Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userShapes of macromolecules in good solvents: field theoretical renormalization group approach
96
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
In this paper, we show how the method of field theoretical renormalization group may be used to analyze universal shape properties of long polymer chains in porous environment. So far such analytical calculations were primarily focussed on the scaling exponents that govern conformational properties of polymer macromolecules. However, there are other observables that along with the scaling exponents are universal (i.e. independent of the chemical structure of macromolecules and of the solvent) and may be analyzed within the renormalization group approach. Here, we address the question of shape which is acquired by the long flexible polymer macromolecule when it is immersed in a solvent in the presence of a porous environment. This question is of relevance for understanding of the behavior of macromolecules in colloidal solutions, near microporous membranes, and in cellular environment. To this end, we consider a previously suggested model of polymers in d-dimensions [V. Blavatska, C. von Ferber, Yu. Holovatch, Phys. Rev. E, 2001, 64, 041102] in an environment with structural obstacles, characterized by a pair correlation function h(r), that decays with distance r according to a power law: h(r) sim r-a. We apply the field-theoretical renormalization group approach and estimate the size ratio <R_e^2>/<R_G^2 > and the asphericity ratio hat{A}_d up to the first order of a double epsilon=4-d, delta=4-a expansion.
rate research
Read More
We introduce an atomistic approach to the dissipative quantum dynamics of charged or neutral excitations propagating through macromolecular systems. Using the Feynman-Vernon path integral formalism, we analytically trace out from the density matrix the atomic coordinates and the heat bath degrees of freedom. This way we obtain an effective field theory which describes the real-time evolution of the quantum excitation and is fully consistent with the fluctuation-dissipation relation. The main advantage of the field-theoretic approach is that it allows to avoid using the Keldysh contour formulation. This simplification makes it straightforward to derive Feynman diagrams to analytically compute the effects of the interaction of the propagating quantum excitation with the heat bath and with the molecular atomic vibrations. For illustration purposes, we apply this formalism to investigate the loss of quantum coherence of holes propagating through a poly(3-alkylthiophene) polymer
The universal critical behavior of the driven-dissipative non-equilibrium Bose-Einstein condensation transition is investigated employing the field-theoretical renormalization group method. Such criticality may be realized in broad ranges of driven open systems on the interface of quantum optics and many-body physics, from exciton-polariton condensates to cold atomic gases. The starting point is a noisy and dissipative Gross-Pitaevski equation corresponding to a complex valued Landau-Ginzburg functional, which captures the near critical non-equilibrium dynamics, and generalizes Model A for classical relaxational dynamics with non-conserved order parameter. We confirm and further develop the physical picture previously established by means of a functional renormalization group study of this system. Complementing this earlier numerical analysis, we analytically compute the static and dynamical critical exponents at the condensation transition to lowest non-trivial order in the dimensional epsilon expansion about the upper critical dimension d_c = 4, and establish the emergence of a novel universal scaling exponent associated with the non-equilibrium drive. We also discuss the corresponding situation for a conserved order parameter field, i.e., (sub-)diffusive Model B with complex coefficients.
In a system of noisy self-propelled particles with interactions that favor directional alignment, collective motion will appear if the density of particles is beyond a critical density. Starting with a reduced model for collective motion, we determine how the critical density depends on the form of the initial perturbation. Specifically, we employ a renormalization-group improved perturbative method to analyze the model equations, and show analytically, up to first order in the perturbation parameter, how the critical density is modified by the strength of the initial angular perturbation in the system.
We develop a theoretical approach to ``spontaneous stochasticity in classical dynamical systems that are nearly singular and weakly perturbed by noise. This phenomenon is associated to a breakdown in uniqueness of solutions for fixed initial data and underlies many fundamental effects of turbulence (unpredictability, anomalous dissipation, enhanced mixing). Based upon analogy with statistical-mechanical critical points at zero temperature, we elaborate a renormalization group (RG) theory that determines the universal statistics obtained for sufficiently long times after the precise initial data are ``forgotten. We apply our RG method to solve exactly the ``minimal model of spontaneous stochasticity given by a 1D singular ODE. Generalizing prior results for the infinite-Reynolds limit of our model, we obtain the RG fixed points that characterize the spontaneous statistics in the near-singular, weak-noise limit, determine the exact domain of attraction of each fixed point, and derive the universal approach to the fixed points as a singular large-deviations scaling, distinct from that obtained by the standard saddle-point approximation to stochastic path-integrals in the zero-noise limit. We present also numerical simulation results that verify our analytical predictions, propose possible experimental realizations of the ``minimal model, and discuss more generally current empirical evidence for ubiquitous spontaneous stochasticity in Nature. Our RG method can be applied to more complex, realistic systems and some future applications are briefly outlined.
The microstructure and electrical conductivity of suspensions of multi-walled carbon nanotubes (MWCNTs) in binary liquid mixtures water-1-Cyclohexyl-2-pyrrolidone (CHP) were studied in the heating and cooling cycles. The concentration of MWCNTs was varied in the interval between 0-1 wt.% and the content of water in a binary mixture X = [water]/([CHP]+[water]) was varied within 0-1.0. The experimental data have shown that dispersing quality of MWCNTs in a mixture of good (CHP) and bad (water) solvents may be finely regulated by adjustment of composition of the CHP+ water mixtures. The aggregation ability of MWCNTs in dependence on X was discussed. The surface of MWCNT clusters was highly tortuous, its fractal dimension df increased with increase of X, approaching -> 1.9 at X->1. It was concluded that the surface tension is not suitable characteristic for prediction of dispersion ability in the mixture of good and bad solvents. The electrical conductivity data evidenced the presence of a fuzzy-type percolation with multiple thresholds in the systems under investigation. This behavior was explained by formation of different percolation networks in dependence of MWCNT concentration.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
