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Register a new userMid-Infrared Spectroscopy of Uranus from the Spitzer Infrared Spectrometer: 2. Determination of the Mean Composition of the Upper Troposphere and Stratosphere
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Mid-infrared spectral observations Uranus acquired with the Infrared Spectrometer (IRS) on the Spitzer Space Telescope are used to determine the abundances of C2H2, C2H6, CH3C2H, C4H2, CO2, and tentatively CH3 on Uranus at the time of the 2007 equinox. For vertically uniform eddy diffusion coefficients in the range 2200-2600 cm2 s-1, photochemical models that reproduce the observed methane emission also predict C2H6 profiles that compare well with emission in the 11.6-12.5 micron wavelength region, where the nu9 band of C2H6 is prominent. Our nominal model with a uniform eddy diffusion coefficient Kzz = 2430 cm2 sec-1 and a CH4 tropopause mole fraction of 1.6x10-5 provides a good fit to other hydrocarbon emission features, such as those of C2H2 and C4H2, but the model profile for CH3C2H must be scaled by a factor of 0.43, suggesting that improvements are needed in the chemical reaction mechanism for C3Hx species. The nominal model is consistent with a CH3D/CH4 ratio of 3.0+-0.2x10-4. From the best-fit scaling of these photochemical-model profiles, we derive column abundances above the 10-mbar level of 4.5+01.1/-0.8 x 10+19 molecule-cm-2 for CH4, 6.2 +- 1.0 x 10+16 molecule-cm-2 for C2H2 (with a value 24% higher from a different longitudinal sampling), 3.1 +- 0.3 x 10+16 molecule-cm-2 for C2H6, 8.6 +- 2.6 x 10+13 molecule-cm-2 for CH3C2H, 1.8 +- 0.3 x 10+13 molecule-cm-2 for C4H2, and 1.7 +- 0.4 x 10+13 molecule-cm-2 for CO2 on Uranus. Our results have implications with respect to the influx rate of exogenic oxygen species and the production rate of stratospheric hazes on Uranus, as well as the C4H2 vapor pressure over C4H2 ice at low temperatures.
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On 2007 December 16-17, spectra were acquired of the disk of Uranus by the Spitzer Infrared Spectrometer (IRS) when its equator was close to the sub-earth point. This spectrum provides the highest-resolution broad-band spectrum ever obtained for Uranus from space, allowing a determination of the disk-averaged temperature and molecule composition to a greater degree of accuracy than ever before. The temperature profiles derived from the Voyager radio occultation experiments that match these data best are those that assume a high abundance of methane in the deep atmosphere, but none of these models provides a satisfactory fit over the full spectral range. This be the result of spatial differences between global and low-latitudinal regions, changes in time, missing continuum opacity sources such as stratospheric hazes or unknown tropospheric constituents, or undiagnosed systematic problems with either the radio-occultation or the Spitzer IRS data sets. The spectrum is compatible with the stratospheric temperatures derived from the Voyager ultraviolet occultations measurements. Thermospheric temperatures determined from the analysis of the observed H2 quadrupole emission features are colder than those derived by Herbert et al. at pressures less than ~1 microbar. Extrapolation of the nominal model spectrum to far-infrared through millimeter wavelengths shows that the spectrum arising solely from H2 collision-induced absorption is too warm to reproduce observations between wavelengths of 0.8 and 3.3 mm. Adding an additional absorber such as H2S provides a reasonable match to the spectrum, although a unique identification of the responsible absorber is not yet possible with available data. An immediate practical use for the spectrum resulting from this model is to establish a high-precision continuum flux model for use as an absolute radiometric standard for future astronomical observations.
NASAs Spitzer Infrared Spectrometer (IRS) acquired mid-infrared (5-37 microns) disc-averaged spectra of Uranus very near to its equinox in December 2007. A mean spectrum was constructed from observations of multiple central meridian longitudes, spaced equally around the planet, which has provided the opportunity for the most comprehensive globally-averaged characterisation of Uranus temperature and composition ever obtained (Orton et al., 2014 a [arXiv:1407.2120], b [arXiv:1407.2118]). In this work we analyse the disc-averaged spectra at four separate central meridian longitudes to reveal significant longitudinal variability in thermal emission occurring in Uranus stratosphere during the 2007 equinox. We detect a variability of up to 15% at wavelengths sensitive to stratospheric methane, ethane and acetylene at the ~0.1-mbar level. The tropospheric hydrogen-helium continuum and deuterated methane absorption exhibit a negligible variation (less than 2%), constraining the phenomenon to the stratosphere. Building on the forward-modelling analysis of the global average study, we present full optimal estimation
In this chapter we describe the remote sensing measurement of nitrogen-bearing species in Titans atmosphere by the Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft. This instrument, which detects the thermal infrared spectrum from 10-1500 cm-1 (1000-7 microns) is sensitive to vibrational emissions of gases and condensates in Titans stratosphere and lower mesosphere, permitting the measurement of ambient temperature and the abundances of gases and particulates. Three N-bearing species are firmly detected: HCN, HC3N and C2N2, and their vertical and latitudinal distributions have been mapped. In addition, ices of HC3N and possibly C4N2 are also seen in the far-infrared spectrum at high latitudes during the northern winter. The HC(15)N isotopologue has been measured, permitting the inference of the 14N/15N ratio in this species, which differs markedly (lower) than in the bulk nitrogen reservoir (N2). We also describe the search in the CIRS spectrum, and inferred upper limits, for NH3 and CH3CN. CIRS is now observing seasonal transition on Titan and the gas abundance distributions are changing accordingly, acting as tracers of the changing atmospheric circulation. The prospects for further CIRS science in the remaining five years of the Cassini mission are discussed.
We present mid-IR spectral decomposition of a sample of 48 Spitzer-selected ULIRGs spanning z~1-3 and likely L_IR~10^12-10^13Lsun. Our study aims at quantifying the star-formation and AGN processes in these sources which recent results suggest have evolved strongly between the observed epoch and today. To do this, we study the mid-IR contribution of PAH emission, continuum, and extinction. About 3/4 of our sample are continuum- (i.e. AGN) dominated sources, but ~60% of these show PAH emission, suggesting the presence of star-formation activity. These sources have redder mid-IR colors than typical optically-selected quasars. About 25% of our sample have strong PAH emission, but none are likely to be pure starbursts as reflected in their relatively high 5um hot dust continua. However, their steep 30um-to-14um slopes suggest that star-formation might dominate the total infrared luminosity. Six of our z~2 sources have EW6.2>~0.3um and L_14um>~10^12Lsun (implying L_IR>~10^13Lsun). At these luminosities, such high EW6.2 ULIRGs do not exist in the local Universe. We find a median optical depth at 9.7um of <tau_9.7>=1.4. This is consistent with local IRAS-selected ULIRGs, but differs from early results on SCUBA-selected z~2 ULIRGs. Similar to local ULIRGs about 25% of our sample show extreme obscuration (tau_9.7>~3) suggesting buried nuclei. In general, we find that our sources are similar to local ULIRGs, but are an order of magnitude more luminous. It is not clear whether our z~2 ULIRGs are simply scaled-u
We present the results of a program of optical and near-infrared spectroscopic follow-up of candidate Active Galactic Nuclei (AGN) selected in the mid-infrared. This survey selects both normal and obscured AGN closely matched in luminosity across a wide range, from Seyfert galaxies with bolometric luminosities L_bol~10^10L_sun, to highly luminous quasars (L_bol~10^14L_sun), and with redshifts from 0-4.3. Samples of candidate AGN were selected through mid-infrared color cuts at several different 24 micron flux density limits to ensure a range of luminosities at a given redshift. The survey consists of 786 candidate AGN and quasars, of which 672 have spectroscopic redshifts and classifications. Of these, 137 (20%) are type-1 AGN with blue continua, 294 (44%) are type-2 objects with extinctions A_V>~5 towards their AGN, 96 (14%) are AGN with lower extinctions (A_V~1) and 145 (22%) have redshifts, but no clear signs of AGN activity in their spectra. 50% of the survey objects have L_bol >10^12L_sun, in the quasar regime. We present composite spectra for type-2 quasars and for objects with no signs of AGN activity in their spectra. We also discuss the mid-infrared - emission-line luminosity correlation and present the results of cross-correlations with serendipitous X-ray and radio sources. The results show that: (1) obscured objects dominate the overall AGN population, (2) there exist mid-infrared selected AGN candidates which lack AGN signatures in their optical spectra, but have AGN-like X-ray or radio counterparts, and (3) X-ray and optical classifications of obscured and unobscured AGN often differ.
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