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Register a new userThermodynamic Geometry, Phase Transitions, and the Widom Line
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We construct a novel approach, based on thermodynamic geometry, to characterize first-order phase transitions from a microscopic perspective, through the scalar curvature in the equilibrium thermodynamic state space. Our method resolves key theoretical issues in macroscopic thermodynamic constructs, and furthermore characterizes the Widom line through the maxima of the correlation length, which is captured by the thermodynamic scalar curvature. As an illustration of our method, we use it in conjunction with the mean field Van der Waals equation of state to predict the coexistence curve and the Widom line. Where closely applicable, it provides excellent agreement with experimental data. The universality of our method is indicated by direct calculations from the NIST database.
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We present a study of phase transitions of the Curie--Weiss Potts model at (inverse) temperature $beta$, in presence of an external field $h$. Both thermodynamic and topological aspects of these transitions are considered. For the first aspect we complement previous results and give an explicit equation of the thermodynamic transition line in the $beta$--$h$ plane as well as the magnitude of the jump of the magnetization (for $q geqslant 3)$. The signature of the latter aspect is characterized here by the presence or not of a giant component in the clusters of a Fortuin--Kasteleyn type representation of the model. We give the equation of the Kertesz line separating (in the $beta$--$h$ plane) the two behaviours. As a result, we get that this line exhibits, as soon as $q geqslant 3$, a very interesting cusp where it separates from the thermodynamic transition line.
We study information theoretic geometry in time dependent quantum mechanical systems. First, we discuss global properties of the parameter manifold for two level systems exemplified by i) Rabi oscillations and ii) quenching dynamics of the XY spin chain in a transverse magnetic field, when driven across anisotropic criticality. Next, we comment upon the nature of the geometric phase from classical holonomy analyses of such parameter manifolds. In the context of the transverse XY model in the thermodynamic limit, our results are in contradiction to those in the existing literature, and we argue why the issue deserves a more careful analysis. Finally, we speculate on a novel geometric phase in the model, when driven across a quantum critical line.
Nonanalyticities of thermodynamic functions are studied by adopting an approach based on stationary points of the potential energy. For finite systems, each stationary point is found to cause a nonanalyticity in the microcanonical entropy, and the functional form of this nonanalytic term is derived explicitly. With increasing system size, the order of the nonanalytic term grows, leading to an increasing differentiability of the entropy. It is found that only asymptotically flat stationary points may cause a nonanalyticity that survives in the thermodynamic limit, and this property is used to derive an analytic criterion establishing the existence or absence of phase transitions. We sketch how this result can be employed to analytically compute transition energies of classical spin models.
When a second-order phase transition is crossed at fine rate, the evolution of the system stops being adiabatic as a result of the critical slowing down in the neighborhood of the critical point. In systems with a topologically nontrivial vacuum manifold, disparate local choices of the ground state lead to the formation of topological defects. The universality class of the transition imprints a signature on the resulting density of topological defects: It obeys a power law in the quench rate, with an exponent dictated by a combination of the critical exponents of the transition. In inhomogeneous systems the situation is more complicated, as the spontaneous symmetry breaking competes with bias caused by the influence of the nearby regions that already chose the new vacuum. As a result, the choice of the broken symmetry vacuum may be inherited from the neighboring regions that have already entered the new phase. This competition between the inherited and spontaneous symmetry breaking enhances the role of causality, as the defect formation is restricted to a fraction of the system where the front velocity surpasses the relevant sound velocity and phase transition remains effectively homogeneous. As a consequence, the overall number of topological defects can be substantially suppressed. When the fraction of the system is small, the resulting total number of defects is still given by a power law related to the universality class of the transition, but exhibits a more pronounced dependence on the quench rate. This enhanced dependence complicates the analysis but may also facilitate experimental test of defect formation theories.
We study the thermodynamic curvature, $R$, around the chiral phase transition at finite temperature and chemical potential, within the quark-meson model augmented with meson fluctuations. We study the effect of the fluctuations, pions and $sigma$-meson, on the top of the mean field thermodynamics and how these affect $R$ around the crossover. We find that for small chemical potential the fluctuations enhance the magnitude of $R$, while they do not affect substantially the thermodynamic geometry in the proximity of the critical endpoint. Moreover, in agreement with previous studies we find that $R$ changes sign in the pseudocritical region, suggesting a change of the nature of interactions at the mesoscopic level from statistically repulsive to attractive. Finally, we find that in the critical region around the critical endpoint $|R|$ scales with the correlation volume, $|R| =K;xi^3$, with $K = O(1)$, as expected from hyperscaling; far from the critical endpoint the correspondence between $|R|$ and the correlation volume is not as good as the one we have found at large $mu$, which is not surprising because at small $mu$ the chiral crossover is quite smooth; nevertheless, we have found that $R$ develops a characteristic peak structure, suggesting that it is still capable to capture the pseudocritical behavior of the condensate.
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