No Arabic abstract
The dynamics of any classical-mechanics system can be formulated in the reparametrization-invariant (RI) form (that is we use the parametric representation for trajectories, ${bf x}={bf x}(tau)$, $t=t(tau)$ instead of ${bf x}={bf x}(t)$). In this pedagogical note we discuss what the quantization rules look like for the RI formulation of mechanics. We point out that in this case some of the rules acquire an intuitively clearer form. Hence the formulation could be an alternative starting point for teaching the basic principles of quantum mechanics. The advantages can be resumed as follows. a) In RI formulation both the temporal and the spatial coordinates are subject to quantization. b) The canonical Hamiltonian of RI formulation is proportional to the quantity $tilde H=p_t+H$, where $H$ is the Hamiltonian of the initial formulation. Due to the reparametrization invariance, the quantity $tilde H$ vanishes for any solution, $tilde H=0$. So the corresponding quantum-mechanical operator annihilates the wave function, $hat{tilde H}Psi=0$, which is precisely the Schrodinger equation $ihbarpartial_tPsi=hat HPsi$. As an illustration, we discuss quantum mechanics of the relativistic particle.
This paper reports the results of an ongoing in-depth analysis of the classical trajectories of the class of non-Hermitian $PT$-symmetric Hamiltonians $H=p^2+ x^2(ix)^varepsilon$ ($varepsilongeq0$). A variety of phenomena, heretofore overlooked, have been discovered such as the existence of infinitely many separatrix trajectories, sequences of critical initial values associated with limiting classical orbits, regions of broken $PT$-symmetric classical trajectories, and a remarkable topological transition at $varepsilon=2$. This investigation is a work in progress and it is not complete; many features of complex trajectories are still under study.
This paper presents the momentum map structures which emerge in the dynamics of mixed states. Both quantum and classical mechanics are shown to possess analogous momentum map pairs. In the quantum setting, the right leg of the pair identifies the Berry curvature, while its left leg is shown to lead to more general realizations of the density operator which have recently appeared in quantum molecular dynamics. Finally, the paper shows how alternative representations of both the density matrix and the classical density are equivariant momentum maps generating new Clebsch representations for both quantum and classical dynamics. Uhlmanns density matrix and Koopman-von Neumann wavefunctions are shown to be special cases of this construction.
In this paper an exact transparent boundary condition (TBC) for the multidimensional Schrodinger equation in a hyperrectangular computational domain is proposed. It is derived as a generalization of exact transparent boundary conditions for 2D and 3D equations reported before. A new exact fully discrete (i.e. derived directly from the finite-difference scheme used) 1D transparent boundary condition is also proposed. Several numerical experiments using an improved unconditionally stable numerical implementation in the 3D space demonstrate propagation of Gaussian wave packets in free space and penetration of a particle through a 3D spherically asymmetrical barrier. The application of the multidimensional transparent boundary condition to the dynamics of the 2D system of two non-interacting particles is considered. The proposed boundary condition is simple, robust and can be useful in the field of computational quantum mechanics, when an exact solution of the multidimensional Schrodinger equation (including multi-particle problems) is required.
Considering symmetric strictly convex potentials, a local relationship is inferred from the virial theorem, based on which a real log-concave function can be constructed. Using this as a weight function and in such a way that the virial theorem can still be verified, parameter-free ansatze for the eigenfunctions of the associated Schrodinger equation are built. To illustrate the process, the technique is successfully tested against the harmonic oscillator, in which it leads to the exact eigenfunctions, and against the quartic anharmonic oscillator, which is considered the paradigmatic testing ground for new approaches to the Schrodinger equation.
Analytical solutions of the Schrodinger equation are obtained for some diatomic molecular potentials with any angular momentum. The energy eigenvalues and wave functions are calculated exactly. The asymptotic form of the equation is also considered. Algebraic method is used in the calculations.