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Asymptotic work distributions in driven bistable systems

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 Added by Daniel Nickelsen
 Publication date 2012
  fields Physics
and research's language is English




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The asymptotic tails of the probability distributions of thermodynamic quantities convey important information about the physics of nanoscopic systems driven out of equilibrium. We apply a recently proposed method to analytically determine the asymptotics of work distributions in Langevin systems to an one-dimensional model of single-molecule force spectroscopy. The results are in excellent agreement with numerical simulations, even in the centre of the distributions. We compare our findings with a recent proposal for an universal form of the asymptotics of work distributions in single-molecule experiments.

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The occurrence of stochastic resonance in bistable systems undergoing anomalous diffusions, which arise from density-dependent fluctuations, is investigated with emphasis on the analytical formulation of the problem as well as a possible analytical derivation of key quantifiers of stochastic resonance. The nonlinear Fokker-Planck equation describing the system dynamics, together with the corresponding Ito-Langevin equation, are formulated. In the linear-response regime analytical expressions of the spectral amplification, of the signal-to-noise ratio and of the hysteresis loop area are derived as quantifiers of stochastic resonance. These quantifiers are found to be strongly dependent on the parameters controlling the type of diffusion, in particular the peak characterizing the signal-to-noise ratio occurs only in close ranges of parameters. Results introduce the relevant information that taking into consideration the interactions of anomalous diffusive systems with a periodic signal, can provide a better understanding of the physics of stochastic resonance in bistable systems driven by periodic forces.
The theoretical treatment of quasi-periodically driven quantum systems is complicated by the inapplicability of the Floquet theorem, which requires strict periodicity. In this work we consider a quantum system driven by a bi-harmonic driving and examine its asymptotic long-time limit, the limit in which features distinguishing systems with periodic and quasi-periodic driving occur. Also, in the classical case this limit is known to exhibit universal scaling, independent of the system details, with the systems reponse under quasi-periodic driving being described in terms of nearby periodically driven system results. We introduce a theoretical framework appropriate for the treatment of the quasi-periodically driven quantum system in the long-time limit, and derive an expression, based on Floquet states for a periodically driven system approximating the different steps of the time evolution, for the asymptotic scaling of relevant quantities for the system at hand. These expressions are tested numerically, finding excellent agreement for the finite-time average velocity in a prototypical quantum ratchet consisting of a space-symmetric potential and a time-asymmetric oscillating force.
We examine the time-dependent behavior of a nonlinear system driven by a two-frequency forcing. By using a non-perturbative approach, we are able to derive an asymptotic expression, valid in the long-time limit, for the time average of the output variable which describes the response of the system. We identify several universal features of the asymptotic response of the system, which are independent of the details of the model. In particular, we determine an asymptotic expression for the width of the resonance observed by keeping one frequency fixed, and varying the other one. We show that this width is smaller than the usually assumed Fourier width by a factor determined by the two driving frequencies, and independent of the model system parameters. Additional general features can also be identified depending on the specific symmetry properties of the system. Our results find direct application in the study of sub-Fourier signal processing with nonlinear systems.
91 - D. Nickelsen , A. Engel 2011
We determine the complete asymptotic behaviour of the work distribution in driven stochastic systems described by Langevin equations. Special emphasis is put on the calculation of the pre-exponential factor which makes the result free of adjustable parameters. The method is applied to various examples and excellent agreement with numerical simulations is demonstrated. For the special case of parabolic potentials with time-dependent frequencies, we derive a universal functional form for the asymptotic work distribution.
For closed quantum systems driven away from equilibrium, work is often defined in terms of projective measurements of initial and final energies. This definition leads to statistical distributions of work that satisfy nonequilibrium work and fluctuation relations. While this two-point measurement definition of quantum work can be justified heuristically by appeal to the first law of thermodynamics, its relationship to the classical definition of work has not been carefully examined. In this paper we employ semiclassical methods, combined with numerical simulations of a driven quartic oscillator, to study the correspondence between classical and quantal definitions of work in systems with one degree of freedom. We find that a semiclassical work distribution, built from classical trajectories that connect the initial and final energies, provides an excellent approximation to the quantum work distribution when the trajectories are assigned suitable phases and are allowed to interfere. Neglecting the interferences between trajectories reduces the distribution to that of the corresponding classical process. Hence, in the semiclassical limit, the quantum work distribution converges to the classical distribution, decorated by a quantum interference pattern. We also derive the form of the quantum work distribution at the boundary between classically allowed and forbidden regions, where this distribution tunnels into the forbidden region. Our results clarify how the correspondence principle applies in the context of quantum and classical work distributions, and contribute to the understanding of work and nonequilibrium work relations in the quantum regime.
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