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Register a new userSpiral precipitation patterns in confined chemical gardens
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Chemical gardens are mineral aggregates that grow in three dimensions with plant-like forms and share properties with self-assembled structures like nano-scale tubes, brinicles or chimneys at hydrothermal vents. The analysis of their shapes remains a challenge, as their growth is influenced by osmosis, buoyancy and reaction-diffusion processes. Here we show that chemical gardens grown by injection of one reactant into the other in confined conditions feature a wealth of new patterns including spirals, flowers, and filaments. The confinement decreases the influence of buoyancy, reduces the spatial degrees of freedom and allows analysis of the patterns by tools classically used to analyze two-dimensional patterns. Injection moreover allows the study in controlled conditions of the effects of variable concentrations on the selected morphology. We illustrate these innovative aspects by characterizing quantitatively, with a simple geometrical model, a new class of self-similar logarithmic spirals observed in a large zone of the parameter space.
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We investigate a number of complex patterns driven by the electro-convection instability in a planarly aligned layer of a nematic liquid crystal. They are traced back to various secondary instabilities of the ideal roll patterns bifurcating at onset of convection, whereby the basic nemato-hydrodynamic equations are solved by common Galerkin expansion methods. Alternatively these equations are systematically approximated by a set of coupled amplitude equations. They describe slow modulations of the convection roll amplitudes, which are coupled to a flow field component with finite vorticity perpendicular to the layer and to a quasi-homogeneous in-plane rotation of the director. It is demonstrated that the Galerkin stability diagram of the convection rolls is well reproduced by the corresponding one based on the amplitude equations. The main purpose of the paper is, however, to demonstrate that their direct numerical simulations match surprisingly well new experiments, which serves as a convincing test of our theoretical approach.
Optical methods are most convenient to analyze spatially periodic patterns with wavevector $bm q$ in a thin layer of a nematic liquid crystal. In the standard experimental setup a beam of parallel light with a short wavelength $lambda ll 2 pi/q$ passes the nematic layer. Recording the transmitted light the patterns are either directly visualized by shadowgraphy or characterized more indirectly by the diffraction fringes due to the optical grating effects of the pattern. In this work we present a systematic short-wavelength analysis of these methods for the commonly used planar orientation of the optical axis of liquid crystal at the confining surfaces. Our approach covers general 3D experimental geometries with respect to the relative orientation of $bm q$ and of the wavevector $bm k$ of the incident light. In particular the importance of phase grating effects is emphasized, which are not accessible in a pure geometric optics approach. Finally, as a byproduct we present also an optical analysis of convection rolls in Rayleigh-Benard convection, where the refraction index of the fluid is isotropic in contrast to its uniaxial symmetry in nematic liquid crystals. Our analysis is in excellent agreement with an earlier physical optics approach by Trainoff and Cannell [Physics of Fluids {bf 14}, 1340 (2002)], which is restricted to a 2D geometry and technically much more demanding.
The effect of superimposed ac and dc electric fields on the formation of electroconvection and flexoelectric patterns in nematic liquid crystals was studied. For selected ac frequencies an extended standard model of the electro-hydrodynamic instabilities was used to characterize the onset of pattern formation in the two-dimensional parameter space of the magnitudes of the ac and dc electric field components. Numerical as well as approximate analytical calculations demonstrate that depending on the type of patterns and on the ac frequency, the combined action of ac and dc fields may either enhance or suppress the formation of patterns. The theoretical predictions are qualitatively confirmed by experiments in most cases. Some discrepancies, however, seem to indicate the need to extend the theoretical description.
The transport of polyelectrolytes confined by oppositely charged surfaces and driven by a constant electric field is of interest in studies of DNA separation according to size. Using molecular dynamics simulations that include surface polarization effect, we find that the mobilities of the polyelectrolytes and their counterions change non-monotonically with the confinement surface charge density. For an optimum value of the confinement charge density, efficient separation of polyelectrolytes can be achieved over a wide range of polyelectrolyte charge due to the differential friction imparted by the oppositely charged confinement on the polyelectrolyte chains. Furthermore, by altering the placement of the charged confinement counterions, enhanced polyelectrolyte separation can be achieved by utilizing surface polarization effect due to dielectric mismatch between the media inside and outside the confinement.
Thin elastic membranes form complex wrinkle patterns when put on substrates of different shapes. Such patterns continue to receive attention across science and engineering. This is due, in part, to the promise of lithography-free micropatterning, but also to the observation that similar patterns arise in biological systems from growth. The challenge is to explain the patterns in any given setup, even when they fail to be robust. Building on the theoretical foundation of [Tobasco, to appear in Arch. Ration. Mech. Anal., arXiv:1906.02153], we derive a complete and simple rule set for wrinkles in the model system of a curved shell on a liquid bath. Our rules apply to shells whose initial Gaussian curvatures are of one sign, such as cutouts of saddles and spheres. They predict the surprising coexistence of orderly wrinkles alongside disordered regions where the response appears stochastic, which we confirm in experiment and simulation. They also unveil the role of the shells medial axis, a distinguished locus of points that we show is a basic driver in pattern selection. Finally, they explain how the sign of the shells initial curvature dictates the presence or lack of disorder. Armed with our simple rules, and the methodology underlying them, one can anticipate the creation of designer wrinkle patterns.
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