Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userLight scattering study of low-energy vibrational excitations in the metallic glass Ni$_{67}$Zr$_{33}$ using electronic Raman scattering
170
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
The Raman response of the metallic glass Ni$_{67}$Zr$_{33}$ is measured as a function of polarization and temperature and analyzed theoretically. Unexpectedly, the intensity in the range up to 300wn increases upon cooling, which is counterintuitive when the response originates from vibrations alone as in insulators. The increase finds a natural explanation if the conduction electrons are assumed to scatter on localized vibrations with a scattering probability proportional to the Debye-Waller factor. None of our assumptions is material specific, and the results are expected to be relevant for disordered systems in general.
rate research
Read More
Using molecular dynamics simulation, we calculate the distribution of atomic jum ps in Cu$_{33}$Zr$_{67}$ in the liquid and glassy states. In both states the distribution of jump lengths can be described by a temperature independent exponential of the length and an effective activation energy plus a contribution of elastic displacements at short distances. Upon cooling the contribution of shorter jumps dominates. No indication of an enhanced probability to jump over a nearest neighbor distance was found. We find a smooth transition from flow in the liquid to jumps in the g lass. The correlation factor of the diffusion constant decreases with decreasing temperature, causing a drop of diffusion below the Arrhenius value, despite an apparent Arrhenius law for the jump probability.
A non--equilibrium occupation distribution relaxes towards the Fermi--Dirac distribution due to electron--electron scattering even in finite Fermi systems. The dynamic evolution of this thermalization process assumed to result from an optical excitation is investigated numerically by solving a Boltzmann equation for the carrier populations using a one--dimensional disordered system. We focus on the short time--scale behavior. The logarithmically long time--scale associated with the glassy behavior of interacting electrons in disordered systems is not treated in our investigation. For weak disorder and short range interaction we recover the expected result that disorder enhances the relaxation rate as compared to the case without disorder. For sufficiently strong disorder, however, we find an opposite trend due to the reduction of scattering probabilities originating from the strong localization of the single--particle states. Long--range interaction in this regime produces a similar effect. The relaxation rate is found to scale with the interaction strength, however, the interplay between the implicit and the explicit character of the interaction produces an anomalous exponent.
We report new inelastic Raman and neutron scattering spectra for glasses with different degrees of fragility; the data are compared for each sample to obtain the Raman coupling function $C(omega)$. The study indicates a general linear behaviour of the $C(omega)$ near the Boson peak maximum, and evidence a correlation between vibrational and relaxational properties, already observed in recent publications.
We investigated temperature dependent Raman spectra of the one-dimensional spin-ladder compound SrCu2O3. At low temperatures a two-magnon peak is identified at 3160+/-10 cm^(-1) and its temperature dependence analyzed in terms of a thermal expansion model. We find that the two-magnon peak position must include a cyclic ring exchange of J_cycl/J_perp=0.09-0.25 with a coupling constant along the rungs of J_perp approx. 1215 cm^(-1) (1750 K) in order to be consistent with other experiments and theoretical results.
High-energy, local multiplet excitations of the d-electrons are revealed in our inelastic neutron scattering measurements on the prototype magnetic insulator NiO. These become allowed by the presence of both non-zero crystal field and spin-orbit coupling. The observed excitations are consistent with optical, x-ray, and EELS measurements of d-d excitations. This experiment serves as a proof of principle that high-energy neutron spectroscopy is a reliable and useful technique for probing electronic excitations in systems with significant crystal field and spin-orbit interactions.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
