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Broadband Linear-Dichroic Photodetector in a Black Phosphorus Vertical p-n Junction

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 Added by Hongtao Yuan
 Publication date 2014
  fields Physics
and research's language is English




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The ability to detect light over a broad spectral range is central for practical optoelectronic applications, and has been successfully demonstrated with photodetectors of two-dimensional layered crystals such as graphene and MoS2. However, polarization sensitivity within such a photodetector remains elusive. Here we demonstrate a linear-dichroic broadband photodetector with layered black phosphorus transistors, using the strong intrinsic linear dichroism arising from the in-plane optical anisotropy with respect to the atom-buckled direction, which is polarization sensitive over a broad bandwidth from 400 nm to 3750 nm. Especially, a perpendicular build-in electric field induced by gating in black phosphorus transistors can spatially separate the photo-generated electrons and holes in the channel, effectively reducing their recombination rate, and thus enhancing the efficiency and performance for linear dichroism photodetection. This provides new functionality using anisotropic layered black phosphorus, thereby enabling novel optical and optoelectronic device applications.



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81 - Leandro Seixas 2021
Black phosphorus is a material with an intrinsic anisotropy in electronic and optical properties due to its puckered honeycomb lattice. Optical absorption is different for incident light with linear polarization in the armchair and zigzag directions (linear dichroism). These directions are also used in the cuts of materials to create black phosphorus nanoribbons. Edges of nanoribbons usually have small reconstruction effects, with minor electronic effects. Here, we show a reconstruction of the armchair edge that introduces a new valence band, which flattens the puckered lattice and increases the linear dichroism extrinsically in the visible spectrum. This enhancement in linear dichroism is explained by the polarization selection rule, which considers the parity of the wave function to a reflection plane. The flattened-edge reconstruction originates from the inversion of chirality of the P atoms at the edges and significantly alters the entire optical absorption of the material. The flattened edges have potential applications in pseudospintronics, photodetectors and might provide new functionalities in optoelectronic and photonic devices.
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