We study a wide range of neutral atoms and ions suitable for ultra-precise atomic optical clocks with naturally suppressed black body radiation shift of clock transition frequency. Calculations show that scalar polarizabilities of clock states cancel each other for at least one order of magnitude for considered systems. Results for calculations of frequencies, quadrupole moments of the states, clock transition amplitudes and natural widths of upper clock states are presented.
In the last ten years extraordinary results in time and frequency metrology have been demonstrated. Frequency-stabilization techniques for continuous-wave lasers and femto-second optical frequency combs have enabled a rapid development of frequency standards based on optical transitions in ultra-cold neutral atoms and trapped ions. As a result, todays best performing atomic clocks tick at an optical rate and allow scientists to perform high-resolution measurements with a precision approaching a few parts in $10^{18}$. This paper reviews the history and the state of the art in optical-clock research and addresses the implementation of optical clocks in a possible future redefinition of the SI second as well as in tests of fundamental physics.
The blackbody radiation shift of the Ga$^+$ $4s^2 ^1S^e_0 to 4s4p ^3P^o_0$ clock transition is computed to be $-$$0.0140 pm 0.0048$ Hz at 300 K. The small shift is consistent with the blackbody shifts of the clock transitions of other group III ions which are of a similar size. The polarizabilities of the Ga$^+$ $4s^2 ^1S^e_0$, $4s4p ^3P^o_0$, and $4s4p ^1P^o_1$ states were computed using the configuration interaction method with an underlying semi-empirical core potential. A byproduct of the analysis involved large scale calculations of the low lying spectrum and oscillator strengths of the Ga$^{2+}$ ion.
We evaluated the static and dynamic polarizabilities of the 5s^2 ^1S_0 and 5s5p ^3P_0^o states of Sr using the high-precision relativistic configuration interaction + all-order method. Our calculation explains the discrepancy between the recent experimental 5s^2 ^1S_0 - 5s5p ^3P_0^o dc Stark shift measurement Delta alpha = 247.374(7) a.u. [Middelmann et. al, arXiv:1208.2848 (2012)] and the earlier theoretical result of 261(4) a.u. [Porsev and Derevianko, Phys. Rev. A 74, 020502R (2006)]. Our present value of 247.5 a.u. is in excellent agreement with the experimental result. We also evaluated the dynamic correction to the BBR shift with 1 % uncertainty; -0.1492(16) Hz. The dynamic correction to the BBR shift is unusually large in the case of Sr (7 %) and it enters significantly into the uncertainty budget of the Sr optical lattice clock. We suggest future experiments that could further reduce the present uncertainties.
We report the theoretical evaluations of the static scalar polarizability of the 133Cs ground state and of the black body radiation shift induced on the transition frequency between the two hyperfine levels with m_F = 0. This shift is of fundamental importance in the evaluation of the accuracy of the primary frequency standards based on atomic fountains and employed in the realization of the SI second in the International Atomic Time (TAI) scale at the level of 1e-15. Our computed value for the polarizability is alpha_0=6.600(16)e-39 Cm^2/V in agreement at the level of 1e-3 with recent theoretical and experimental values. As regards the black body radiation shift we .nd for the relative hyper.ne transition frequency beta=-1.49 (7)e-14 at T = 300 K in agreement with frequency measurements reported by our group and by Bauch and Schroder [Phys. Rev. Lett. 78, 622, (1997)]. This value is lower by 2e-15 than that obtained with measurements based on the dc Stark shift and than the value commonly accepted up to now.
We propose a space-based gravitational wave detector consisting of two spatially separated, drag-free satellites sharing ultra-stable optical laser light over a single baseline. Each satellite contains an optical lattice atomic clock, which serves as a sensitive, narrowband detector of the local frequency of the shared laser light. A synchronized two-clock comparison between the satellites will be sensitive to the effective Doppler shifts induced by incident gravitational waves (GWs) at a level competitive with other proposed space-based GW detectors, while providing complementary features. The detected signal is a differential frequency shift of the shared laser light due to the relative velocity of the satellites, and the detection window can be tuned through the control sequence applied to the atoms internal states. This scheme enables the detection of GWs from continuous, spectrally narrow sources, such as compact binary inspirals, with frequencies ranging from ~3 mHz - 10 Hz without loss of sensitivity, thereby bridging the detection gap between space-based and terrestrial optical interferometric GW detectors. Our proposed GW detector employs just two satellites, is compatible with integration with an optical interferometric detector, and requires only realistic improvements to existing ground-based clock and laser technologies.