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Register a new userComplex Organic Molecules at High Spatial Resolution Toward Orion-KL II: Kinematics
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It has recently been suggested that chemical processing can shape the spatial distributions of complex molecules in the Orion-KL region and lead to the nitrogen-oxygen chemical differentiation seen in previous observations of this source. Orion-KL is a very dynamic region, and it is therefore also possible that physical conditions can shape the molecular distributions in this source. Only high spatial resolution observations can provide the information needed to disentangle these effects. Here we present millimeter imaging studies of Orion-KL at various beam sizes using the Combined Array for Research in Millimeter-Wave Astronomy (CARMA). We compare molecular images with high spatial resolution images that trace the temperature, continuum column density, and kinematics of the source in order to investigate the effects of physical conditions on molecular distributions. These observations were conducted at lambda = 3 mm and included transitions of ethyl cyanide [C2H5CN], methyl formate [HCOOCH3], formic acid [HCOOH], acetone [(CH3)2CO], SiO, and methanol [CH3OH]. We find differences in the molecular distributions as a function of each of these factors. These results indicate that acetone may be produced by chemical processing and is robust to large changes in physical conditions, while formic acid is readily destroyed by gas-phase processing in warm and dense regions. We also find that while the spatial distributions of ethyl cyanide and methyl formate are not distinct as is suggested by the concept of chemical differentiation, local physical conditions shape the small-scale emission structure for these species.
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Here we present high spatial resolution (<1 arcsecond) observations of molecular emission in Orion-KL conducted using the Combined Array for Research in Millimeter-Wave Astronomy (CARMA). This work was motivated by recent millimeter continuum imaging studies of this region conducted at a similarly high spatial resolution, which revealed that the bulk of the emission arises from numerous compact sources, rather than the larger-scale extended structures typically associated with the Orion Hot Core and Compact Ridge. Given that the spatial extent of molecular emission greatly affects the determination of molecular abundances, it is important to determine the true spatial scale for complex molecules in this region. Additionally, it has recently been suggested that the relative spatial distributions of complex molecules in a source might give insight into the chemical mechanisms that drive complex chemistry in star-forming regions. In order to begin to address these issues, this study seeks to determine the spatial distributions of ethyl cyanide [C2H5CN], dimethyl ether [(CH3)2O], methyl formate [HCOOCH3], formic acid [HCOOH], acetone [(CH3)2CO], SiO, methanol [CH3OH], and methyl cyanide [CH3CN] in Orion-KL at lambda = 3 mm. We find that for all observed molecules, the molecular emission arises from multiple components of the cloud that include a range of spatial scales and physical conditions. Here we present the results of these observations and discuss the implications for studies of complex molecules in star-forming regions.
Recent interferometric observations have called into question the traditional view of the Orion-KL region, which displays one of the most well-defined cases of chemical differentiation in a star-forming region. Previous, lower-resolution images of Orion-KL show emission signatures for oxygen-bearing organic molecules toward the Orion Compact Ridge, and emission for nitrogen-bearing organic molecules toward the Orion Hot Core. However, more recent observations at higher spatial resolution indicate that the bulk of the molecular emission is arising from many smaller, compact clumps that are spatially distinct from the traditional Hot Core and Compact Ridge sources. It is this type of observational information that is critical for guiding astrochemical models, as the spatial distribution of molecules and their relation to energetic sources will govern the chemical mechanisms at play in star-forming regions. We have conducted millimeter imaging studies of Orion-KL with various beam sizes using CARMA in order to investigate the continuum structure. These lambda;=3mm observations have synthesized beam sizes of ~0.5-5.0. These observations reveal the complex continuum structure of this region, which stands in sharp contrast to the previous structural models assumed for Orion-KL based on lower spatial resolution images. The new results indicate that the spatial scaling previously used in determination of molecular abundances for this region are in need of complete revision. Here we present the results of the continuum observations, discuss the sizes and structures of the detected sources, and suggest an observational strategy for determining the proper spatial scaling to accurately determine molecular abundances in the Orion-KL region.
We present high resolution, Combined Array for Research in Millimeter-Wave Astronomy (CARMA), $lambda$=1mm observations of several molecular species toward Orion-KL. These are the highest spatial and spectral resolution 1mm observations of these molecules to date. Our observations show that ethyl cyanide [C$_2$H$_5$CN] and vinyl cyanide [C$_2$H$_3$CN] originate from multiple cores near the Orion hot core and IRc7. Additionally we show that dimethyl ether [(CH$_3$)$_2$O] and methyl formate [HCOOCH$_3$] originate from IRc5 and IRc6 and that acetone [(CH$_3$)$_2$CO] originates only from areas where both N-bearing and O-bearing species are present.
Orion KL has served as a benchmark for spectral line searches throughout the (sub)millimeter regime. The main goal is to systematically study spectral characteristics of Orion KL in the 1.3 cm band. We carried out a spectral line survey (17.9 GHz to 26.2 GHz) with the Effelsberg-100 m telescope towards Orion KL. We find 261 spectral lines, yielding an average line density of about 32 spectral features per GHz above 3$sigma$. The identified lines include 164 radio recombination lines (RRLs) and 97 molecular lines. A total of 23 molecular transitions from species known to exist in Orion KL are detected for the first time in the interstellar medium. Non-metastable 15NH3 transitions are detected in Orion KL for the first time. Based on the velocity information of detected lines and the ALMA images, the spatial origins of molecular emission are constrained and discussed. A narrow feature is found in SO2 ($8_{1,7}-7_{2,6}$), possibly suggesting the presence of a maser line. Column densities and fractional abundances relative to H2 are estimated for 12 molecules with LTE methods. Rotational diagrams of non-metastable 14NH3 transitions with J=K+1 to J=K+4 yield different results; metastable 15NH3 is found to have a higher excitation temperature than non-metastable 15NH3, indicating that they may trace different regions. Elemental and isotopic abundance ratios are estimated: 12C/13C=63+-17, 14N/15N=100+-51, D/H=0.0083+-0.0045. The dispersion of the He/H ratios derived from H$alpha$/He$alpha$ pairs to H$delta$/He$delta$ pairs is very small, which is consistent with theoretical predictions that the departure coefficients bn factors for hydrogen and helium are nearly identical. Based on a non-LTE code neglecting excitation by the infrared radiation field and a likelihood analysis, we find that the denser regions have lower kinetic temperature, which favors an external heating of the Hot Core.
We present a comprehensive study of the deuterated molecules detected in the fullband HIFI survey of the Orion KL region. Ammonia, formaldehyde, and methanol and their singly deuterated isotopologues are each detected through numerous transitions in this survey with a wide range in optical depths and excitation conditions. In conjunction with a recent study of the abundance of HDO and H$_2$O in Orion KL, this study yields the best constraints on deuterium fractionation in an interstellar molecular cloud to date. As previous studies have found, both the Hot Core and Compact Ridge regions within Orion KL contain significant abundances of deuterated molecules, suggesting an origin in cold grain mantles. In the Hot Core, we find that ammonia is roughly a factor of 2 more fractionated than water. In the Compact Ridge, meanwhile, we find similar deuterium fractionation in water, formaldehyde, and methanol, with D/H ratios of (2---8) $times$ $10^{-3}$. The [CH$_2$DOH]/[CH$_3$OD] ratio in the Compact Ridge is found to be $1.2 pm 0.3$. The Hot Core generally has lower deuterium fractionation than the Compact Ridge, suggesting a slightly warmer origin, or a greater contribution from warm gas phase chemistry.
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