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Register a new userOptical spectroscopy study of Nd(O,F)BiS2 single crystals
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We present an optical spectroscopy study on F-substituted NdOBiS$_2$ superconducting single crystals grown using KCl/LiCl flux method. The measurement reveals a simple metallic response with a relatively low screened plasma edge near 5000 cm. The plasma frequency is estimated to be 2.1 eV, which is much smaller than the value expected from the first-principles calculations for an electron doping level of x=0.5, but very close to the value based on a doping level of 7$%$ of itinerant electrons per Bi site as determined by ARPES experiment. The energy scales of the interband transitions are also well reproduced by the first-principles calculations. The results suggest an absence of correlation effect in the compound, which essentially rules out the exotic pairing mechanism for superconductivity or scenario based on the strong electronic correlation effect. The study also reveals that the system is far from a CDW instability as being widely discussed for a doping level of x=0.5.
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We report the electrical resistivity measurements under pressure for the recently discovered BiS2-based layered superconductors Bi4O4S3 and La(O,F)BiS2. In Bi4O4S3, the transition temperature Tc decreases monotonically without a distinct change in the metallic behavior in the normal state. In La(O,F)BiS2, on the other hand, Tc initially increases with increasing pressure and then decreases above ? 1 GPa. The semiconducting behavior in the normal state is suppressed markedly and monotonically, whereas the evolution of Tc is nonlinear. The strong suppression of the semiconducting behavior without doping in La(O,F)BiS2 suggests that the Fermi surface is located in the vicinity of some instability. In the present study, we elucidate that the superconductivity in the BiS2 layer favors the Fermi surface at the boundary between the semiconducting and metallic behaviors.
F-substituted ROBiS2 (R = La, Ce, Nd) superconducting single crystals with different F concentration were grown successfully using CsCl/KCl flux. All the obtained single crystals had a plate-like shape with a well-developed ab-plane of 1-2 mm in size. The flux components of Cs, K, and Cl were not detected in the obtained single crystals by electron probe microanalysis. The grown single crystals of F-substituted LaOBiS2 and CeOBiS2 showed superconducting at about 3 K while the Tc of the F-substituted NdOBiS2 exhibited approximately 5 K. The superconducting anisotropy of the single crystals of F-substituted LaOBiS2 and NdOBiS2 was estimated to be 30-45 according to the effective mass model whereas those values were 13-21 for the F-substituted CeOBiS2 single crystals. The F-substituted CeOBiS2 single crystals exhibited magnetic order at about 7 K that apparently coexisted with superconductivity below around 3 K.
A new BiS2-based superconductor Bi2(O,F)S2 was discovered. This is a layered compound consisting of alternate stacking structure of rock-salt-type BiS2 superconducting layer and fluorite-type Bi(O,F) blocking layer. Bi2(O,F)S2 was obtained as the main phase by topotactic fluorination of undoped Bi2OS2 using XeF2, which is the first topotactic synthesis of an electron-doped superconductor via reductive fluorination. With increasing F-content, a- and c-axis length increased and decreased, respectively, and Tc increased up to 5.1 K.
The superconducting penetration depth, $lambda(T)$, has been measured in RFeAsO$_{0.9}$F$_{0.1}$ (R=La,Nd) single crystals (R-1111). In Nd-1111, we find an upturn in $lambda(T)$ upon cooling and attribute it to the paramagnetism of the Nd ions, similar to the case of the electron-doped cuprate Nd-Ce-Cu-O. After the correction for paramagnetism, the London penetration depth variation is found to follow a power-law behavior, $Delta lambda_L(T)propto T^{2}$ at low temperatures. The same $T^2$ variation of $lambda(T)$ was found in non-magnetic La-1111 crystals. Analysis of the superfluid density and of penetration depth anisotropy over the full temperature range is consistent with two-gap superconductivity. Based on this and on our previous work, we conclude that both the RFeAsO (1111) and BaFe$_2$As$_2$ (122) families of pnictide superconductors exhibit unconventional two-gap superconductivity.
Measurements of electrical resistivity were performed between 3 and 300 K at various pressures up to 2.8 GPa on the BiS2-based superconductors LnO0.5F0.5BiS2 (Ln = Pr, Nd). At lower pressures, PrO0.5F0.5BiS2 and NdO0.5F0.5BiS2 exhibit superconductivity with critical temperatures Tc of 3.5 and3.9 K, respectively. As pressure is increased, both compounds undergo a transition at a pressure Pt from a low Tc superconducting phase to a high Tc superconducting phase in which Tc reaches maximum values of 7.6 and 6.4 K for PrO0.5F0.5BiS2 and NdO0.5F0.5BiS2, respectively. The pressure-induced transition is characterized by a rapid increase in Tc within a small range in pressure of ~0.3 GPa for both compounds. In the normal state of PrO0.5F0.5BiS2, the transition pressure Pt correlates with the pressure where the suppression of semiconducting behaviour saturates. In the normal state of NdO0.5F0.5BiS2, Pt is coincident with a semiconductor-metal transition. This behaviour is similar to the results recently reported for the LnO0.5F0.5BiS2 (Ln = La, Ce) compounds. We observe that Pt and the size of the jump in Tc between the two superconducting phases both scale with the lanthanide element in LnO0.5F0.5BiS2 (Ln = La, Ce, Pr, Nd).
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