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We studied the abundance of HCN, H13CN, and HN13C in a sample of prestellar cores, in order to search for species associated with high density gas. We used the IRAM 30m radiotelescope to observe along the major and the minor axes of L1498, L1521E, and TMC 2, three cores chosen on the basis of their CO depletion properties. We mapped the J=1-0 transition of HCN, H13CN, and HN13C towards the source sample plus the J=1-0 transition of N2H+ and the J=2-1 transition of C18O in TMC 2. We used two different radiative transfer codes, making use of recent collisional rate calculations, in order to determine more accurately the excitation temperature, leading to a more exact evaluation of the column densities and abundances. We find that the optical depths of both H13CN(1-0) and HN13C(1-0) are non-negligible, allowing us to estimate excitation temperatures for these transitions in many positions in the three sources. The observed excitation temperatures are consistent with recent computations of the collisional rates for these species and they correlate with hydrogen column density inferred from dust emission. We conclude that HCN and HNC are relatively abundant in the high density zone, n(H2) about 10^5 cm-3, where CO is depleted. The relative abundance [HNC]/[HCN] differs from unity by at most 30 per cent consistent with chemical expectations. The three hyperfine satellites of HCN(1-0) are optically thick in the regions mapped, but the profiles become increasingly skewed to the blue (L1498 and TMC 2) or red (L1521E) with increasing optical depth suggesting absorption by foreground layers.
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We study the abundance of CCH in prestellar cores both because of its role in the chemistry and because it is a potential probe of the magnetic field. We also consider the non-LTE behaviour of the N=1-0 and N=2-1 transitions of CCH and improve current estimates of the spectroscopic constants of CCH. We used the IRAM 30m radiotelescope to map the N=1-0 and N=2-1 transitions of CCH towards the prestellar cores L1498 and CB246. Towards CB246, we also mapped the 1.3 mm dust emission, the J=1-0 transition of N2H+ and the J=2-1 transition of C18O. We used a Monte Carlo radiative transfer program to analyse the CCH observations of L1498. We derived the distribution of CCH column densities and compared with the H2 column densities inferred from dust emission. We find that while non-LTE intensity ratios of different components of the N=1-0 and N=2-1 lines are present, they are of minor importance and do not impede CCH column density determinations based upon LTE analysis. Moreover, the comparison of our Monte-Carlo calculations with observations suggest that the non-LTE deviations can be qualitatively understood. For L1498, our observations in conjunction with the Monte Carlo code imply a CCH depletion hole of radius 9 x 10^{16} cm similar to that found for other C-containing species. We briefly discuss the significance of the observed CCH abundance distribution. Finally, we used our observations to provide improved estimates for the rest frequencies of all six components of the CCH(1-0) line and seven components of CCH(2-1). Based on these results, we compute improved spectroscopic constants for CCH. We also give a brief discussion of the prospects for measuring magnetic field strengths using CCH.
The CS molecule is known to be absorbed onto dust in the cold and dense conditions, causing it to get significantly depleted in the central region of cores. This study is aimed to investigate the depletion of the CS molecule using the optically thin C$^{34}$S molecular line observations. We mapped five prestellar cores, L1544, L1552, L1689B, L694-2, and L1197 using two molecular lines, C$^{34}$S $(J=2-1)$ and N$_2$H$^+$ $(J=1-0)$ with the NRO 45-m telescope, doubling the number of cores where the CS depletion was probed using C$^{34}$S. In most of our targets, the distribution of C$^{34}$S emission shows features that suggest that the CS molecule is generally depleted in the center of the prestellar cores. The radial profile of the CS abundance with respect to H$_2$ directly measured from the CS emission and the Herschel dust emission indicates that the CS molecule is depleted by a factor of $sim$3 toward the central regions of the cores with respect to their outer regions. The degree of the depletion is found to be even more enhanced by an order of magnitude when the contaminating effect introduced by the presence of CS molecules in the surrounding envelope that lie along the line-of-sight is removed. Except for L1197 which is classified as relatively the least evolved core in our targets based on its observed physical parameters, we found that the remaining four prestellar cores are suffering from significant CS depletion at their central region regardless of the relative difference in their evolutionary status.
Although hydrogen cyanide has become quite a common molecular tracing species for a variety of astrophysical sources, it, however, exhibits dramatic non-LTE behaviour in its hyperfine line structure. Individual hyperfine components can be strongly boosted or suppressed. If these so-called hyperfine line anomalies are present in the HCN rotational spectra towards low or high mass cores, this will affect the interpretation of various physical properties such as the line opacity and excitation temperature in the case of low mass objects and infall velocities in the case of their higher mass counterparts. This is as a consequence of the direct effects that anomalies have on the underlying line shape, be it with the line structural width or through the inferred line strength. This work involves the first observational investigation of these anomalies in two HCN rotational transitions, J=1!0 and J=3!2, towards both low mass starless cores and high mass protostellar objects. The degree of anomaly in these two rotational transitions is considered by computing the ratios of neighboring hyperfine lines in individual spectra. Results indicate some degree of anomaly is present in all cores considered in our survey, the most likely cause being line overlap effects among hyperfine components in higher rotational transitions.
Young massive stars are usually found embedded in dense massive molecular clumps and are known for being highly obscured and distant. During their formation process, deuteration is regarded as a potentially good indicator of the very early formation stages. In this work, we test the observability of the ground-state transition of ortho-H$_2$D$^+$ $J_{rm {K_a, K_c}} = 1_{10}$-$1_{11} $ by performing interferometric and single-dish synthetic observations using magneto-hydrodynamic simulations of high-mass collapsing molecular cores, including deuteration chemistry. We studied different evolutionary times and source distances (from 1 to 7 kpc) to estimate the information loss when comparing the column densities inferred from the synthetic observations to the column densities in the model. We mimicked single-dish observations considering an APEX-like beam and interferometric observations using CASA and assuming the most compact configuration for the ALMA antennas. We found that, for centrally concentrated density distributions, the column densities are underestimated by about 51% in the case of high-resolution ALMA observations ($leqslant$1) and up to 90% for APEX observations (17). Interferometers retrieve values closer to the real ones, however, their finite spatial sampling results in the loss of contribution from large-scale structures due to the lack of short baselines. We conclude that, the emission of o-H$_2$D$^+$ in distant massive dense cores is faint and would require from $sim$1 to $sim$7 hours of observation at distances of 1 and 7 kpc, respectively, to achieve a 14$sigma$ detection in the best case scenario. Additionally, the column densities derived from such observations will certainly be affected by beam dilution in the case of single-dishes and spatial filtering in the case of interferometers.
Determining the structure of and the velocity field in prestellar cores is essential to understanding protostellar evolution.} {We have observed the dense prestellar cores L 1544 and L 183 in the $N = 1 to 0$ rotational transition of CN and thcn in order to test whether CN is depleted in the high--density nuclei of these cores.} {We have used the IRAM 30 m telescope to observe along the major and minor axes of these cores. We compare these observations with the 1 mm dust emission, which serves as a proxy for the hydrogen column density.}{We find that while CNjone is optically thick, the distribution of thcnjone intensity follows the dust emission well, implying that the CN abundance does not vary greatly with density. We derive an abundance ratio of $rm [CN]/[hh]=dix{-9}$ in L 183 and 1-3tdix{-9} in L 1544, which, in the case of L 183, is similar to previous estimates obtained by sampling lower--density regions of the core.}{We conclude that CN is not depleted towards the high--density peaks of these cores and thus behaves like the N-containing molecules nhp and hhh. CN is, to our knowledge, the first C--containing molecule to exhibit this characteristic.
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