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Register a new userTuning the magnetic and structural phase transitions of PrFeAsO via Fe/Ru spin dilution
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Neutron diffraction and muon spin relaxation measurements are used to obtain a detailed phase diagram of Pr(Fe,Ru)AsO. The isoelectronic substitution of Ru for Fe acts effectively as spin dilution, suppressing both the structural and magnetic phase transitions. The temperature of the tetragonal-orthorhombic structural phase transition decreases gradually as a function of x. Slightly below the transition temperature coherent precessions of the muon spin are observed corresponding to static magnetism, possibly reflecting a significant magneto-elastic coupling in the FeAs layers. Short range order in both the Fe and Pr moments persists for higher levels of x. The static magnetic moments disappear at a concentration coincident with that expected for percolation of the J1-J2 square lattice model.
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We present results of transport and magnetic properties and heat capacity measurements on polycrystalline CeFeAsO, PrFeAsO, and NdFeAsO. These materials undergo structural phase transitions, spin density wave-like magnetic ordering of small moments on iron, and antiferromagnetic ordering of rare earth moments. The temperature dependence of the electrical resistivity, Seebeck coefficient, thermal conductivity, Hall coefficient, and magnetoresistance are reported. The magnetic behavior of the materials have been investigated using Mossbauer spectroscopy and magnetization measurements. Transport and magnetic properties are affected strongly by the structural and magnetic transitions, suggesting significant changes in the band structure and/or carrier mobilities occur, and phonon-phonon scattering is reduced upon transformation to the low temperature structure. Results are compared to recent reports for LaFeAsO, and systematic variations in properties as the identity of Ln is changed are observed and discussed. As Ln progresses across the rare-earth series from La to Nd, an increase in the hole contributions to Seebeck coefficient, and increases in magnetoresistance and the Hall coefficient are observed in the low temperature phase. Analysis of hyperfine fields at the iron nuclei determined from Mossbauer spectra indicates that the moment on Fe in the orthorhombic phase is nearly independent of the identity of Ln, in apparent contrast to reports of powder neutron diffraction refinements.
We use bulk magnetic susceptibility, electronic specific heat, and neutron scattering to study structural and magnetic phase transitions in Fe$_{1+y}$Se% $_x$Te$_{1-x}$. Fe$_{1.068}$Te exhibits a first order phase transition near 67 K with a tetragonal to monoclinic structural transition and simultaneously develops a collinear antiferromagnetic (AF) order responsible for the entropy change across the transition. Systematic studies of FeSe$%_{1-x}$Te$_x$ system reveal that the AF structure and lattice distortion in these materials are different from those of FeAs-based pnictides. These results call into question the conclusions of present density functional calculations, where FeSe$_{1-x}$Te$_x$ and FeAs-based pnictides are expected to have similar Fermi surfaces and therefore the same spin-density-wave AF order.
We have studied the magnetism of the Pr3+ ions in PrFeAsO_1-xF_x (x = 0; 0.15) and its interaction with the Fe magnetic order (for x = 0). Specific heat data confirm the presence of a first excited crystal electric field (CEF) level around 3.5 meV in the undoped compound PrFeAsO. This finding is in agreement with recent neutron scattering experiments. The doped compound is found to have a much lower first CEF splitting of about 2.0 meV. The Pr ordering in PrFeAsO gives rise to large anomalies in the specific heat and the thermal expansion coefficient. In addition, a field-induced transition is found at low temperatures that is most pronounced for the magnetostriction coefficient. This transition, which is absent in the doped compound, is attributed to a reversal of the Fe spin canting as the antiferromagnetic Pr order is destroyed by the external magnetic field.
We have investigated structural and magnetic phase transitions under high pressures in a quaternary rare earth transition metal arsenide oxide NdCoAsO compound that is isostructural to high temperature superconductor NdFeAsO. Four-probe electrical resistance measurements carried out in a designer diamond anvil cell show that the ferromagnetic Curie temperature and anti-ferromagnetic Neel temperature increase with an increase in pressure. High pressure x-ray diffraction studies using a synchrotron source show a structural phase transition from a tetragonal phase to a new crystallographic phase at a pressure of 23 GPa at 300 K. The NdCoAsO sample remained anti-ferromagnetic and non-superconducting to temperatures down to 10 K and to the highest pressure achieved in this experiment of 53 GPa. A P-T phase diagram for NdCoAsO is presented to a pressure of 53 GPa and low temperatures of 10 K.
Study and comparison of over 30 examples of electron doped BaFe2As2 for transition metal (TM) = Co, Ni, Cu, and (Co/Cu mixtures) have lead to an understanding that the suppression of the structural/antiferromagnetic phase transition to low enough temperature in these compounds is a necessary condition for superconductivity, but not a sufficient one. Whereas the structural/antiferromagnetic transitions are suppressed by the number of TM dopant ions (or changes in the c-axis) the superconducting dome exists over a limited range of values of the number of electrons added by doping (or values of the {a/c} ratio). By choosing which combination of dopants are used we can change the relative positions of the upper phase lines and the superconducting dome, even to the extreme limit of suppressing the upper structural and magnetic phase transitions without the stabilization of low temperature superconducting dome.
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