No Arabic abstract
The statistical mechanics of periodically driven (Floquet) systems in contact with a heat bath exhibits some radical differences from the traditional statistical mechanics of undriven systems. In Floquet systems all quasienergies can be placed in a finite frequency interval, and the number of near degeneracies in this interval grows without limit as the dimension N of the Hilbert space increases. This leads to pathologies, including drastic changes in the Floquet states, as N increases. In earlier work these difficulties were put aside by fixing N, while taking the coupling to the bath to be smaller than any quasienergy difference. This led to a simple explicit theory for the reduced density matrix, but with some major differences from the usual time independent statistical mechanics. We show that, for weak but finite coupling between system and heat bath, the accuracy of a calculation within the truncated Hilbert space spanned by the N lowest energy eigenstates of the undriven system is limited, as N increases indefinitely, only by the usual neglect of bath memory effects within the Born and Markov approximations. As we seek higher accuracy by increasing N, we inevitably encounter quasienergy differences smaller than the system-bath coupling. We therefore derive the steady state reduced density matrix without restriction on the size of quasienergy splittings. In general, it is no longer diagonal in the Floquet states. We analyze, in particular, the behavior near a weakly avoided crossing, where quasienergy near degeneracies routinely appear. The explicit form of our results for the denisty matrix gives a consistent prescription for the statistical mechanics for many periodically driven systems with N infinite, in spite of the Floquet state pathologies.
Equilibrium statistical mechanics rests on the assumption of ergodic dynamics of a system modulo the conservation laws of local observables: extremization of entropy immediately gives Gibbs ensemble (GE) for energy conserving systems and a generalized version of it (GGE) when the number of local conserved quantities (LCQ) is more than one. Through the last decade, statistical mechanics has been extended to describe the late-time behaviour of periodically driven (Floquet) quantum matter starting from a generic state. The structure built on the fundamental assumptions of ergodicity and identification of the relevant conservation laws in this inherently non-equilibrium setting. More recently, it has been shown that the statistical mechanics has a much richer structure due to the existence of {it emergent} conservation laws: these are approximate but stable conservation laws arising {it due to the drive}, and are not present in the undriven system. Extensive numerical and analytical results support perpetual stability of these emergent (though approximate) conservation laws, probably even in the thermodynamic limit. This banks on the recent finding of a sharp ergodicity threshold for Floquet thermalization in clean, interacting non-integrable Floquet systems. This opens up a new possibility of stable Floquet engineering in such systems. This review intends to give a theoretical overview of these developments. We conclude by briefly surveying the experimental scenario.
Do negative absolute temperatures matter physics and specifically Statistical Physics? We provide evidence that we can certainly answer positively to this vexata quaestio. The great majority of models investigated by statistical mechanics over almost one century and a half exhibit positive absolute temperature, because their entropy is a nondecreasing function of energy. Since more than half a century ago it has been realized that this may not be the case for some physical systems as incompressible fluids, nuclear magnetic chains, lasers, cold atoms and optical waveguides. We review these examples and discuss their peculiar thermodynamic properties, which have been associated to the presence of thermodynamic regimes, characterized by negative absolute temperatures. As reported in this review, the ambiguity inherent the definition of entropy has recurrently raised a harsh debate about the possibility of considering negative temperature states as genuine thermodynamic equilibrium ones. Here we show that negative absolute temperatures are consistent with equilibrium as well as with non-equilibrium thermodynamics. In particular, thermometry, thermodynamics of cyclic transformations, ensemble equivalence, fluctuation-dissipation relations, response theory and even transport processes can be reformulated to include them, thus dissipating any prejudice about their exceptionality, typically presumed as a manifestation of transient metastable effects.
The majority game, modelling a system of heterogeneous agents trying to behave in a similar way, is introduced and studied using methods of statistical mechanics. The stationary states of the game are given by the (local) minima of a particular Hopfield like hamiltonian. On the basis of a replica symmetric calculations, we draw the phase diagram, which contains the analog of a retrieval phase. The number of metastable states is estimated using the annealed approximation. The results are confronted with extensive numerical simulations.
We address the statistical mechanics of randomly and permanently crosslinked networks. We develop a theoretical framework (vulcanization theory) which can be used to systematically analyze the correlation between the statistical properties of random networks and their histories of formation. Generalizing the original idea of Deam and Edwards, we consider an instantaneous crosslinking process, where all crosslinkers (modeled as Gaussian springs) are introduced randomly at once in an equilibrium liquid state, referred to as the preparation state. The probability that two functional sites are crosslinked by a spring exponentially decreases with their distance squared. After formally averaging over network connectivity, we obtained an effective theory with all degrees of freedom replicated 1 + n times. Two thermodynamic ensembles, the preparation ensemble and the measurement ensemble, naturally appear in this theory. The former describes the thermodynamic fluctuations in the state of preparation, while the latter describes the thermodynamic fluctuations in the state of measurement. We classify various correlation functions and discuss their physical significances. In particular, the memory correlation functions characterize how the properties of networks depend on their history of formation, and are the hallmark properties of all randomly crosslinked materials. We clarify the essential difference between our approach and that of Deam-Edwards, discuss the saddle-point order parameters and its physical significance. Finally we also discuss the connection between saddle-point approximation of vulcanization theory, and the classical theory of rubber elasticity as well as the neo-classical theory of nematic elastomers.
Recently, we have presented some simple arguments supporting the existence of certain complementarity between thermodynamic quantities of temperature and energy, an idea suggested by Bohr and Heinsenberg in the early days of Quantum Mechanics. Such a complementarity is expressed as the impossibility of perform an exact simultaneous determination of the system energy and temperature by using an experimental procedure based on the thermal equilibrium with other system regarded as a measure apparatus (thermometer). In this work, we provide a simple generalization of this latter approach with the consideration of a thermodynamic situation with several control parameters.