Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userThe Nitrogen Budget of Earth
103
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We comprehensively compile and review N content in geologic materials to calculate a new N budget for Earth. Using analyses of rocks and minerals in conjunction with N-Ar geochemistry demonstrates that the Bulk Silicate Earth (BSE) contains sim7pm4 times present atmospheric N (4times10^18 kg N, PAN), with 27pm16times10^18 kg N. Comparison to chondritic composition, after subtracting N sequestered into the core, yields a consistent result, with BSE N between 17pm13times10^18 kg to 31pm24times10^18 kg N. In the chondritic comparison we calculate a N mass in Earths core (180pm110 to 300pm180times10^18 kg) and discuss the Moon as a proxy for the early mantle. Significantly, we find the majority of the planetary budget of N is in the solid Earth. The N estimate herein precludes the need for a missing N reservoir. Nitrogen-Ar systematics in mantle rocks and basalts identify two mantle reservoirs: MORB-source like (MSL) and high-N. High-N mantle is composed of young, N-rich material subducted from the surface and is identified in OIB and some xenoliths. In contrast, MSL appears to be made of old material, though a component of subducted material is evident in this reservoir as well. Using our new budget, we calculate a {delta}15N value for BSE plus atmosphere of sim2permil. This value should be used when discussing bulk Earth N isotope evolution. Additionally, our work indicates that all surface N could pass through the mantle over Earth history, and the mantle may act as a long-term sink for N. Since N acts as a tracer of exchange between the atmosphere, oceans, and mantle over time, clarifying its distribution in the Earth is critical for evolutionary models concerned with Earth system evolution. We suggest that N be viewed in the same vein as carbon: it has a fast, biologically mediated cycle which connects it to a slow, tectonically-controlled geologic cycle.
rate research
Read More
We predict that cyanoacetylene (HC$_3$N) is produced photochemically in the atmosphere of GJ 1132 b in abundances detectable by the James Webb Space Telescope (JWST), assuming that the atmosphere is as described by Swain et al. (2021). First, we construct line list and cross-sections for HC$_3$N. Then we apply these cross-sections and the model atmosphere of Swain et al. (2021) to a radiative transfer model in order to simulate the transmission spectrum of GJ 1132 b as it would be seen by JWST, accounting for the uncertainty in the retrieved abundances. We predict that cyanoacetylene features at various wavelengths, with a clear lone feature at 4.5 $mu$m, observable by JWST after four transits. This feature persists within the $1-sigma$ uncertainty of the retrieved abundances of HCN and CH$_4$.
The large day--night temperature contrast of WASP-43b has so far eluded explanation. We revisit the energy budget of this planet by considering the impact of reflected light on dayside measurements, and the physicality of implied nightside temperatures. Previous analyses of the infrared eclipses of WASP-43b have assumed reflected light from the planet is negligible and can be ignored. We develop a phenomenological eclipse model including reflected light, thermal emission, and water absorption, and use it to fit published Hubble and Spitzer eclipse data. We infer a near-infrared geometric albedo of 27$pm1%$ and a cooler dayside temperature of $1527 pm 10~$K. Additionally, we perform lightcurve inversion on the three published orbital phase curves of WASP-43b and find that each requires unphysical, negative flux on the nightside. By requiring non-negative brightnesses at all longitudes, we correct the unphysical parts of the maps and obtain a much hotter nightside effective temperature of $1076 pm 11~$K. The cooler dayside and hotter nightside suggests a heat recirculation efficiency of $47%$ for WASP-43b, essentially the same as for HD 209458b, another hot Jupiter with nearly the same temperature. Our analysis therefore reaffirms the trend that planets with lower irradiation temperatures have more efficient day-night heat transport. Moreover, we note that 1) reflected light may be significant for many near-IR eclipse measurements of hot Jupiters, and 2) phase curves should be fit with physically possible longitudinal brightness profiles --- it is insufficient to only require that the disk-integrated lightcurve be non-negative.
Solar photospheric abundances of refractory elements mirror the Earths to within ~10 mol% when normalized to the dominant terrestrial planet-forming elements Mg, Si and Fe. This allows for the adoption of Solar composition as an order-of-magnitude proxy for Earths. It is not known, however, the degree to which this mirroring of stellar and terrestrial planet abundances holds true for other star-planet systems without determination of the composition of initial planetesimals via condensation sequence calculations and post condensation processes. We present the open-source Arbitrary Composition Condensation Sequence calculator (ArCCoS) to assess how the elemental composition of a parent star affects that of the planet-building material, including the extent of oxidation within the planetesimals. We demonstrate the utility of ArCCoS by showing how variations in the abundance of the stellar refractory elements Mg and Si affect the condensation of oxygen, a controlling factor in the relative proportions of planetary core and silicate mantle material. This, thereby, removes significant degeneracy in the interpretation of the structures of exoplanets as well as providing observational tests for the validity of this model.
Understanding the total flux and polarization signals of Earth-like planets and their spectral and temporal variability is essential for the future characterization of such exoplanets. We provide computed total (F) and linearly (Q and U) and circularly (V) polarized fluxes, and the degree of polarization P of sunlight that is reflected by a model Earth, to be used for instrument designs, optimizing observational strategies, and/or developing retrieval algorithms. We modeled a realistic Earth-like planet using one year of daily Earth-observation data: cloud parameters (distribution, optical thickness, top pressure, and particle effective radius), and surface parameters (distribution, surface type, and albedo). The Stokes vector of the disk-averaged reflected sunlight was computed for phase angles alpha from 0 to 180 degrees, and for wavelengths lambda from 350 to 865 nm. The total flux F is one order of magnitude higher than the polarized flux Q, and Q is two and four orders of magnitude higher than U and V, respectively. Without clouds, the peak-to-peak daily variations due to the planetary rotation increase with increasing lambda for F, Q, and P, while they decrease for U and V. Clouds modify but do not completely suppress the variations that are due to rotating surface features. With clouds, the variation in F increases with increasing lambda, while in Q, it decreases with increasing lambda, except at the largest phase angles. In earlier work, it was shown that with oceans, Q changes color from blue through white to red. The alpha where the color changes increases with increasing cloud coverage. Here, we show that this unique color change in Q also occurs when the oceans are partly replaced by continents, with or without clouds. The degree of polarization P shows a similar color change. Our computed fluxes and degree of polarization will be made publicly available.
This brief review will discuss the current knowledge on the origin and evolution of the nitrogen atmospheres of the icy bodies in the solar system, particularly of Titan, Triton and Pluto. An important tool to analyse and understand the origin and evolution of these atmospheres can be found in the different isotopic signatures of their atmospheric constituents. The $^{14}$N/$^{15}$N ratio of the N$_2$-dominated atmospheres of these bodies serve as a footprint of the building blocks from which Titan, Triton and Pluto originated and of the diverse fractionation processes that shaped these atmospheres over their entire evolution. Together with other measured isotopic and elemental ratios such as $^{12}$C/$^{13}$C or Ar/N these atmospheres can give important insights into the history of the icy bodies in the solar system, the diverse processes that affect their N$_2$-dominated atmospheres, and the therewith connected solar activity evolution. Titans gaseous envelope most likely originated from ammonia ices with possible contributions from refractory organics. Its isotopic signatures can yet be seen in the - compared to Earth - comparatively heavy $^{14}$N/$^{15}$N ratio of 167.7, even though this value slightly evolved over its history due to atmospheric escape and photodissociation of N$_2$. The origin and evolution of Plutos and Tritons tenuous nitrogen atmospheres remain unclear, even though it might be likely that their atmospheres originated from the protosolar nebula or from comets. An in-situ space mission to Triton such as the recently proposed Trident mission, and/or to the ice giants would be a crucial cornerstone for a better understanding of the origin and evolution of the icy bodies in the outer solar system and their atmospheres in general.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
