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Register a new userCoherent transfer of photoassociated molecules into the rovibrational ground state
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We report on the direct conversion of laser-cooled 41K and 87Rb atoms into ultracold 41K87Rb molecules in the rovibrational ground state via photoassociation followed by stimulated Raman adiabatic passage. High-resolution spectroscopy based on the coherent transfer revealed the hyperfine structure of weakly bound molecules in an unexplored region. Our results show that a rovibrationally pure sample of ultracold ground-state molecules is achieved via the all-optical association of laser-cooled atoms, opening possibilities to coherently manipulate a wide variety of molecules.
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We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by stimulated Raman adiabatic passage (STIRAP). We measure the binding energy of the RbCs molecule to be $h c times 3811.576(1)$ cm$^{-1}$ and the $|v=0, J=0>$ to $|v=0, J=2>$ splitting to be $h times 2940.09(6)$ MHz. Stark spectroscopy of the rovibrational ground state yields an electric dipole moment of 1.225(3)(8) D, where the values in parentheses are the statistical and systematic uncertainties, respectively. We demonstrate that a space-fixed dipole moment of 0.355(2)(4) D is accessible in RbCs, which is substantially higher than in previous work.
We propose and experimentally investigate a scheme for narrow-line cooling of KRb molecules in the rovibrational ground state. We show that the spin-forbidden $mathrm{X^1Sigma^+} rightarrow mathrm{b^3Pi_{0^+}}$ transition of KRb is ideal for realizing narrow-line laser cooling of molecules because it has highly diagonal Franck-Condon factors and narrow linewidth. In order to confirm the prediction, we performed the optical and microwave spectroscopy of ultracold $^{41}$K$^{87}$Rb molecules, and determined the linewidth ($2pitimes$ 4.9(4) kHz) and Franck-Condon factors for the $mathrm{X^1Sigma^+} (v=0) rightarrow mathrm{b^3Pi_{0^+}} (v=0)$ transition (0.9474(1)). This result opens the door towards all-optical production of polar molecules at sub-microkelvin temperatures.
In this work we discuss the rotational structure of Rydberg molecules. We calculate the complete wave function in a laboratory fixed frame and derive the transition matrix elements for the pho- toassociation of free ground state atoms. We discuss the implications for the excitation of different rotational states as well as the shape of the angular nuclear wave function. We find a rather com- plex shape and unintuitive coupling strengths, depending on the angular momenta coupling that are relevant for the states. This work explains the different steps to calculate the wave functions and the transition matrix elements in a way, that they can be directly transferred to different molecular states, atomic species or molecular coupling cases.
We demonstrate the coherent creation of a single NaCs molecule in its rotational, vibrational, and electronic (rovibronic) ground state in an optical tweezer. Starting with a weakly bound Feshbach molecule, we locate a two-photon transition via the $|{c^3Sigma,v=26}rangle$ excited state and drive coherent Rabi oscillations between the Feshbach state and a single hyperfine level of the NaCs rovibronic ground state $|{X^1Sigma,v=0,N=0}rangle$ with a binding energy of $D_0 = h times 147038.30(2)$ GHz. We measure a lifetime of $3.4pm1.6$ s for the rovibronic ground-state molecule, which possesses a large molecule-frame dipole moment of 4.6 Debye and occupies predominantly the motional ground state. These long-lived, fully quantum-state-controlled individual dipolar molecules provide a key resource for molecule-based quantum simulation and information processing.
We report the observation of microwave coherent control of rotational states of ultracold $^{85}$Rb$^{133}$Cs molecules formed in their vibronic ground state by short-range photoassociation. Molecules are formed in the single rotational state $X(v=0,J=1)$ by exciting pairs of atoms to the short-range state $(2)^{3}Pi_{0^{-}} (v=11, J=0)$, followed by spontaneous decay. We use depletion spectroscopy to record the dynamic evolution of the population distribution and observe clear Rabi oscillations while irradiating on a microwave transition between coupled neighbouring rotational levels. A density-matrix formalism that accounts for longitudinal and transverse decay times reproduces both the dynamic evolution during the coherent process and the equilibrium population. The coherent control reported here is valuable both for investigating coherent quantum effects and for applications of cold polar molecules produced by continuous short-range photoassociation.
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