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Register a new userThe Near-IR Spectrum of Titan Modeled with an Improved Methane Line List
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We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ~5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ~2.1 {mu}m. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 {mu}m. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 {mu}m and allow us to model regions, such as the 1.55 {mu}m window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 {mu}m and 2 {mu}m windows. After the methane lines are modelled our observations are sensitive to additional absorptions, and we use the data in the 1.55 {mu}m region to determine a D/H ratio of 1.77 pm 0.20 x 10-4, and a CO mixing ratio of 50 pm 11 ppmv. In the 2 {mu}m window we detect absorption features that can be identified with the { u}5+3{ u}6 and 2{ u}3+2{ u}6 bands of CH3D.
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A methane line list for the HITEMP spectroscopic database, covering 0-13,400 cm$^{-1}$ ($>$746 nm), is presented. To create this compilation, ab initio line lists of $^{12}$CH$_{4}$ from Rey et al. (2017) ApJ, 847, 105 (provided at separate temperatures in the TheoReTS information system), are now combined with HITRAN2016 methane data to produce a single line list suitable for high-temperature line-by-line calculations up to 2000 K. An effective-temperature interpolation model was created in order to represent continuum-like features at any temperature of interest. This model is advantageous to previously-used approaches that employ so-called ``super-lines, which are suitable only at a given temperature and require separate line lists for different temperatures. The resultant HITEMP line list contains $sim$32 million lines and is significantly more flexible than alternative line lists of methane, while accuracy required for astrophysical or combustion applications is retained. Comparisons against experimental observations of methane absorption at high temperatures have been used to demonstrate the accuracy of the new work. The line list includes both strong lines and quasi-continuum features and is provided in the common user-friendly HITRAN/HITEMP format, making it the most practical methane line list for radiative transfer modeling at high-temperature conditions.
We retrieve vertical and meridional variations of methane mole fraction in Titans lower troposphere by re-analyzing near-infrared ground-based observations from 17 July 2014 UT (Adamkovics et al., 2016). We generate synthetic spectra using atmospheric methane profiles that do not contain supersaturation or discontinuities to fit the observations, and thereby retrieve minimum saturation altitudes and corresponding specific humidities in the boundary layer. We relate these in turn to surface-level relative humidities using independent surface temperature measurements. We also compare our results with general circulation model simulations to interpret and constrain the relationship between humidities and surface liquids. The results show that Titans lower troposphere is undersaturated at latitudes south of 60N, consistent with a dry surface there, but increases in humidity toward the north pole indicate appreciable surface liquid coverage. While our observations are consistent with considerably more liquid methane existing at the north pole than is present in observed lakes, a degeneracy between low-level methane and haze leads to substantial uncertainty in determining the extent of the source region.
DIBs are ubiquitous in stellar spectra. Traditionally, they have been studied through their extraction from hot stars, because of their smooth continuum. In an era where there are several going-on or planned massive Galactic surveys using multi-object spectrographs, cool stars constitute an appealing set of targets. From the technical point of view, the extraction of DIBs in their spectra is more challenging due to the complexity of the continuum. In this contribution we will provide the community with an improved set of stellar lines in the spectral regions associated to the strong DIBs at l6196, l6269, l6284, and l6379. These lines will allow for the creation of better stellar synthetic spectra, reproducing the background emission and a more accurate extraction of the magnitudes associated with a given DIB. The Sun and Arcturus were used as representative examples of dwarf and giant stars, respectively. A high quality spectrum for each of them was modeled using TURBOSPECTRUM and the VALD stellar line list. The oscillator strength log(gf) and/or wavelength of specific lines were modified to create synthetic spectra where the residuals in both the Sun and Arcturus were minimized. The synthetic spectra based on the improved line lists reproduce the observed spectra for the Sun and Arcturus in the mentioned spectral ranges with greater accuracy. Residuals between the synthetic and observed spectra are always <10%, much better than with previously existing options. The new line list has been tested with some characteristic spectra, from a variety of stars, including both giant and dwarf stars, and under different degrees of extinction. As it happened with the Sun and Arcturus residuals in the fits used to extract the DIB information are smaller when using synthetic spectra made with the updated line lists. Tables with the updated parameters are provided to the community.
The spectrum of dicarbon (C2) is important in astrophysics and for spectroscopic studies of plasmas and flames. The C2 spectrum is characterized by many band systems with new ones still being actively identified; astronomical observations involve eight of these bands. Recently, Furtenbacher et al. (2016, Astrophys. J. Suppl., 224, 44) presented a set of 5699 empirical energy levels for 12C2, distributed among 11 electronic states and 98 vibronic bands, derived from 42 experimental studies and obtained using the MARVEL (Measured Active Rotational-Vibrational Energy Levels) procedure. Here, we add data from 13 new sources and update data from 5 sources. Many of these data sources characterize high-lying electronic states, including the newly detected 3Pig state. Older studies have been included following improvements in the MARVEL procedure which allow their uncertainties to be estimated. These older works in particular determine levels in the C1Pig state, the upper state of the insufficiently characterized Deslandres-dAzambuja (C1Pig-A1Piu) band. The new compilation considers a total of 31323 transitions and derives 7047 empirical(MARVEL) energy levels spanning 20 electronic and 142 vibronic states. These new empirical energy levels are used here to update the 8states C2 ExoMol line list. This updated line list is highly suitable for high-resolution cross-correlation studies in astronomical spectroscopy of, for example, exoplanets, as 99.4% of the transitions with intensities over 10^(-18) cm/molecule at 1000 K have frequencies determined by empirical energy levels.
In this research note, we present linemake, an open-source atomic and molecular line list generator. Rather than a replacement for a number of well-established atomic and molecular spectral databases, linemake aims to be a lightweight, easy-to-use tool to generate formatted and curated lists suitable for spectral synthesis work. We encourage users of linemake to understand the sources of their transition data and cite them as appropriate in published work. We provide the code, line database, and an extensive list of literature references in a GitHub repository (https://github.com/vmplacco/linemake), which will be updated regularly as new data become available.
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