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Scattering lengths of calcium and barium isotopes

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 Added by Steven Knoop
 Publication date 2011
  fields Physics
and research's language is English




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We have calculated the s-wave scattering length of all the even isotopes of calcium (Ca) and barium (Ba), in order to investigate the prospect of Bose-Einstein condensation (BEC). For Ca we have used an accurate molecular potential based on detailed spectroscopic data. Our calculations show that Ca does not provide other isotopes alternative to the recently Bose condensed 40Ca that suffers strong losses because of a very large scattering length. For Ba we show by using a model potential that the even isotopes cover a broad range of scattering lengths, opening the possibility of BEC for at least one of the isotopes.



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We have investigated the ultracold interspecies scattering properties of metastable triplet He and Rb. We performed state-of-the-art ab initio calculations of the relevant interaction potential, and measured the interspecies elastic cross section for an ultracold mixture of metastable triplet $^4$He and $^{87}$Rb in a quadrupole magnetic trap at a temperature of 0.5 mK. Our combined theoretical and experimental study gives an interspecies scattering length $a_{4+87}=+17^{+1}_{-4}$ $a_0$, which prior to this work was unknown. More general, our work shows the possibility of obtaining accurate scattering lengths using ab initio calculations for a system containing a heavy, many-electron atom, such as Rb.
We have obtained accurate ab initio quartet potentials for the diatomic metastable triplet helium + alkali-metal (Li, Na, K, Rb) systems, using all-electron restricted open-shell coupled cluster singles and doubles with noniterative triples corrections [CCSD(T)] calculations and accurate calculations of the long-range $C_6$ coefficients. These potentials provide accurate ab initio quartet scattering lengths, which for these many-electron systems is possible, because of the small reduced masses and shallow potentials that results in a small amount of bound states. Our results are relevant for ultracold metastable triplet helium + alkali-metal mixture experiments.
We use collective oscillations of a two-component Bose-Einstein condensate (2CBEC) of Rb atoms prepared in the internal states $ket{1}equivket{F=1, m_F=-1}$ and $ket{2}equivket{F=2, m_F=1}$ for the precision measurement of the interspecies scattering length $a_{12}$ with a relative uncertainty of $1.6times 10^{-4}$. We show that in a cigar-shaped trap the three-dimensional (3D) dynamics of a component with a small relative population can be conveniently described by a one-dimensional (1D) Schr{o}dinger equation for an effective harmonic oscillator. The frequency of the collective oscillations is defined by the axial trap frequency and the ratio $a_{12}/a_{11}$, where $a_{11}$ is the intra-species scattering length of a highly populated component 1, and is largely decoupled from the scattering length $a_{22}$, the total atom number and loss terms. By fitting numerical simulations of the coupled Gross-Pitaevskii equations to the recorded temporal evolution of the axial width we obtain the value $a_{12}=98.006(16),a_0$, where $a_0$ is the Bohr radius. Our reported value is in a reasonable agreement with the theoretical prediction $a_{12}=98.13(10),a_0$ but deviates significantly from the previously measured value $a_{12}=97.66,a_0$ cite{Mertes07} which is commonly used in the characterisation of spin dynamics in degenerate Rb atoms. Using Ramsey interferometry of the 2CBEC we measure the scattering length $a_{22}=95.44(7),a_0$ which also deviates from the previously reported value $a_{22}=95.0,a_0$ cite{Mertes07}. We characterise two-body losses for the component 2 and obtain the loss coefficients ${gamma_{12}=1.51(18)times10^{-14} textrm{cm}^3/textrm{s}}$ and ${gamma_{22}=8.1(3)times10^{-14} textrm{cm}^3/textrm{s}}$.
We have observed 26 interspecies Feshbach resonances at fields up to 2050 G in ultracold $^6$Li+$^{23}$Na mixtures for different spin-state combinations. Applying the asymptotic bound-state model to assign the resonances, we have found that most resonances have d-wave character. This analysis serves as guidance for a coupled-channel calculation, which uses modified interaction potentials to describe the positions of the Feshbach resonances well within the experimental uncertainty and to calculate their widths. The scattering length derived from the improved interaction potentials is experimentally confirmed and deviates from previously reported values in sign and magnitude. We give prospects for $^7$Li+$^{23}$Na and predict broad Feshbach resonances suitable for tuning.
We use the operator product expansion (OPE) and dispersion relations to obtain new model-independent Borel-resummed sum rules for both shear and bulk viscosity of many-body systems of spin-1/2 fermions with predominantly short range S-wave interactions. These sum rules relate Gaussian weights of the frequency-dependent viscosities to the Tan contact parameter C(a). Our results are valid for arbitrary values of the scattering length a, but receive small corrections from operators of dimension larger than 5 in the OPE, and can be used to study transport properties in the vicinity of the infinite scattering length fixed point. In particular, we find that the exact dependence of the shear viscosity sum rule on scattering length is controlled by the function C(a). The sum rules that we obtain depend on a frequency scale w that can be optimized to maximize their overlap with low-energy data.
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