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Register a new userOxygen-annealing effects on superconductivity in polycrystalline Fe1-xTe1-ySey
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Superconductivity in anti-PbO-type iron chalcogenides Fe1-xTe1-ySey (x = 0, 0.1, y = 0.1 0.4) depends on the amount (x) of interstitial iron atoms located between the FeTe1-ySey layers. Non-superconducting samples of nominal Fe1.1Te1-ySey convert to superconductors with critical temperatures up to 14 K after annealing at 300{deg}C in an oxygen atmosphere. The process is irreversible upon subsequent hydrogen annealing. Magnetic measurements are consistent with the formation of iron oxides suggesting that oxygen annealing preferably extracts interstitial iron from Fe1-xTe1-ySey which interfere with superconductivity.
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We present measurements of resistivity and thermopower of Fe1+xTe1-ySey single crystalline samples with y=0, 0.1, 0.2, 0.3 and 0.45 in zero field and in a magnetic field B=8T. We propose a qualitative analysis of the temperature behavior of S, where the samples are described as almost compensated semimetals: different electron and hole bands with similar carrier concentrations compete and their relative contribution to the thermoelectric transport depends on the respective filling, mobility and coupling with phonons. For y>=0.2, superconductivity occurs and the optimum Se-doping level for a maximum Tc of 13 K turns out to be y=0.3. At low temperatures, evidence of a contribution to S by an excitation-drag mechanism is found, while at high temperatures a strikingly flat behavior of S is explained within a narrow band Hubbard model. The support of a theoretical background which could provide band resolved parameters such as carrier density, mobility and electron-phonon coupling of each band would allow to extract from our data valuable quantitative information on the transport and superconducting mechanisms of these iron chalcogenides.
Effects of iodine annealing to induce bulk superconductivity in Fe1+yTe0.6Se0.4 have been systematically studied by changing the molar ratio of iodine to the sample and annealing temperature. The optimal condition to induce bulk superconductivity with Tc ~14.5 K and self-field Jc(2 K) ~ 5x10^5 A/cm2 is found to be a molar ratio of iodine of 5-7 % at the annealing temperature of 400 C. Furthermore, the fact that no compounds containing iodine are detected in the crystal and a significant amount of FeTe2 is produced after the iodine annealing strongly indicate that the excess iron is consumed to form FeTe2 and iodine works as a catalyst in this process.
We have systematically investigated and compared different methods to induce superconductivity in iron chalcogenide Fe1+yTe0.6Se0.4 including annealing in vacuum, N2, O2, I2 atmosphere, and immersing samples into acid and alcoholic beverages. Vacuum and N2 annealing are proved to be ineffective to induce superconductivity in Fe1+yTe0.6Se0.4 single crystal. O2 and I2 annealing, acid and alcoholic beverages can induce superconductivity by oxidizing the excess Fe in the sample. Superconductivity in O2 annealed sample is in bulk nature, while I2, acid and alcoholic beverages can only induce superconductivity near the surface. By comparing different effects of O2, I2, acid and alcoholic beverages, we propose a scenario to explain how the superconductivity is induced in the non-superconducting as-grown Fe1+yTe0.6Se0.4.
We have investigated uniaxial and hydrostatic pressure effects on superconductivity in Fe1.07Te0.88S0.12 through magnetic-susceptibility measurements down to 1.8 K. The superconducting transition temperature Tc is enhanced by out-of-plane pressure (uniaxial pressure along the c-axis); the onset temperature of the superconductivity reaches 11.8 K at 0.4 GPa. In contrast, Tc is reduced by in-plane pressure (uniaxial pressure along the ab-plane) and hydrostatic pressure. Taking into account these results, it is inferred that the superconductivity of Fe1+yTe1-xSx is enhanced when the lattice constant c considerably shrinks. This implies that the relationship between Tc and the anion height for Fe1+yTe1-xSx is similar to that applicable to most iron-based superconductors. We consider the reduction of Tc by hydrostatic pressure due to suppression of spin fluctuations because the system moves away from antiferromagnetic ordering, and the enhancement of Tc by out-of-plane pressure due to the anion height effect on Tc.
For the Fe-based superconductor Fe{1+y}Te{1-x}S{x}, superconductivity is induced by annealing treatment in oxygen atmosphere, whereas as-grown samples do not show superconductivity. We have investigated the sample-size dependence of O2-annealing effects in Fe1.01Te0.91S0.09. The annealing conditions are fixed to be 1 atm, 200 C, and 2 hours. We have carried out magnetic susceptibility and specific heat measurements in order to evaluate the superconducting volume fraction. We have found that Fe{1+y}Te{1-x}S{x} has an optimal size for the induction of bulk superconductivity by O2 annealing. Our results indicate that O2 annealing is probably effective near the surface of samples over a length of a few tens of micro meters.
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