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Register a new userCharge-density wave, superconductivity and $f$-electron valence instability in EuBiS$_2$F
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Superconductivity (SC) and charge-density wave (CDW) are two contrasting yet relevant collective electronic states which have received sustained interest for decades. Here we report that, in a layered europium bismuth sulfofluoride, EuBiS$_2$F, a CDW-like transition occurs at 280 K, below which SC emerges at 0.3 K, without any extrinsic doping. The Eu ions were found to exhibit an anomalously temperature-independent mixed valence of about +2.2, associated with the formation of CDW. The mixed valence of Eu gives rise to self electron doping into the conduction bands mainly consisting of the in-plane Bi-6$p$ states, which in turn brings about the CDW and SC. In particular, the electronic specific-heat coefficient is enhanced by ~ 50 times, owing to the significant hybridizations between Eu-4$f$ and Bi-6$p$ electrons, as verified by band-structure calculations. Thus, EuBiS$_2$F manifests itself as an unprecedented material that simultaneously accommodates SC, CDW and $f$-electron valence instability.
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We present a pressure study of the electrical resistivity, AC magnetic susceptibility and powder x-ray diffraction (XRD) of the newly discovered BiS$_2$-based superconductor EuBiS$_2$F. At ambient pressure, EuBiS$_2$F shows an anomaly in the resistivity at around $T_0approx 280$ K and a superconducting transition at $T_capprox 0.3$ K. Upon applying hydrostatic pressure, there is little change in $T_0$ but the amplitude of the resistive anomaly is suppressed, whereas there is a dramatic enhancement of $T_c$ from 0.3 K to about 8.6 K at a critical pressure of $p_c$ $approx{1.4}$ GPa. XRD measurements confirm that this enhancement of $T_c$ coincides with a structural phase transition from a tetragonal phase ($P4/nmm$) to a monoclinic phase ($P2_1$/m), which is similar to that observed in isostructural LaO$_{0.5}$F$_{0.5}$BiS$_2$. Our results suggest the presence of two different superconducting phases with distinct crystal structures in EuBiS$_2$F, which may be a general property of this family of BiS$_2$-based superconductors.
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