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Register a new userIntrinsic and extrinsic x-ray absorption effects in soft x-ray diffraction from the superstructure in magnetite
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We studied the (001/2) diffraction peak in the low-temperature phase of magnetite (Fe3O4) using resonant soft x-ray diffraction (RSXD) at the Fe-L2,3 and O-K resonance. We studied both molecular-beam-epitaxy (MBE) grown thin films and in-situ cleaved single crystals. From the comparison we have been able to determine quantitatively the contribution of intrinsic absorption effects, thereby arriving at a consistent result for the (001/2) diffraction peak spectrum. Our data also allow for the identification of extrinsic effects, e.g. for a detailed modeling of the spectra in case a dead surface layer is present that is only absorbing photons but does not contribute to the scattering signal.
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Here we show that the low temperature phase of magnetite is associated with an effective, although fractional, ordering of the charge. Evidence and a quantitative evaluation of the atomic charges are achieved by using resonant x-ray diffraction (RXD) experiments whose results are further analyzed with the help of ab initio calculations of the scattering factors involved. By confirming the results obtained from X-ray crystallography we have shown that RXD is able to probe quantitatively the electronic structure in very complex oxides, whose importance covers a wide domain of applications.
A general symmetry analysis of the optical conductivity or scattering tensor is used to rewrite the conductivity tensor as a sum of fundamental spectra multiplied by simple functions depending on the local magnetization direction. Using this formalism, we present several numerical examples at the transition metal L23 edge. From these numerical calculations we can conclude that large deviations from the magneto-optical effects in spherical symmetry are found. These findings are in particular important for resonant x-ray diffraction experiments where the polarization dependence and azimuthal dependence of the scattered Bragg intensity is used to determine the local ordered magnetization direction.
Magnetite, Fe$_3$O$_4$, displays a highly complex low temperature crystal structure that may be charge and orbitally ordered. Many of the recent experimental claims of such ordering rely on resonant soft x-ray diffraction at the oxygen K and iron L edges. We have re-examined this system and undertaken soft x-ray diffraction experiments on a high-quality single crystal. Contrary to previous claims in the literature, we show that the intensity observed at the Bragg forbidden (001/2)$_c$ reflection can be explained purely in terms of the low-temperature structural displacements around the resonant atoms. This does not necessarily mean that magnetite is not charge or orbitally ordered, but rather that the present sensitivity of resonant soft x-ray experiments does not allow conclusive demonstration of such ordering.
We report the design and construction of a novel soft x-ray diffractometer installed at Diamond Light Source. The beamline endstation RASOR is constructed for general users and designed primarily for the study of single crystal diffraction and thin film reflectivity. The instrument is comprised of a limited three circle ({theta}, 2{theta}, {chi}) diffractometer with an additional removable rotation ({phi}) stage. It is equipped with a liquid helium cryostat, and post-scatter polarization analysis. Motorised motions are provided for the precise positioning of the sample onto the diffractometer centre of rotation, and for positioning the centre of rotation onto the x-ray beam. The functions of the instrument have been tested at Diamond Light Source, and initial test measurements are provided, demonstrating the potential of the instrument.
Strong resonant enhancements of the charge-order and spin-order superstructure-diffraction intensities in La1.8Sr0.2NiO4 are observed when x-ray energies in the vicinity of the Ni L2,3 absorption edges are used. The pronounced photon-energy and polarization dependences of these diffraction intensities allow for a critical determination of the local symmetry of the ordered spin and charge carriers. We found that not only the antiferromagnetic order but also the charge-order superstructure resides within the NiO2 layers; the holes are mainly located on in-plane oxygens surrounding a Ni2+ site with the spins coupled antiparallel in close analogy to Zhang-Rice singlets in the cuprates.
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