal equilibrium, it depends only on bulk properties (density, temperature, etc.) through an equation of state. Here we show that in a wide class of active systems the pressure depends on the precise interactions between the active particles and the confining walls. In general, therefore, active fluids have no equation of state, their mechanical pressures exhibit anomalous properties that defy the familiar thermodynamic reasoning that holds in equilibrium. The pressure remains a function of state, however, in some specific and well-studied active models that tacitly restrict the character of the particle-wall and/or particle-particle interactions.
We study the velocity autocorrelation function (VACF) of a driven granular fluid in the stationary state in 3 dimensions. As the critical volume fraction of the glass transition in the corresponding elastic system is approached, we observe pronounced cage effects in the VACF as well as a strong decrease of the diffusion constant. At moderate densities the VACF is shown to decay algebraically in time (t^{-3/2}) like in a molecular fluid, as long as the driving conserves momentum locally.
Self-diffusion and radial distribution functions are studied in a strongly confined Lennard-Jones fluid. Surprisingly, in the solid-liquid phase transition region, where the system exhibits dynamic coexistence, the self-diffusion constants are shown to present up to three-fold variations from solid to liquid phases at fixed temperature, while the radial distribution function corresponding to both the liquid and the solid phases are essentially indistinguishable.
The equilibrium properties of a Janus fluid made of two-face particles confined to a one-dimensional channel are revisited. The exact Gibbs free energy for a finite number of particles $N$ is exactly derived for both quenched and annealed realizations. It is proved that the results for both classes of systems tend in the thermodynamic limit ($Ntoinfty$) to a common expression recently derived (Maestre M A G and Santos A 2020 J Stat Mech 063217). The theoretical finite-size results are particularized to the Kern--Frenkel model and confirmed by Monte Carlo simulations for quenched and (both biased and unbiased) annealed systems.
The terminology granular matter refers to systems with a large number of hard objects (grains) of mesoscopic size ranging from millimeters to meters. Geological examples include desert sand and the rocks of a landslide. But the scope of such systems is much broader, including powders and snow, edible products such a seeds and salt, medical products like pills, and extraterrestrial systems such as the surface regolith of Mars and the rings of Saturn. The importance of a fundamental understanding for granular matter properties can hardly be overestimated. Practical issues of current concern range from disaster mitigation of avalanches and explosions of grain silos to immense economic consequences within the pharmaceutical industry. In addition, they are of academic and conceptual importance as well as examples of systems far from equilibrium. Under many conditions of interest, granular matter flows like a normal fluid. In the latter case such flows are accurately described by the equations of hydrodynamics. Attention is focused here on the possibility for a corresponding hydrodynamic description of granular flows. The tools of nonequilibrium statistical mechanics, developed over the past fifty years for fluids composed of atoms and molecules, are applied here to a system of grains for a fundamental approach to both qualitative questions and practical quantitative predictions. The nonlinear Navier-Stokes equations and expressions for the associated transport coefficients are obtained.
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