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Register a new userComment on Thermodynamic properties of rock-salt ZnO by Leitner et al. [Thermochimica Acta 572 (2013) 1-5]
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Very recently Leitner et al. [Thermochimica Acta 572 (2013) 1-5] have tried to extract the thermodynamic data of rock-salt ZnO from ab initio and experimental data available in the literature. In this Comment we show that neglecting (i) the strongly pronounced kinetic features of the pressure-induced phase transition in ZnO at room temperature and (ii) results of calorimetric measurements available in the literature [Russ. Chem. Bull. 59 (2010) 325-328] makes the proposed set of thermodynamic functions completely incorrect.
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Low-temperature heat capacities (Cp) of nanostructured rock salt (rs-ZnO) and wurtzite (w-ZnO) polymorphs of zinc oxide were measured in the 2-315 K temperature range. No significant influence of nanostructuring on Cp of w-ZnO has been observed. The measured Cp of rock salt ZnO is lower than that of wurtzite ZnO below 100 K and is higher above this temperature. Using available thermodynamic data, we established that the equilibrium pressure between nanocrystalline w-ZnO and rs-ZnO is close to 4.6 GPa at 300 K (half as much as the onset pressure of direct phase transformation) and slightly changes with temperature up to 1000 K.
The CLAS Collaboration provides a comment on the physics interpretation of the results presented in a paper published by M. Amaryan et al. regarding the possible observation of a narrow structure in the mass spectrum of a photoproduction experiment.
In this Comment we report a phenomenon identical to that observed in ({Y. Sun, M. B. Salamon, K. Garnier and R. S. Averback, Phys. Rev. Lett. 91, 167206 (2003)}) for systems of NiFe{$_2$}O{$_4$} particles (mean size $approx$ 3nm) embedded in a SiO{$_2$} matrix with two different interparticle spacings 4 nm (1) and 15 nm (2), which controls the strength of the dipolar interactions. Not only do we find the memory effect to be present in the non-interacting sample (2), indeed we find it to be {em more} prominent than in the interacting case (1). We demonstrate that this effect can be simply attributed to a superposition of relaxation times of two sets of particles.
In this reply, we point out several criticisms of the analysis in arXiv:0909.2633 and show that the comment does not change the underlying conclusion presented by ourselves that there is no measurable deficit in the scattering cross section of hydrogen. We therefore consider that our original conclusions are correct namely that the previous anomalies in the cross section are due to experimental effects related to the use of indirect geometry spectrometers.
In a comment on arXiv:1006.5070v1, Drechsler et al. present new band-structure calculations suggesting that the frustrated ferromagnetic spin-1/2 chain LiCuVO4 should be described by a strong rather than weak ferromagnetic nearest-neighbor interaction, in contradiction with their previous calculations. In our reply, we show that their new results are at odds with the observed magnetic structure, that their analysis of the static susceptibility neglects important contributions, and that their criticism of the spin-wave analysis of the bound-state dispersion is unfounded. We further show that their new exact diagonalization results reinforce our conclusion on the existence of a four-spinon continuum in LiCuVO4, see Enderle et al., Phys. Rev. Lett. 104 (2010) 237207.
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